Tetra-μ-acetato-κ 8 O : O '-bis-[(3-chloro-pyridine-κ N )ruthenium(II,III)]( Ru - Ru ) hexa-fluorido-phosphate 1,2-di-chloro-ethane monosolvate

The title compound, [Ru (μ-O CCH ) (C H ClN) ]PF ·C H Cl , was obtained a rapid substitution reaction of 3-chloro-pyridine for water in [Ru (μ-O CCH ) (H O) ]PF in 2-propanol and subsequent crystallization from a di-chloro-ethane solution. The cationic diruthenium(II,III) tetra-acetate core lies on...

Full description

Saved in:
Bibliographic Details
Published in:IUCrData 2022-03, Vol.7 (Pt 3), p.x220249
Main Authors: Aquino, Anthony J, Gerrior, Daniel, Cameron, T Stanley, Robertson, Katherine N, Aquino, Manuel A S
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The title compound, [Ru (μ-O CCH ) (C H ClN) ]PF ·C H Cl , was obtained a rapid substitution reaction of 3-chloro-pyridine for water in [Ru (μ-O CCH ) (H O) ]PF in 2-propanol and subsequent crystallization from a di-chloro-ethane solution. The cationic diruthenium(II,III) tetra-acetate core lies on a crystallographic inversion center with Ru-Ru and Ru-N bond lengths of 2.2738 (3) and 2.2920 (17) Å, respectively. The Ru-Ru-N bond angle is close to linear at 176.48 (4)°, and a significant π-stacking inter-action of 3.5649 (16) Å is seen between overlapping pyridine rings of adjacent cations.
ISSN:2414-3146