Poly[μ(6)-pyridine-2,4-dicarboxyl-ato-barium]

In the title complex, [Ba(C(7)H(3)NO(4))](n), the coordination geometry around the Ba(II) ion can be described as a distorted bicapped trigonal-prismatic BaNO(7) arrangement. The pyridine-2,4-dicarb-oxy-lic acid ligands exhibit a new coordination mode. Adjacent metal centers are linked by the O atom...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-06, Vol.66 (Pt 7), p.m832
Main Authors: Shuai, Qi, Zhao, Xiao-Nong, Zhao, Li, Hu, Fan
Format: Article
Language:English
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Summary:In the title complex, [Ba(C(7)H(3)NO(4))](n), the coordination geometry around the Ba(II) ion can be described as a distorted bicapped trigonal-prismatic BaNO(7) arrangement. The pyridine-2,4-dicarb-oxy-lic acid ligands exhibit a new coordination mode. Adjacent metal centers are linked by the O atoms of the pyridine-2,4-dicarb-oxy-lic acid ligands, and then form a three-dimensional supra-molecular polymeric framework.
ISSN:1600-5368