Piezoelectric Ceramics of the (1 - x)Bi 0.50 Na 0.50 TiO₃-xBa 0.90 Ca 0.10 TiO₃ Lead-Free Solid Solution: Chemical Shift of the Morphotropic Phase Boundary, a Case Study for x = 0.06

Research and development of lead-free piezoelectric materials are still the hottest topics in the field of piezoelectricity. One of the most promising lead-free family of compounds to replace lead zirconate-titanate for actuators is that of Bi Na TiO₃ (BNT) based solid solutions. The pseudo-binary (...

Full description

Saved in:
Bibliographic Details
Published in:Materials 2017-07, Vol.10 (7)
Main Authors: Vivar-Ocampo, Rodrigo, Pardo, Lorena, Ávila, David, Morán, Emilio, González, Amador M, Bucio, Lauro, Villafuerte-Castrejón, María-Elena
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page
container_issue 7
container_start_page
container_title Materials
container_volume 10
creator Vivar-Ocampo, Rodrigo
Pardo, Lorena
Ávila, David
Morán, Emilio
González, Amador M
Bucio, Lauro
Villafuerte-Castrejón, María-Elena
description Research and development of lead-free piezoelectric materials are still the hottest topics in the field of piezoelectricity. One of the most promising lead-free family of compounds to replace lead zirconate-titanate for actuators is that of Bi Na TiO₃ (BNT) based solid solutions. The pseudo-binary (1 - )Bi Na TiO₃- Ba Ca TiO₃ system has been proposed for high temperature capacitors and not yet fully explored as piezoelectric material. In this work, the solid solution with = 0.06 and = 0.10 was obtained by two different synthesis routes: solid state and Pechini, aiming at using reduced temperatures, both in synthesis (
format article
fullrecord <record><control><sourceid>pubmed</sourceid><recordid>TN_cdi_pubmed_primary_28773096</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>28773096</sourcerecordid><originalsourceid>FETCH-pubmed_primary_287730963</originalsourceid><addsrcrecordid>eNqFT8FKw0AQXUSxpfYXZI4Kruw2Ne0KXhIsHqwW0ntZkwm7knTD7gZSj_pXfo5f4gYNeHMO8948hvdmjsiYCxFTLubz4z98RKbOvbJQUcSXM3FKRrPlYhExEY_J50bjm8EKc291DilaWevcgSnBK4QLDhS6y0QDu75h8CR_cKufv94_aJf0s2CQ9sgHHR5RFnRlESEzlS763npt9reQKgz2soJM6dIPKWtjG2W8NU04YaOkQ0hMuy-kPVyBDO5ByHxbHKA0Fjq4C2ksPiMnpawcTn9xQs5X99v0gTbtS43FrrG6Dg674dno34VvVFxeYQ</addsrcrecordid><sourcetype>Index Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Piezoelectric Ceramics of the (1 - x)Bi 0.50 Na 0.50 TiO₃-xBa 0.90 Ca 0.10 TiO₃ Lead-Free Solid Solution: Chemical Shift of the Morphotropic Phase Boundary, a Case Study for x = 0.06</title><source>Publicly Available Content Database</source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><creator>Vivar-Ocampo, Rodrigo ; Pardo, Lorena ; Ávila, David ; Morán, Emilio ; González, Amador M ; Bucio, Lauro ; Villafuerte-Castrejón, María-Elena</creator><creatorcontrib>Vivar-Ocampo, Rodrigo ; Pardo, Lorena ; Ávila, David ; Morán, Emilio ; González, Amador M ; Bucio, Lauro ; Villafuerte-Castrejón, María-Elena</creatorcontrib><description>Research and development of lead-free piezoelectric materials are still the hottest topics in the field of piezoelectricity. One of the most promising lead-free family of compounds to replace lead zirconate-titanate for actuators is that of Bi Na TiO₃ (BNT) based solid solutions. The pseudo-binary (1 - )Bi Na TiO₃- Ba Ca TiO₃ system has been proposed for high temperature capacitors and not yet fully explored as piezoelectric material. In this work, the solid solution with = 0.06 and = 0.10 was obtained by two different synthesis routes: solid state and Pechini, aiming at using reduced temperatures, both in synthesis (&lt;800 °C) and sintering (&lt;1150 °C), while maintaining appropriated piezoelectric performance. Crystal structure, ceramic grain size, and morphology depend on the synthesis route and were analyzed by X-ray diffraction, together with scanning and transmission electron microscopy. The effects of processing and ceramic microstructure on the structural, dielectric, ferroelectric, and piezoelectric properties were discussed in terms of a shift of the Morphotropic Phase Boundary, chemically induced by the synthesis route.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>PMID: 28773096</identifier><language>eng</language><publisher>Switzerland</publisher><ispartof>Materials, 2017-07, Vol.10 (7)</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28773096$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Vivar-Ocampo, Rodrigo</creatorcontrib><creatorcontrib>Pardo, Lorena</creatorcontrib><creatorcontrib>Ávila, David</creatorcontrib><creatorcontrib>Morán, Emilio</creatorcontrib><creatorcontrib>González, Amador M</creatorcontrib><creatorcontrib>Bucio, Lauro</creatorcontrib><creatorcontrib>Villafuerte-Castrejón, María-Elena</creatorcontrib><title>Piezoelectric Ceramics of the (1 - x)Bi 0.50 Na 0.50 TiO₃-xBa 0.90 Ca 0.10 TiO₃ Lead-Free Solid Solution: Chemical Shift of the Morphotropic Phase Boundary, a Case Study for x = 0.06</title><title>Materials</title><addtitle>Materials (Basel)</addtitle><description>Research and development of lead-free piezoelectric materials are still the hottest topics in the field of piezoelectricity. One of the most promising lead-free family of compounds to replace lead zirconate-titanate for actuators is that of Bi Na TiO₃ (BNT) based solid solutions. The pseudo-binary (1 - )Bi Na TiO₃- Ba Ca TiO₃ system has been proposed for high temperature capacitors and not yet fully explored as piezoelectric material. In this work, the solid solution with = 0.06 and = 0.10 was obtained by two different synthesis routes: solid state and Pechini, aiming at using reduced temperatures, both in synthesis (&lt;800 °C) and sintering (&lt;1150 °C), while maintaining appropriated piezoelectric performance. Crystal structure, ceramic grain size, and morphology depend on the synthesis route and were analyzed by X-ray diffraction, together with scanning and transmission electron microscopy. The effects of processing and ceramic microstructure on the structural, dielectric, ferroelectric, and piezoelectric properties were discussed in terms of a shift of the Morphotropic Phase Boundary, chemically induced by the synthesis route.</description><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqFT8FKw0AQXUSxpfYXZI4Kruw2Ne0KXhIsHqwW0ntZkwm7knTD7gZSj_pXfo5f4gYNeHMO8948hvdmjsiYCxFTLubz4z98RKbOvbJQUcSXM3FKRrPlYhExEY_J50bjm8EKc291DilaWevcgSnBK4QLDhS6y0QDu75h8CR_cKufv94_aJf0s2CQ9sgHHR5RFnRlESEzlS763npt9reQKgz2soJM6dIPKWtjG2W8NU04YaOkQ0hMuy-kPVyBDO5ByHxbHKA0Fjq4C2ksPiMnpawcTn9xQs5X99v0gTbtS43FrrG6Dg674dno34VvVFxeYQ</recordid><startdate>20170701</startdate><enddate>20170701</enddate><creator>Vivar-Ocampo, Rodrigo</creator><creator>Pardo, Lorena</creator><creator>Ávila, David</creator><creator>Morán, Emilio</creator><creator>González, Amador M</creator><creator>Bucio, Lauro</creator><creator>Villafuerte-Castrejón, María-Elena</creator><scope>NPM</scope></search><sort><creationdate>20170701</creationdate><title>Piezoelectric Ceramics of the (1 - x)Bi 0.50 Na 0.50 TiO₃-xBa 0.90 Ca 0.10 TiO₃ Lead-Free Solid Solution: Chemical Shift of the Morphotropic Phase Boundary, a Case Study for x = 0.06</title><author>Vivar-Ocampo, Rodrigo ; Pardo, Lorena ; Ávila, David ; Morán, Emilio ; González, Amador M ; Bucio, Lauro ; Villafuerte-Castrejón, María-Elena</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-pubmed_primary_287730963</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vivar-Ocampo, Rodrigo</creatorcontrib><creatorcontrib>Pardo, Lorena</creatorcontrib><creatorcontrib>Ávila, David</creatorcontrib><creatorcontrib>Morán, Emilio</creatorcontrib><creatorcontrib>González, Amador M</creatorcontrib><creatorcontrib>Bucio, Lauro</creatorcontrib><creatorcontrib>Villafuerte-Castrejón, María-Elena</creatorcontrib><collection>PubMed</collection><jtitle>Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vivar-Ocampo, Rodrigo</au><au>Pardo, Lorena</au><au>Ávila, David</au><au>Morán, Emilio</au><au>González, Amador M</au><au>Bucio, Lauro</au><au>Villafuerte-Castrejón, María-Elena</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Piezoelectric Ceramics of the (1 - x)Bi 0.50 Na 0.50 TiO₃-xBa 0.90 Ca 0.10 TiO₃ Lead-Free Solid Solution: Chemical Shift of the Morphotropic Phase Boundary, a Case Study for x = 0.06</atitle><jtitle>Materials</jtitle><addtitle>Materials (Basel)</addtitle><date>2017-07-01</date><risdate>2017</risdate><volume>10</volume><issue>7</issue><issn>1996-1944</issn><eissn>1996-1944</eissn><abstract>Research and development of lead-free piezoelectric materials are still the hottest topics in the field of piezoelectricity. One of the most promising lead-free family of compounds to replace lead zirconate-titanate for actuators is that of Bi Na TiO₃ (BNT) based solid solutions. The pseudo-binary (1 - )Bi Na TiO₃- Ba Ca TiO₃ system has been proposed for high temperature capacitors and not yet fully explored as piezoelectric material. In this work, the solid solution with = 0.06 and = 0.10 was obtained by two different synthesis routes: solid state and Pechini, aiming at using reduced temperatures, both in synthesis (&lt;800 °C) and sintering (&lt;1150 °C), while maintaining appropriated piezoelectric performance. Crystal structure, ceramic grain size, and morphology depend on the synthesis route and were analyzed by X-ray diffraction, together with scanning and transmission electron microscopy. The effects of processing and ceramic microstructure on the structural, dielectric, ferroelectric, and piezoelectric properties were discussed in terms of a shift of the Morphotropic Phase Boundary, chemically induced by the synthesis route.</abstract><cop>Switzerland</cop><pmid>28773096</pmid></addata></record>
fulltext fulltext
identifier ISSN: 1996-1944
ispartof Materials, 2017-07, Vol.10 (7)
issn 1996-1944
1996-1944
language eng
recordid cdi_pubmed_primary_28773096
source Publicly Available Content Database; PubMed Central; Free Full-Text Journals in Chemistry
title Piezoelectric Ceramics of the (1 - x)Bi 0.50 Na 0.50 TiO₃-xBa 0.90 Ca 0.10 TiO₃ Lead-Free Solid Solution: Chemical Shift of the Morphotropic Phase Boundary, a Case Study for x = 0.06
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T18%3A24%3A02IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmed&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Piezoelectric%20Ceramics%20of%20the%20(1%20-%20x)Bi%200.50%20Na%200.50%20TiO%E2%82%83-xBa%200.90%20Ca%200.10%20TiO%E2%82%83%20Lead-Free%20Solid%20Solution:%20Chemical%20Shift%20of%20the%20Morphotropic%20Phase%20Boundary,%20a%20Case%20Study%20for%20x%20=%200.06&rft.jtitle=Materials&rft.au=Vivar-Ocampo,%20Rodrigo&rft.date=2017-07-01&rft.volume=10&rft.issue=7&rft.issn=1996-1944&rft.eissn=1996-1944&rft_id=info:doi/&rft_dat=%3Cpubmed%3E28773096%3C/pubmed%3E%3Cgrp_id%3Ecdi_FETCH-pubmed_primary_287730963%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/28773096&rfr_iscdi=true