Controlled solvothermal synthesis of novel organic functionalized polyoxovanadates

Four novel organic functionalized polyoxovanadates are solvothermally synthesized by altering the reaction temperature and using different organoarsonic acids. These POVs are fully characterized and the phase transitions between different POVs structures are confirmed by X-ray diffraction analyses....

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Published in:Dalton transactions : an international journal of inorganic chemistry 2012-06, Vol.41 (23), p.691-6913
Main Authors: Chen, Baokuan, Wang, Bo, Lin, Zhengguo, Fan, Linyuan, Gao, Yuanzhe, Chi, Yingnan, Hu, Changwen
Format: Article
Language:English
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Controlled atmospheres
Diffraction
Phase transformations
Synthesis
X-rays
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container_title Dalton transactions : an international journal of inorganic chemistry
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creator Chen, Baokuan
Wang, Bo
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description Four novel organic functionalized polyoxovanadates are solvothermally synthesized by altering the reaction temperature and using different organoarsonic acids. These POVs are fully characterized and the phase transitions between different POVs structures are confirmed by X-ray diffraction analyses. Such a transition is temperature-dependent and thus controlled synthesis of new POVs can be achieved. Four novel organic functionalized polyoxovanadates are solvothermally synthesized by altering the reaction temperature and by using different organoarsonic acids.
doi_str_mv 10.1039/c2dt30660c
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subjects Controlled atmospheres
Diffraction
Phase transformations
Synthesis
X-rays
title Controlled solvothermal synthesis of novel organic functionalized polyoxovanadates
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