Crystal structure of (6 E ,20 E )-3,24-di-fluoro-13,14,28,29-tetra-hydro-5 H ,22 H -tetra-benzo[ e , j , p , u ][1,4,12,15]tetra-oxa-cyclo-docosine-5,22-dione

The conformation of the title compound, C H F O , is cone-shaped, partially determined by intra-molecular C-H⋯O short contacts. The benzene rings at the top of the cone are inclined to one another by 73.10 (7)°, while the benzene rings at the bottom of the cone are inclined to one another by 35.49 (...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2017-01, Vol.73 (Pt 1), p.13
Main Authors: Mohamed, Shaaban K, Akkurt, Mehmet, Hawaiz, Farouq E, Ayoob, Mzgin M, Hosten, Eric
Format: Article
Language:English
Online Access:Get full text
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Summary:The conformation of the title compound, C H F O , is cone-shaped, partially determined by intra-molecular C-H⋯O short contacts. The benzene rings at the top of the cone are inclined to one another by 73.10 (7)°, while the benzene rings at the bottom of the cone are inclined to one another by 35.49 (8)°. In the crystal, mol-ecules are linked by C-H⋯O and C-H⋯F hydrogen bonds, forming a three-dimensional supra-molecular structure. There are also C-H⋯π contacts present within the framework structure.
ISSN:2056-9890
2056-9890