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Synthesis of Triangular Metallodendrimers via Coordination-Driven Self-Assembly

A new family of 60° dendritic di-Pt(II) acceptor tectons have been successfully designed and synthesized, from which a series of novel “three-component” triangular metallodendrimers were prepared via [3 + 3] coordination-driven self-assembly. The structures of newly designed triangular metallodendri...

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Published in:	Journal of organic chemistry 2012-04, Vol.77 (7), p.3426-3432
Main Authors:	Han, Qing, Wang, Li-Lei, Li, Quan-Jie, Zhao, Guang-Zhen, He, Jiuming, Hu, Bingjie, Tan, Hongwei, Abliz, Zeper, Yu, Yihua, Yang, Hai-Bo
Format:	Article
Language:	English
Subjects:	Applied sciences Chemistry Coordination compounds Cross-disciplinary physics: materials science rheology Crystallography, X-Ray Dendrimers - chemical synthesis Dendrimers - chemistry Exact sciences and technology Inorganic chemistry and origins of life Magnetic Resonance Spectroscopy Materials science Methods of nanofabrication Models, Molecular Organic polymers Organoplatinum Compounds - chemical synthesis Organoplatinum Compounds - chemistry Physicochemistry of polymers Physics Polymers with particular structures Preparation, kinetics, thermodynamics, mechanism and catalysts Preparations and properties Supramolecular and biochemical assembly
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container_title	Journal of organic chemistry
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creator	Han, Qing Wang, Li-Lei Li, Quan-Jie Zhao, Guang-Zhen He, Jiuming Hu, Bingjie Tan, Hongwei Abliz, Zeper Yu, Yihua Yang, Hai-Bo
description	A new family of 60° dendritic di-Pt(II) acceptor tectons have been successfully designed and synthesized, from which a series of novel “three-component” triangular metallodendrimers were prepared via [3 + 3] coordination-driven self-assembly. The structures of newly designed triangular metallodendrimers are characterized by multinuclear NMR (1H and 31P), 1H DOSY NMR, mass spectrometry (CSI-TOF-MS), and elemental analysis. The shape and size of all supramolecular dendritic triangles were investigated with PM6 semiempirical molecular orbital methods.
doi_str_mv	10.1021/jo300016a
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Org. Chem</addtitle><description>A new family of 60° dendritic di-Pt(II) acceptor tectons have been successfully designed and synthesized, from which a series of novel “three-component” triangular metallodendrimers were prepared via [3 + 3] coordination-driven self-assembly. The structures of newly designed triangular metallodendrimers are characterized by multinuclear NMR (1H and 31P), 1H DOSY NMR, mass spectrometry (CSI-TOF-MS), and elemental analysis. 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source	American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects	Applied sciences Chemistry Coordination compounds Cross-disciplinary physics: materials science rheology Crystallography, X-Ray Dendrimers - chemical synthesis Dendrimers - chemistry Exact sciences and technology Inorganic chemistry and origins of life Magnetic Resonance Spectroscopy Materials science Methods of nanofabrication Models, Molecular Organic polymers Organoplatinum Compounds - chemical synthesis Organoplatinum Compounds - chemistry Physicochemistry of polymers Physics Polymers with particular structures Preparation, kinetics, thermodynamics, mechanism and catalysts Preparations and properties Supramolecular and biochemical assembly
title	Synthesis of Triangular Metallodendrimers via Coordination-Driven Self-Assembly
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