A green route to platinum N-heterocyclic carbene complexes: mechanism and expanded scope

A sustainable and facile weak-base synthetic route to platinum N-heterocyclic carbene (NHC) complexes is disclosed. The mechanism of this reaction is also elucidated via experimental and computational investigations. This straightforward protocol is then used for the synthesis of novel Pt( ii )-NHC...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2022-04, Vol.51 (16), p.624-6211
Main Authors: Maliszewski, Benon P, Ritacco, Ida, Beliš, Marek, Hashim, Ishfaq Ibni, Tzouras, Nikolaos V, Caporaso, Lucia, Cavallo, Luigi, Van Hecke, Kristof, Nahra, Fady, Cazin, Catherine S. J, Nolan, Steven P
Format: Article
Language:English
Subjects:
Carbenes
Platinum
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Summary:A sustainable and facile weak-base synthetic route to platinum N-heterocyclic carbene (NHC) complexes is disclosed. The mechanism of this reaction is also elucidated via experimental and computational investigations. This straightforward protocol is then used for the synthesis of novel Pt( ii )-NHC complexes and its utility is further explored to access key Pt(0)-NHC precatalysts. A sustainable and facile weak-base synthetic route to platinum N-heterocyclic carbene (NHC) complexes is disclosed.
ISSN:1477-9226
1477-9234
DOI:10.1039/d2dt00504b