Crystal structure of (6 E ,20 E )-3,24-di-fluoro-13,14,28,29-tetra-hydro-5 H ,22 H -tetra-benzo[ e , j , p , u ][1,4,12,15]tetra-oxa-cyclo-docosine-5,22-dione

The conformation of the title compound, C H F O , is cone-shaped, partially determined by intra-molecular C-H⋯O short contacts. The benzene rings at the top of the cone are inclined to one another by 73.10 (7)°, while the benzene rings at the bottom of the cone are inclined to one another by 35.49 (...

Full description

Saved in:
Bibliographic Details
Published in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2017-01, Vol.73 (Pt 1), p.13
Main Authors: Mohamed, Shaaban K, Akkurt, Mehmet, Hawaiz, Farouq E, Ayoob, Mzgin M, Hosten, Eric
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page
container_issue Pt 1
container_start_page 13
container_title Acta crystallographica. Section E, Crystallographic communications
container_volume 73
creator Mohamed, Shaaban K
Akkurt, Mehmet
Hawaiz, Farouq E
Ayoob, Mzgin M
Hosten, Eric
description The conformation of the title compound, C H F O , is cone-shaped, partially determined by intra-molecular C-H⋯O short contacts. The benzene rings at the top of the cone are inclined to one another by 73.10 (7)°, while the benzene rings at the bottom of the cone are inclined to one another by 35.49 (8)°. In the crystal, mol-ecules are linked by C-H⋯O and C-H⋯F hydrogen bonds, forming a three-dimensional supra-molecular structure. There are also C-H⋯π contacts present within the framework structure.
format article
fullrecord <record><control><sourceid>pubmed</sourceid><recordid>TN_cdi_pubmed_primary_28083124</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>28083124</sourcerecordid><originalsourceid>FETCH-pubmed_primary_280831243</originalsourceid><addsrcrecordid>eNqFT0FqwzAQFKWhCW2-UPbYghaklWTsc0jJA3oLISi2TBwcy0gW1H1M31pBU-ith5kdhtld5o6tSJgCq7IS93_0kq1jvAghpDaqMPTAllSKUknSK_a1CXOcbA9xCqmeUnDgW3gpYAucROZXVJw0Nh22ffLBo1Rcak4lpwonNwWL57nJvoFdXqHMN_vkhk-_BwccLhljRoLDXnLNJXFpDj8x_2GxnuveY-NrH7vBocl38kc_uCe2aG0f3fo2H9nz2_Z9s8Mxna6uOY6hu9owH38LqX8D3zjqUIw</addsrcrecordid><sourcetype>Index Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Crystal structure of (6 E ,20 E )-3,24-di-fluoro-13,14,28,29-tetra-hydro-5 H ,22 H -tetra-benzo[ e , j , p , u ][1,4,12,15]tetra-oxa-cyclo-docosine-5,22-dione</title><source>PubMed (Medline)</source><source>IngentaConnect Journals</source><creator>Mohamed, Shaaban K ; Akkurt, Mehmet ; Hawaiz, Farouq E ; Ayoob, Mzgin M ; Hosten, Eric</creator><creatorcontrib>Mohamed, Shaaban K ; Akkurt, Mehmet ; Hawaiz, Farouq E ; Ayoob, Mzgin M ; Hosten, Eric</creatorcontrib><description>The conformation of the title compound, C H F O , is cone-shaped, partially determined by intra-molecular C-H⋯O short contacts. The benzene rings at the top of the cone are inclined to one another by 73.10 (7)°, while the benzene rings at the bottom of the cone are inclined to one another by 35.49 (8)°. In the crystal, mol-ecules are linked by C-H⋯O and C-H⋯F hydrogen bonds, forming a three-dimensional supra-molecular structure. There are also C-H⋯π contacts present within the framework structure.</description><identifier>ISSN: 2056-9890</identifier><identifier>EISSN: 2056-9890</identifier><identifier>PMID: 28083124</identifier><language>eng</language><publisher>England</publisher><ispartof>Acta crystallographica. Section E, Crystallographic communications, 2017-01, Vol.73 (Pt 1), p.13</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28083124$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Mohamed, Shaaban K</creatorcontrib><creatorcontrib>Akkurt, Mehmet</creatorcontrib><creatorcontrib>Hawaiz, Farouq E</creatorcontrib><creatorcontrib>Ayoob, Mzgin M</creatorcontrib><creatorcontrib>Hosten, Eric</creatorcontrib><title>Crystal structure of (6 E ,20 E )-3,24-di-fluoro-13,14,28,29-tetra-hydro-5 H ,22 H -tetra-benzo[ e , j , p , u ][1,4,12,15]tetra-oxa-cyclo-docosine-5,22-dione</title><title>Acta crystallographica. Section E, Crystallographic communications</title><addtitle>Acta Crystallogr E Crystallogr Commun</addtitle><description>The conformation of the title compound, C H F O , is cone-shaped, partially determined by intra-molecular C-H⋯O short contacts. The benzene rings at the top of the cone are inclined to one another by 73.10 (7)°, while the benzene rings at the bottom of the cone are inclined to one another by 35.49 (8)°. In the crystal, mol-ecules are linked by C-H⋯O and C-H⋯F hydrogen bonds, forming a three-dimensional supra-molecular structure. There are also C-H⋯π contacts present within the framework structure.</description><issn>2056-9890</issn><issn>2056-9890</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqFT0FqwzAQFKWhCW2-UPbYghaklWTsc0jJA3oLISi2TBwcy0gW1H1M31pBU-ith5kdhtld5o6tSJgCq7IS93_0kq1jvAghpDaqMPTAllSKUknSK_a1CXOcbA9xCqmeUnDgW3gpYAucROZXVJw0Nh22ffLBo1Rcak4lpwonNwWL57nJvoFdXqHMN_vkhk-_BwccLhljRoLDXnLNJXFpDj8x_2GxnuveY-NrH7vBocl38kc_uCe2aG0f3fo2H9nz2_Z9s8Mxna6uOY6hu9owH38LqX8D3zjqUIw</recordid><startdate>20170101</startdate><enddate>20170101</enddate><creator>Mohamed, Shaaban K</creator><creator>Akkurt, Mehmet</creator><creator>Hawaiz, Farouq E</creator><creator>Ayoob, Mzgin M</creator><creator>Hosten, Eric</creator><scope>NPM</scope></search><sort><creationdate>20170101</creationdate><title>Crystal structure of (6 E ,20 E )-3,24-di-fluoro-13,14,28,29-tetra-hydro-5 H ,22 H -tetra-benzo[ e , j , p , u ][1,4,12,15]tetra-oxa-cyclo-docosine-5,22-dione</title><author>Mohamed, Shaaban K ; Akkurt, Mehmet ; Hawaiz, Farouq E ; Ayoob, Mzgin M ; Hosten, Eric</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-pubmed_primary_280831243</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mohamed, Shaaban K</creatorcontrib><creatorcontrib>Akkurt, Mehmet</creatorcontrib><creatorcontrib>Hawaiz, Farouq E</creatorcontrib><creatorcontrib>Ayoob, Mzgin M</creatorcontrib><creatorcontrib>Hosten, Eric</creatorcontrib><collection>PubMed</collection><jtitle>Acta crystallographica. Section E, Crystallographic communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mohamed, Shaaban K</au><au>Akkurt, Mehmet</au><au>Hawaiz, Farouq E</au><au>Ayoob, Mzgin M</au><au>Hosten, Eric</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal structure of (6 E ,20 E )-3,24-di-fluoro-13,14,28,29-tetra-hydro-5 H ,22 H -tetra-benzo[ e , j , p , u ][1,4,12,15]tetra-oxa-cyclo-docosine-5,22-dione</atitle><jtitle>Acta crystallographica. Section E, Crystallographic communications</jtitle><addtitle>Acta Crystallogr E Crystallogr Commun</addtitle><date>2017-01-01</date><risdate>2017</risdate><volume>73</volume><issue>Pt 1</issue><spage>13</spage><pages>13-</pages><issn>2056-9890</issn><eissn>2056-9890</eissn><abstract>The conformation of the title compound, C H F O , is cone-shaped, partially determined by intra-molecular C-H⋯O short contacts. The benzene rings at the top of the cone are inclined to one another by 73.10 (7)°, while the benzene rings at the bottom of the cone are inclined to one another by 35.49 (8)°. In the crystal, mol-ecules are linked by C-H⋯O and C-H⋯F hydrogen bonds, forming a three-dimensional supra-molecular structure. There are also C-H⋯π contacts present within the framework structure.</abstract><cop>England</cop><pmid>28083124</pmid></addata></record>
fulltext fulltext
identifier ISSN: 2056-9890
ispartof Acta crystallographica. Section E, Crystallographic communications, 2017-01, Vol.73 (Pt 1), p.13
issn 2056-9890
2056-9890
language eng
recordid cdi_pubmed_primary_28083124
source PubMed (Medline); IngentaConnect Journals
title Crystal structure of (6 E ,20 E )-3,24-di-fluoro-13,14,28,29-tetra-hydro-5 H ,22 H -tetra-benzo[ e , j , p , u ][1,4,12,15]tetra-oxa-cyclo-docosine-5,22-dione
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T15%3A12%3A11IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmed&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Crystal%20structure%20of%20(6%20E%20,20%20E%20)-3,24-di-fluoro-13,14,28,29-tetra-hydro-5%20H%20,22%20H%20-tetra-benzo%5B%20e%20,%20j%20,%20p%20,%20u%20%5D%5B1,4,12,15%5Dtetra-oxa-cyclo-docosine-5,22-dione&rft.jtitle=Acta%20crystallographica.%20Section%20E,%20Crystallographic%20communications&rft.au=Mohamed,%20Shaaban%20K&rft.date=2017-01-01&rft.volume=73&rft.issue=Pt%201&rft.spage=13&rft.pages=13-&rft.issn=2056-9890&rft.eissn=2056-9890&rft_id=info:doi/&rft_dat=%3Cpubmed%3E28083124%3C/pubmed%3E%3Cgrp_id%3Ecdi_FETCH-pubmed_primary_280831243%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/28083124&rfr_iscdi=true