Synthesis of magnetic core-shell amino adsorbent by using uniform design and response surface analysis (RSM) and its application for the removal of Cu 2+ , Zn 2+ , and Pb 2

• Published in: Environmental science and pollution research international 2021-03
• Main Authors: Alam, Easar, Feng, Qiyan, Yang, Hong, Fan, Jiaxi, Mumtaz, Sameena
• Format: Article
• Language: English
• ISSN: 1614-7499

The magnetic Fe O was synthesized by using a one-step solvothermal method. Then, anhydrous ethanol as a solvent, tetramethyl ammonium hydroxide (TMAOH) as an auxiliary agent, tetraethyl orthosilicate (TEOS) as a silicon source, and (3-aminopropyl) triethoxysilane (APTES) as amino source were used to prepare Fe O @mSiO -NH by using the sol-gel method. Uniform design U14*(14 ) and the response surface method (RSM) were used to optimize the synthesis ratio. According to the results of TEM, SEM, N adsorption-desorption test, VSM, and XRD, it found that the best coating effect obtained when the relative molar ratio of TMAOH:TEOS:APTES:Fe O was 5:4:6:0.45. The results of EDS and elemental analysis confirmed the success of amino group coating; VSM magnetization after surface modification was 32 emu/g; BET results show that specific surface area is 236 m /g, size 5 nm, and the pore volume is 0.126 cm /g. The removal of Cu , Zn , and Pb by Fe O @mSiO -NH was studied at the optimal initial pH value 6 of the adsorption test system. The isothermal adsorption results show that the Langmuir model and Redlich-Peterson model are more suitable than the Freundlich model to describe the adsorption behavior, and Cu , Zn , and Pb adsorption is mainly single molecular layer. The maximum adsorption capacity qm of the Langmuir model for Cu , Zn , and Pb removal was 48.04 mg/g, 41.31 mg/g, and 62.17 mg/g, respectively. The adsorption kinetic rates of Cu , Zn , and Pb on Fe O @mSiO -NH relatively more suitable for pseudo-second-order kinetic model, i.e., R , were ranged between 0.995 and 0.999, and the suitable reaction time was 60 min. These results proved that Fe O @m-SiO -NH prepared by using this method is easy to synthesize, has easy recovery, is ecofriendly, and can be potential adsorbent for Cu , Zn , and Pb removal.