Catalytic, enantioselective vinylogous Michael reactions

Recent progress in the field of catalytic, enantioselective vinylogous Michael reactions of latent dienolates is described which furnish optically highly enriched chiral 1,7-dioxo compounds of great utility in one synthetic operation. Emphasis is given to new catalysis modes which realise this chall...

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2014-06, Vol.12 (22), p.3531-3543
Main Authors: Schneider, Christoph, Abels, Falko
Format: Article
Language:English
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Summary:Recent progress in the field of catalytic, enantioselective vinylogous Michael reactions of latent dienolates is described which furnish optically highly enriched chiral 1,7-dioxo compounds of great utility in one synthetic operation. Emphasis is given to new catalysis modes which realise this challenging transformation with high regio- as well as enantioselectivity. Recent progress towards catalytic, enantioselective vinylogous Michael reactions is presented which deliver optically highly enriched 1,7-dioxo compounds of great utility in organic synthesis.
ISSN:1477-0520
1477-0539
DOI:10.1039/c4ob00332b