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Comparison of the benzene sorption properties of metal organic frameworks: influence of the textural properties
The adsorption of benzene by CuBTC and MIL101(Cr) is investigated. The differences between both materials are discussed in terms of porous volume and affinities, determined by calculating Henry's constants and by measuring the adsorption enthalpies. If MIL101(Cr) adsorbs higher quantities of be...
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Published in: | Environmental science--processes & impacts 2019-03, Vol.21 (3), p.47-412 |
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Main Authors: | , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | The adsorption of benzene by CuBTC and MIL101(Cr) is investigated. The differences between both materials are discussed in terms of porous volume and affinities, determined by calculating Henry's constants and by measuring the adsorption enthalpies. If MIL101(Cr) adsorbs higher quantities of benzene, CuBTC develops stronger interaction, interesting for VOC remediation.
CuBTC exhibits stronger interaction with benzene as compared to MIL-101. It should be preferred for benzene remediation. |
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ISSN: | 2050-7887 2050-7895 |
DOI: | 10.1039/c8em00481a |