Selenoamides modulate dipole-dipole interactions in hydrogen bonded supramolecular polymers of 1,3,5-substituted benzenes

We report the synthesis and self-assembly behavior of a chiral C 3 -symmetrical benzene-tricarboselenoamide. The introduction of the selenoamide moiety enhances the dipolar character of the supramolecular interaction and confers a remarkable thermal stability to the supramolecular polymers obtained....

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2019-12, Vol.55 (99), p.1496-1499
Main Authors: Berrocal, José Augusto, Mabesoone, Mathijs F. J, García Iglesias, Miguel, Huizinga, Alex, Meijer, E. W, Palmans, Anja R. A
Format: Article
Language:English
Subjects:
Benzene
Dipole interactions
Self-assembly
Supramolecular polymers
Synthesis
Temperature dependence
Thermal stability
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Summary:We report the synthesis and self-assembly behavior of a chiral C 3 -symmetrical benzene-tricarboselenoamide. The introduction of the selenoamide moiety enhances the dipolar character of the supramolecular interaction and confers a remarkable thermal stability to the supramolecular polymers obtained. Selenoamide moieties introduced into C 3 -symmetrical molecules enhance supramolecular interactions and confer a remarkable thermal stability to the supramolecular polymers.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc08423a