Comparison of the benzene sorption properties of metal organic frameworks: influence of the textural properties

The adsorption of benzene by CuBTC and MIL101(Cr) is investigated. The differences between both materials are discussed in terms of porous volume and affinities, determined by calculating Henry's constants and by measuring the adsorption enthalpies. If MIL101(Cr) adsorbs higher quantities of be...

Full description

Saved in:
Bibliographic Details
Published in:Environmental science--processes & impacts 2019-03, Vol.21 (3), p.47-412
Main Authors: Belarbi, Hichem, Gonzales, Philippe, Basta, Altaf, Trens, Philippe
Format: Article
Language:English
Subjects:
Adsorption
Air Pollutants - analysis
Air Pollutants - chemistry
Benzene
Benzene - analysis
Benzene - chemistry
Chemical Sciences
Chromium
Enthalpy
Hydrocarbons
Kinetics
Metal-organic frameworks
Metal-Organic Frameworks - chemistry
Models, Theoretical
Surface Properties
Thermodynamics
VOCs
Volatile organic compounds
Volatile Organic Compounds - analysis
Volatile Organic Compounds - chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The adsorption of benzene by CuBTC and MIL101(Cr) is investigated. The differences between both materials are discussed in terms of porous volume and affinities, determined by calculating Henry's constants and by measuring the adsorption enthalpies. If MIL101(Cr) adsorbs higher quantities of benzene, CuBTC develops stronger interaction, interesting for VOC remediation. CuBTC exhibits stronger interaction with benzene as compared to MIL-101. It should be preferred for benzene remediation.
ISSN:2050-7887
2050-7895
DOI:10.1039/c8em00481a