Loading…
Automated method for the determination of total arsenic and selenium in natural and drinking water by HG-AAS
A multicommutated flow system was designed and evaluated for the determination of total arsenic and selenium by Hydride Generation Atomic Absorption Spectrometry (HG-AAS). It was applied to the determination of arsenic and selenium in samples of natural and drinking water. Detection limits were 0.46...
Saved in:
| Published in: | Environmental geochemistry and health 2012-04, Vol.34 (2), p.273-278 |
|---|---|
| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-a425t-dd69d57be698af3f23fab848c4906a270330087ca1aab31c6aa6b9e786fe3cdb3 |
|---|---|
| cites | cdi_FETCH-LOGICAL-a425t-dd69d57be698af3f23fab848c4906a270330087ca1aab31c6aa6b9e786fe3cdb3 |
| container_end_page | 278 |
| container_issue | 2 |
| container_start_page | 273 |
| container_title | Environmental geochemistry and health |
| container_volume | 34 |
| creator | Pistón, Mariela Silva, Javier Pérez-Zambra, Ramiro Dol, Isabel Knochen, Moisés |
| description | A multicommutated flow system was designed and evaluated for the determination of total arsenic and selenium by Hydride Generation Atomic Absorption Spectrometry (HG-AAS). It was applied to the determination of arsenic and selenium in samples of natural and drinking water. Detection limits were 0.46 and 0.08 μg l
−1
for arsenic and selenium, respectively; sampling frequency was 120 samples h
−1
for arsenic and 160 samples h
−1
for selenium. Linear ranges found were 1.54–10 μg l
−1
(
R
= 0.999) for arsenic and 0.27–27 μg l
−1
(
R
= 0.999) for selenium. Accuracy was evaluated by spiking various water samples and using a reference material. Recoveries were in the range 95–116%. Analytical precision (
s
r
(%),
n
= 10) was 6% for both elements. Compared with the Standard Methods, APHA, 3114B manual method, the system consumes at least 10 times less sample per determination, and the quantities of acid and reducing agent used are significantly lower with a reduction in the generation of pollutants and waste. As an additional advantage, the system is very fast, efficient and environmentally friendly for monitoring total arsenic and selenium levels in waters. |
| doi_str_mv | 10.1007/s10653-011-9436-9 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_968167019</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>968167019</sourcerecordid><originalsourceid>FETCH-LOGICAL-a425t-dd69d57be698af3f23fab848c4906a270330087ca1aab31c6aa6b9e786fe3cdb3</originalsourceid><addsrcrecordid>eNp1kU1rFTEUhoMo9lr9AW4kuHEVzcdMPpaXUttCwYW6DmcmZ9qpM0lNMpT-e3O5VUFwlZDz5DmH8xLyVvCPgnPzqQiue8W4EMx1SjP3jOxEbxSTzqrnZMeldqzjnTwhr0q545w709mX5EQKpzvb6x1Z9ltNK1QMdMV6mwKdUqb1FmnAinmdI9Q5RZomWlOFhUIuGOeRQgy04NLu20rnSBu35UO9vYc8xx9zvKEPTZzp8EgvL9h-__U1eTHBUvDN03lKvn8-_3Z2ya6_XFyd7a8ZdLKvLATtQm8G1M7CpCapJhhsZ8fOcQ3ScKU4t2YEATAoMWoAPTg0Vk-oxjCoU_Lh6L3P6eeGpfp1LiMuC0RMW_FOW6ENF66R7_8h79KWYxvOO6n73ggpGySO0JhTKRknf5_nFfKjF9wfgvDHIHwLwh-C8AfxuyfxNqwY_vz4vfkGyCNQWineYP7b-f_WX_pwk7E</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>926557122</pqid></control><display><type>article</type><title>Automated method for the determination of total arsenic and selenium in natural and drinking water by HG-AAS</title><source>Springer Nature</source><creator>Pistón, Mariela ; Silva, Javier ; Pérez-Zambra, Ramiro ; Dol, Isabel ; Knochen, Moisés</creator><creatorcontrib>Pistón, Mariela ; Silva, Javier ; Pérez-Zambra, Ramiro ; Dol, Isabel ; Knochen, Moisés</creatorcontrib><description>A multicommutated flow system was designed and evaluated for the determination of total arsenic and selenium by Hydride Generation Atomic Absorption Spectrometry (HG-AAS). It was applied to the determination of arsenic and selenium in samples of natural and drinking water. Detection limits were 0.46 and 0.08 μg l
−1
for arsenic and selenium, respectively; sampling frequency was 120 samples h
−1
for arsenic and 160 samples h
−1
for selenium. Linear ranges found were 1.54–10 μg l
−1
(
R
= 0.999) for arsenic and 0.27–27 μg l
−1
(
R
= 0.999) for selenium. Accuracy was evaluated by spiking various water samples and using a reference material. Recoveries were in the range 95–116%. Analytical precision (
s
r
(%),
n
= 10) was 6% for both elements. Compared with the Standard Methods, APHA, 3114B manual method, the system consumes at least 10 times less sample per determination, and the quantities of acid and reducing agent used are significantly lower with a reduction in the generation of pollutants and waste. As an additional advantage, the system is very fast, efficient and environmentally friendly for monitoring total arsenic and selenium levels in waters.</description><identifier>ISSN: 0269-4042</identifier><identifier>EISSN: 1573-2983</identifier><identifier>DOI: 10.1007/s10653-011-9436-9</identifier><identifier>PMID: 21964856</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Arsenic ; Arsenic - analysis ; Arsenic - chemistry ; Arsenic content ; Atomic absorption spectroscopy ; Calibration ; Detection limits ; Drinking water ; Drinking Water - chemistry ; Earth and Environmental Science ; Environment ; Environmental Chemistry ; Environmental Health ; Geochemistry ; Medical research ; Original Paper ; Public Health ; Selenium ; Selenium - analysis ; Selenium - chemistry ; Soil Science & Conservation ; Spectral analysis ; Spectrometry ; Spectrophotometry, Atomic - methods ; Terrestrial Pollution ; Water analysis ; Water Pollutants, Chemical - analysis ; Water Pollutants, Chemical - chemistry ; Water sampling</subject><ispartof>Environmental geochemistry and health, 2012-04, Vol.34 (2), p.273-278</ispartof><rights>Springer Science+Business Media B.V. 2011</rights><rights>Springer Science+Business Media B.V. 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a425t-dd69d57be698af3f23fab848c4906a270330087ca1aab31c6aa6b9e786fe3cdb3</citedby><cites>FETCH-LOGICAL-a425t-dd69d57be698af3f23fab848c4906a270330087ca1aab31c6aa6b9e786fe3cdb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21964856$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Pistón, Mariela</creatorcontrib><creatorcontrib>Silva, Javier</creatorcontrib><creatorcontrib>Pérez-Zambra, Ramiro</creatorcontrib><creatorcontrib>Dol, Isabel</creatorcontrib><creatorcontrib>Knochen, Moisés</creatorcontrib><title>Automated method for the determination of total arsenic and selenium in natural and drinking water by HG-AAS</title><title>Environmental geochemistry and health</title><addtitle>Environ Geochem Health</addtitle><addtitle>Environ Geochem Health</addtitle><description>A multicommutated flow system was designed and evaluated for the determination of total arsenic and selenium by Hydride Generation Atomic Absorption Spectrometry (HG-AAS). It was applied to the determination of arsenic and selenium in samples of natural and drinking water. Detection limits were 0.46 and 0.08 μg l
−1
for arsenic and selenium, respectively; sampling frequency was 120 samples h
−1
for arsenic and 160 samples h
−1
for selenium. Linear ranges found were 1.54–10 μg l
−1
(
R
= 0.999) for arsenic and 0.27–27 μg l
−1
(
R
= 0.999) for selenium. Accuracy was evaluated by spiking various water samples and using a reference material. Recoveries were in the range 95–116%. Analytical precision (
s
r
(%),
n
= 10) was 6% for both elements. Compared with the Standard Methods, APHA, 3114B manual method, the system consumes at least 10 times less sample per determination, and the quantities of acid and reducing agent used are significantly lower with a reduction in the generation of pollutants and waste. As an additional advantage, the system is very fast, efficient and environmentally friendly for monitoring total arsenic and selenium levels in waters.</description><subject>Arsenic</subject><subject>Arsenic - analysis</subject><subject>Arsenic - chemistry</subject><subject>Arsenic content</subject><subject>Atomic absorption spectroscopy</subject><subject>Calibration</subject><subject>Detection limits</subject><subject>Drinking water</subject><subject>Drinking Water - chemistry</subject><subject>Earth and Environmental Science</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Geochemistry</subject><subject>Medical research</subject><subject>Original Paper</subject><subject>Public Health</subject><subject>Selenium</subject><subject>Selenium - analysis</subject><subject>Selenium - chemistry</subject><subject>Soil Science & Conservation</subject><subject>Spectral analysis</subject><subject>Spectrometry</subject><subject>Spectrophotometry, Atomic - methods</subject><subject>Terrestrial Pollution</subject><subject>Water analysis</subject><subject>Water Pollutants, Chemical - analysis</subject><subject>Water Pollutants, Chemical - chemistry</subject><subject>Water sampling</subject><issn>0269-4042</issn><issn>1573-2983</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp1kU1rFTEUhoMo9lr9AW4kuHEVzcdMPpaXUttCwYW6DmcmZ9qpM0lNMpT-e3O5VUFwlZDz5DmH8xLyVvCPgnPzqQiue8W4EMx1SjP3jOxEbxSTzqrnZMeldqzjnTwhr0q545w709mX5EQKpzvb6x1Z9ltNK1QMdMV6mwKdUqb1FmnAinmdI9Q5RZomWlOFhUIuGOeRQgy04NLu20rnSBu35UO9vYc8xx9zvKEPTZzp8EgvL9h-__U1eTHBUvDN03lKvn8-_3Z2ya6_XFyd7a8ZdLKvLATtQm8G1M7CpCapJhhsZ8fOcQ3ScKU4t2YEATAoMWoAPTg0Vk-oxjCoU_Lh6L3P6eeGpfp1LiMuC0RMW_FOW6ENF66R7_8h79KWYxvOO6n73ggpGySO0JhTKRknf5_nFfKjF9wfgvDHIHwLwh-C8AfxuyfxNqwY_vz4vfkGyCNQWineYP7b-f_WX_pwk7E</recordid><startdate>20120401</startdate><enddate>20120401</enddate><creator>Pistón, Mariela</creator><creator>Silva, Javier</creator><creator>Pérez-Zambra, Ramiro</creator><creator>Dol, Isabel</creator><creator>Knochen, Moisés</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7ST</scope><scope>7UA</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>88I</scope><scope>8AO</scope><scope>8C1</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>F1W</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>H97</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>L.G</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>SOI</scope><scope>7QH</scope><scope>7SN</scope><scope>7TV</scope></search><sort><creationdate>20120401</creationdate><title>Automated method for the determination of total arsenic and selenium in natural and drinking water by HG-AAS</title><author>Pistón, Mariela ; Silva, Javier ; Pérez-Zambra, Ramiro ; Dol, Isabel ; Knochen, Moisés</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a425t-dd69d57be698af3f23fab848c4906a270330087ca1aab31c6aa6b9e786fe3cdb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Arsenic</topic><topic>Arsenic - analysis</topic><topic>Arsenic - chemistry</topic><topic>Arsenic content</topic><topic>Atomic absorption spectroscopy</topic><topic>Calibration</topic><topic>Detection limits</topic><topic>Drinking water</topic><topic>Drinking Water - chemistry</topic><topic>Earth and Environmental Science</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Geochemistry</topic><topic>Medical research</topic><topic>Original Paper</topic><topic>Public Health</topic><topic>Selenium</topic><topic>Selenium - analysis</topic><topic>Selenium - chemistry</topic><topic>Soil Science & Conservation</topic><topic>Spectral analysis</topic><topic>Spectrometry</topic><topic>Spectrophotometry, Atomic - methods</topic><topic>Terrestrial Pollution</topic><topic>Water analysis</topic><topic>Water Pollutants, Chemical - analysis</topic><topic>Water Pollutants, Chemical - chemistry</topic><topic>Water sampling</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pistón, Mariela</creatorcontrib><creatorcontrib>Silva, Javier</creatorcontrib><creatorcontrib>Pérez-Zambra, Ramiro</creatorcontrib><creatorcontrib>Dol, Isabel</creatorcontrib><creatorcontrib>Knochen, Moisés</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Environment Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>Public Health Database</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Science Database</collection><collection>Environmental Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>Environment Abstracts</collection><collection>Aqualine</collection><collection>Ecology Abstracts</collection><collection>Pollution Abstracts</collection><jtitle>Environmental geochemistry and health</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pistón, Mariela</au><au>Silva, Javier</au><au>Pérez-Zambra, Ramiro</au><au>Dol, Isabel</au><au>Knochen, Moisés</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Automated method for the determination of total arsenic and selenium in natural and drinking water by HG-AAS</atitle><jtitle>Environmental geochemistry and health</jtitle><stitle>Environ Geochem Health</stitle><addtitle>Environ Geochem Health</addtitle><date>2012-04-01</date><risdate>2012</risdate><volume>34</volume><issue>2</issue><spage>273</spage><epage>278</epage><pages>273-278</pages><issn>0269-4042</issn><eissn>1573-2983</eissn><abstract>A multicommutated flow system was designed and evaluated for the determination of total arsenic and selenium by Hydride Generation Atomic Absorption Spectrometry (HG-AAS). It was applied to the determination of arsenic and selenium in samples of natural and drinking water. Detection limits were 0.46 and 0.08 μg l
−1
for arsenic and selenium, respectively; sampling frequency was 120 samples h
−1
for arsenic and 160 samples h
−1
for selenium. Linear ranges found were 1.54–10 μg l
−1
(
R
= 0.999) for arsenic and 0.27–27 μg l
−1
(
R
= 0.999) for selenium. Accuracy was evaluated by spiking various water samples and using a reference material. Recoveries were in the range 95–116%. Analytical precision (
s
r
(%),
n
= 10) was 6% for both elements. Compared with the Standard Methods, APHA, 3114B manual method, the system consumes at least 10 times less sample per determination, and the quantities of acid and reducing agent used are significantly lower with a reduction in the generation of pollutants and waste. As an additional advantage, the system is very fast, efficient and environmentally friendly for monitoring total arsenic and selenium levels in waters.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><pmid>21964856</pmid><doi>10.1007/s10653-011-9436-9</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0269-4042 |
| ispartof | Environmental geochemistry and health, 2012-04, Vol.34 (2), p.273-278 |
| issn | 0269-4042 1573-2983 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_968167019 |
| source | Springer Nature |
| subjects | Arsenic Arsenic - analysis Arsenic - chemistry Arsenic content Atomic absorption spectroscopy Calibration Detection limits Drinking water Drinking Water - chemistry Earth and Environmental Science Environment Environmental Chemistry Environmental Health Geochemistry Medical research Original Paper Public Health Selenium Selenium - analysis Selenium - chemistry Soil Science & Conservation Spectral analysis Spectrometry Spectrophotometry, Atomic - methods Terrestrial Pollution Water analysis Water Pollutants, Chemical - analysis Water Pollutants, Chemical - chemistry Water sampling |
| title | Automated method for the determination of total arsenic and selenium in natural and drinking water by HG-AAS |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-02T23%3A48%3A36IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Automated%20method%20for%20the%20determination%20of%20total%20arsenic%20and%20selenium%20in%20natural%20and%20drinking%20water%20by%20HG-AAS&rft.jtitle=Environmental%20geochemistry%20and%20health&rft.au=Pist%C3%B3n,%20Mariela&rft.date=2012-04-01&rft.volume=34&rft.issue=2&rft.spage=273&rft.epage=278&rft.pages=273-278&rft.issn=0269-4042&rft.eissn=1573-2983&rft_id=info:doi/10.1007/s10653-011-9436-9&rft_dat=%3Cproquest_cross%3E968167019%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a425t-dd69d57be698af3f23fab848c4906a270330087ca1aab31c6aa6b9e786fe3cdb3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=926557122&rft_id=info:pmid/21964856&rfr_iscdi=true |