Kinetic study of dye removal using TiO 2 supported on polyethylene terephthalate by advanced oxidation processes through neural networks

• Published in: Water science and technology 2019-03, Vol.79 (6), p.1134
• Main Authors: Barbosa, Ada Azevedo, de Aquino, Ramon Vinicius Santos, da Cruz Santana Neves, Naiana Santos, Dantas, Renato Falcão, Duarte, Marta Maria Menezes Bezerra, Rossiter Sá da Rocha, Otidene
• Format: Article
• Language: English
• Subjects: Catalysis; Coloring Agents - analysis; Coloring Agents - chemistry; Hydrogen Peroxide; Kinetics; Models, Chemical; Neural Networks, Computer; Oxidation-Reduction; Polyethylene Terephthalates - chemistry; Titanium; Ultraviolet Rays; Water Pollutants, Chemical - analysis; Water Pollutants, Chemical - chemistry; Water Purification - methods
• ISSN: 0273-1223
• DOI: 10.2166/wst.2019.111

This work investigated the efficiency of polyethylene terephthalate (PET) as support material for TiO films in the photocatalytic degradation of red Bordeaux and yellow tartrazine dyes. The optimum operating conditions were determined by a factorial design, which resulted after 180 min of treatment in degradations of 99.5% and 99.1% for the UVC/H O /TiO and solar/H O /TiO systems, respectively. For the kinetic study, the experimental data fitted to the pseudo-first-order model and the calculated kinetic constants (k) values were 0.03 min for the UVC/H O /TiO system and 0.0213 min for the system solar/H O /TiO . It was verified that TiO supported in the PET remained with high degradation efficiency even after five cycles of reuse, indicating a good stability of the photocatalyst in the support. A significant reduction of TOC content was also observed along the reaction time. The phytotoxicity bioassay with Lactuca sativa demonstrated that after treatment with UVC/H O /TiO and solar/H O /TiO , an increase in IC50 and consequently lower toxicity was observed.