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Phase diversity in an adsorption model of an additive binary gas mixture for all sets of lateral interactions

Complete analysis of phase behavior of an adsorption model of a binary gas mixture on a square lattice was carried out for all possible sets of lateral interactions between nearest adsorbed molecules of the same type and no interaction between adsorbed molecules of different types. The model was com...

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Bibliographic Details
Published in:Physical chemistry chemical physics : PCCP 2018, Vol.2 (15), p.1359-1368
Main Authors: Fefelov, V. F, Myshlyavtsev, A. V, Myshlyavtseva, M. D
Format: Article
Language:English
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Summary:Complete analysis of phase behavior of an adsorption model of a binary gas mixture on a square lattice was carried out for all possible sets of lateral interactions between nearest adsorbed molecules of the same type and no interaction between adsorbed molecules of different types. The model was completely investigated in the ground state, and it was shown that the phase behavior of the system is conserved at finite temperatures by means of a transfer matrix method. Complete analysis of phase behavior of an adsorption model of a binary gas mixture on a square lattice was carried out for all possible sets of lateral interactions between nearest adsorbed molecules of the same type and no interaction between adsorbed molecules of different types.
ISSN:1463-9076
1463-9084
DOI:10.1039/c7cp08426a