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Metal-organic frameworks for electronics: emerging second order nonlinear optical and dielectric materials
Metal-organic frameworks (MOFs) have been intensively studied over the past decade because they represent a new category of hybrid inorganic-organic materials with extensive surface areas, ultrahigh porosity, along with the extraordinary tailorability of structure, shape and dimensions. In this high...
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Published in: | Science and technology of advanced materials 2015-10, Vol.16 (5), p.054204-54210 |
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description | Metal-organic frameworks (MOFs) have been intensively studied over the past decade because they represent a new category of hybrid inorganic-organic materials with extensive surface areas, ultrahigh porosity, along with the extraordinary tailorability of structure, shape and dimensions. In this highlight, we summarize the current state of MOF research and report on structure-property relationships for nonlinear optical (NLO) and dielectric applications. We focus on the design principles and structural elements needed to develop potential NLO and low dielectric (low-κ) MOFs with an emphasis on enhancing material performance. In addition, we highlight experimental evidence for the design of devices for low-dielectric applications. These results motivate us to develop better low-dielectric and NLO materials and to perform in-depth studies related to deposition techniques, patterning and the mechanical performance of these materials in the future. |
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subjects | Categories Deposition dielectric Dielectric properties Dielectrics Electronics Mechanical properties Metal-organic frameworks nonlinear optical Nonlinear optics Nonlinearity Optical properties Organic materials Porosity Structural members Surface area |
title | Metal-organic frameworks for electronics: emerging second order nonlinear optical and dielectric materials |
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