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Engineering an iridium-containing metal-organic molecular capsule for induced-fit geometrical conversion and dual catalysis
By introducing photoactive fac -tris(2-phenylpyridine)iridium moieties as a ligand backbone to constrain the coordination geometry of cobalt ions, a multifunctional Ir 2 Co 3 -type capsule was achieved and showed induced-fit capsule-capsule conversion by cooperative binding one carbonate anion with...
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| Published in: | Chemical communications (Cambridge, England) England), 2016-08, Vol.52 (62), p.9628-9631 |
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| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c408t-357fb94a5db51a95a1379f3a32c577bc235404e1cc7ab9adab8a6bd8489916ea3 |
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| cites | cdi_FETCH-LOGICAL-c408t-357fb94a5db51a95a1379f3a32c577bc235404e1cc7ab9adab8a6bd8489916ea3 |
| container_end_page | 9631 |
| container_issue | 62 |
| container_start_page | 9628 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 52 |
| creator | Li, Xuezhao Wu, Jinguo Chen, Liyong Zhong, Xiaoming He, Cheng Zhang, Rong Duan, Chunying |
| description | By introducing photoactive
fac
-tris(2-phenylpyridine)iridium moieties as a ligand backbone to constrain the coordination geometry of cobalt ions, a multifunctional Ir
2
Co
3
-type capsule was achieved and showed induced-fit capsule-capsule conversion by cooperative binding one carbonate anion with the equatorial Co(
ii
) centers. The capsule combined photocatalysis and transition metal activation synergistically and exhibited efficient catalytic ability on visible light-activated α-trichloromethylation.
Quantitative dynamic capsule-capsule conversion by cooperative binding one carbonate anion and switchable dual catalysis was achieved within an Ir
2
Co
3
-type capsule. |
| doi_str_mv | 10.1039/c6cc04647a |
| format | article |
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fac
-tris(2-phenylpyridine)iridium moieties as a ligand backbone to constrain the coordination geometry of cobalt ions, a multifunctional Ir
2
Co
3
-type capsule was achieved and showed induced-fit capsule-capsule conversion by cooperative binding one carbonate anion with the equatorial Co(
ii
) centers. The capsule combined photocatalysis and transition metal activation synergistically and exhibited efficient catalytic ability on visible light-activated α-trichloromethylation.
Quantitative dynamic capsule-capsule conversion by cooperative binding one carbonate anion and switchable dual catalysis was achieved within an Ir
2
Co
3
-type capsule.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c6cc04647a</identifier><identifier>PMID: 27320443</identifier><language>eng</language><publisher>England</publisher><subject>Activation ; Binding ; Carbonates ; Catalysis ; Cobalt ; Conversion ; Ligands ; Transition metals</subject><ispartof>Chemical communications (Cambridge, England), 2016-08, Vol.52 (62), p.9628-9631</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c408t-357fb94a5db51a95a1379f3a32c577bc235404e1cc7ab9adab8a6bd8489916ea3</citedby><cites>FETCH-LOGICAL-c408t-357fb94a5db51a95a1379f3a32c577bc235404e1cc7ab9adab8a6bd8489916ea3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27320443$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Xuezhao</creatorcontrib><creatorcontrib>Wu, Jinguo</creatorcontrib><creatorcontrib>Chen, Liyong</creatorcontrib><creatorcontrib>Zhong, Xiaoming</creatorcontrib><creatorcontrib>He, Cheng</creatorcontrib><creatorcontrib>Zhang, Rong</creatorcontrib><creatorcontrib>Duan, Chunying</creatorcontrib><title>Engineering an iridium-containing metal-organic molecular capsule for induced-fit geometrical conversion and dual catalysis</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>By introducing photoactive
fac
-tris(2-phenylpyridine)iridium moieties as a ligand backbone to constrain the coordination geometry of cobalt ions, a multifunctional Ir
2
Co
3
-type capsule was achieved and showed induced-fit capsule-capsule conversion by cooperative binding one carbonate anion with the equatorial Co(
ii
) centers. The capsule combined photocatalysis and transition metal activation synergistically and exhibited efficient catalytic ability on visible light-activated α-trichloromethylation.
Quantitative dynamic capsule-capsule conversion by cooperative binding one carbonate anion and switchable dual catalysis was achieved within an Ir
2
Co
3
-type capsule.</description><subject>Activation</subject><subject>Binding</subject><subject>Carbonates</subject><subject>Catalysis</subject><subject>Cobalt</subject><subject>Conversion</subject><subject>Ligands</subject><subject>Transition metals</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkT1r3TAUhkVpyVezdE_QGAJuJEuyrDGY9AMCXRLIZo6P5IuKLd1IdiHkz0e3N03GnkWHV4-eQS8hXzj7ypkwV9ggMtlIDR_IEReNrJRsHz7udmUqLaQ6JMc5_2ZluGoPyGGtRc2kFEfk-SZsfHAu-bChEKhP3vp1rjCGBXzYpbNbYKpi2kDwSOc4OVwnSBRhm9fJ0TEm6oNd0dlq9AvduFieJI8w0aL541L2MRS5pXbdZVB8T9nnz-TTCFN2p6_nCbn_dnPX_ahuf33_2V3fVihZu1RC6XEwEpQdFAejgAttRgGiRqX1gLVQkknHETUMBiwMLTSDbWVrDG8ciBNysfduU3xcXV762Wd00wTBxTX3vBVKqVaWX_k_ynStjdSioJd7FFPMObmx3yY_Q3rqOet3vfRd03V_e7ku8Pmrdx1mZ9_Qf0UU4GwPpIxvt-_FihemeZSJ</recordid><startdate>20160811</startdate><enddate>20160811</enddate><creator>Li, Xuezhao</creator><creator>Wu, Jinguo</creator><creator>Chen, Liyong</creator><creator>Zhong, Xiaoming</creator><creator>He, Cheng</creator><creator>Zhang, Rong</creator><creator>Duan, Chunying</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160811</creationdate><title>Engineering an iridium-containing metal-organic molecular capsule for induced-fit geometrical conversion and dual catalysis</title><author>Li, Xuezhao ; Wu, Jinguo ; Chen, Liyong ; Zhong, Xiaoming ; He, Cheng ; Zhang, Rong ; Duan, Chunying</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c408t-357fb94a5db51a95a1379f3a32c577bc235404e1cc7ab9adab8a6bd8489916ea3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Activation</topic><topic>Binding</topic><topic>Carbonates</topic><topic>Catalysis</topic><topic>Cobalt</topic><topic>Conversion</topic><topic>Ligands</topic><topic>Transition metals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Xuezhao</creatorcontrib><creatorcontrib>Wu, Jinguo</creatorcontrib><creatorcontrib>Chen, Liyong</creatorcontrib><creatorcontrib>Zhong, Xiaoming</creatorcontrib><creatorcontrib>He, Cheng</creatorcontrib><creatorcontrib>Zhang, Rong</creatorcontrib><creatorcontrib>Duan, Chunying</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Xuezhao</au><au>Wu, Jinguo</au><au>Chen, Liyong</au><au>Zhong, Xiaoming</au><au>He, Cheng</au><au>Zhang, Rong</au><au>Duan, Chunying</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Engineering an iridium-containing metal-organic molecular capsule for induced-fit geometrical conversion and dual catalysis</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2016-08-11</date><risdate>2016</risdate><volume>52</volume><issue>62</issue><spage>9628</spage><epage>9631</epage><pages>9628-9631</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>By introducing photoactive
fac
-tris(2-phenylpyridine)iridium moieties as a ligand backbone to constrain the coordination geometry of cobalt ions, a multifunctional Ir
2
Co
3
-type capsule was achieved and showed induced-fit capsule-capsule conversion by cooperative binding one carbonate anion with the equatorial Co(
ii
) centers. The capsule combined photocatalysis and transition metal activation synergistically and exhibited efficient catalytic ability on visible light-activated α-trichloromethylation.
Quantitative dynamic capsule-capsule conversion by cooperative binding one carbonate anion and switchable dual catalysis was achieved within an Ir
2
Co
3
-type capsule.</abstract><cop>England</cop><pmid>27320443</pmid><doi>10.1039/c6cc04647a</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2016-08, Vol.52 (62), p.9628-9631 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_pubmed_primary_27320443 |
| source | Royal Society of Chemistry |
| subjects | Activation Binding Carbonates Catalysis Cobalt Conversion Ligands Transition metals |
| title | Engineering an iridium-containing metal-organic molecular capsule for induced-fit geometrical conversion and dual catalysis |
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