Deuteration enhances catalyst lifetime in palladium-catalysed alcohol oxidation

The catalyst palladium/2,9-CD 3 -phenanthroline has a 1.8 times higher turnover number than its non-deuterated counterpart in the aerobic alcohol oxidation of methyl glucoside and allows the regioselective oxidation with dioxygen as the terminal oxidant. The catalyst palladium/2,9-CD 3 -phenanthroli...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (1), p.2189-2191
Main Authors: Armenise, Nicola, Tahiri, Nabil, Eisink, Niek N. H. M, Denis, Mathieu, Jäger, Manuel, De Vries, Johannes G, Witte, Martin D, Minnaard, Adriaan J
Format: Article
Language:English
Subjects:
Alcohols
Catalysts
Deuteration
Oxidants
Oxidation
Oxidizing agents
Palladium
Terminals
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Summary:The catalyst palladium/2,9-CD 3 -phenanthroline has a 1.8 times higher turnover number than its non-deuterated counterpart in the aerobic alcohol oxidation of methyl glucoside and allows the regioselective oxidation with dioxygen as the terminal oxidant. The catalyst palladium/2,9-CD 3 -phenanthroline has a 1.8 times higher turnover number than its non-deuterated counterpart in the aerobic alcohol oxidation of methyl glucoside and allows the regioselective oxidation with dioxygen as the terminal oxidant.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc08588h