A controlled spatial distribution of functional units in the two dimensional nanospace of layered silicates and titanates

The immobilization of functional units in the interlayer spaces of layered silicates and titanates is summarized from the viewpoint of how the spatial distribution of functional units in the interlayer affects the performance of the intercalation compounds. The ways of incorporating controlled amoun...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2014-07, Vol.43 (27), p.134-1354
Main Authors: Ogawa, Makoto, Saito, Kanji, Sohmiya, Minoru
Format: Article
Language:English
Subjects:
Energy transfer
Intercalation compounds
Interlayers
Nanostructure
Silicates
Spatial distribution
Titanates
Two dimensional
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Summary:The immobilization of functional units in the interlayer spaces of layered silicates and titanates is summarized from the viewpoint of how the spatial distribution of functional units in the interlayer affects the performance of the intercalation compounds. The ways of incorporating controlled amounts of functional units with controlled spatial distribution are also discussed. As a result of controlled spatial distribution of functional units in two-dimensional nanospace, one can achieve improved efficiency of photo-induced events (photoluminescence and photoinduced electron/energy transfer), molecular sieving and substrate/product selective catalytic reactions. The effects of the spatial distribution of functional units in the interlayer space of intercalation compounds are discussed.
ISSN:1477-9226
1477-9234
DOI:10.1039/c4dt00147h