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A controlled spatial distribution of functional units in the two dimensional nanospace of layered silicates and titanates

The immobilization of functional units in the interlayer spaces of layered silicates and titanates is summarized from the viewpoint of how the spatial distribution of functional units in the interlayer affects the performance of the intercalation compounds. The ways of incorporating controlled amoun...

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Published in:Dalton transactions : an international journal of inorganic chemistry 2014-07, Vol.43 (27), p.134-1354
Main Authors: Ogawa, Makoto, Saito, Kanji, Sohmiya, Minoru
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Language:English
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description The immobilization of functional units in the interlayer spaces of layered silicates and titanates is summarized from the viewpoint of how the spatial distribution of functional units in the interlayer affects the performance of the intercalation compounds. The ways of incorporating controlled amounts of functional units with controlled spatial distribution are also discussed. As a result of controlled spatial distribution of functional units in two-dimensional nanospace, one can achieve improved efficiency of photo-induced events (photoluminescence and photoinduced electron/energy transfer), molecular sieving and substrate/product selective catalytic reactions. The effects of the spatial distribution of functional units in the interlayer space of intercalation compounds are discussed.
doi_str_mv 10.1039/c4dt00147h
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source Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)
subjects Energy transfer
Intercalation compounds
Interlayers
Nanostructure
Silicates
Spatial distribution
Titanates
Two dimensional
title A controlled spatial distribution of functional units in the two dimensional nanospace of layered silicates and titanates
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