Constituting fully integrated colorimetric analysis system for Fe(III) on multifunctional nitrogen-doped MoO 3 /cellulose paper

• Published in: Talanta (Oxford) 2018-04, Vol.180, p.352
• Main Authors: Lin, Fan, Cai, Jiabai, Li, Yuehai, Yu, Huiwu, Li, Shunxing
• Format: Article
• Language: English
• ISSN: 1873-3573

Using ammonium molybdate and thiourea as precursors, nitrogen-doped MoO was produced by a one-step carbonization and then fixed into the cellulose filter paper (NMCP) with acrylic resin as a fixative. NMCP was designed as a multifunctional nanocomposite, i.e., solid phase adsorbent for Fe(III) preconcentration, photocatalyst for iron species transformation and color interference removal, and colorimetric sensor for Fe(III) determination. After photocatalysis, the complex of Fe-humic substances could be transformed into Fe(III) ions, the interference of colored organic matter (e.g., aqueous humic substance) was removed, Fe(III) was enriched selectively onto NMCP with the coexistence of interference metal ions (e.g. Co(II) and Cd(II)) and then transformed into Fe(II) by hydroxylamine and photoreduction and for colorimetric analysis. The obstacle of o-phenanthroline colorimetric method was overcome. The photodegradation activity of MoO was improved 2.02 times by nitrogen doping with the optimal mass ratio, which was also 5.11 times of P25-TiO . The concentration of Fe(III) on NMCP was quantified by the gray-scale using smart phones and image processing software, without complicated equipment. Based on multifunctional NMCP, a fully integrated visual analysis system was proposed and suitable for the field detection of Fe(III) in natural water. The log-linear calibration curve for Fe(III) was in the range of 0.05-5mg/L with a determination coefficient (R ) of 0.976 and detection limit of 15μg/L.