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Heavy metalla vinyl-cations show metal-Lewis acid cooperativity in reaction with small molecules (NH, NH, HO, H)
Halide abstraction from tetrylidene complexes [TbbE(Br)IrH(PMe 3 ) 3 ] [E = Ge ( 1 ), Sn ( 2 )] and [Ar*E(Cl)IrH(PMe 3 ) 3 ] gives the salts [TbbEIrH(PMe 3 ) 3 ][BAr F 4 ] [E = Ge ( 3 ), Sn ( 4 )] and [Ar*EIrH(PMe 3 ) 3 ][BAr F 4 ] [E = Ge ( 3′ ), E = Sn ( 4′ )] (Tbb = 2,6-[CH(SiMe 3 ) 2 ] 2 -4-( t...
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| Published in: | Chemical science (Cambridge) 2023-01, Vol.14 (3), p.514-524 |
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| Main Authors: | , , , , , |
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| container_start_page | 514 |
| container_title | Chemical science (Cambridge) |
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| creator | Auer, Maximilian Bolten, Janina Eichele, Klaus Schubert, Hartmut Sindlinger, Christian P Wesemann, Lars |
| description | Halide abstraction from tetrylidene complexes [TbbE(Br)IrH(PMe
3
)
3
] [E = Ge (
1
), Sn (
2
)] and [Ar*E(Cl)IrH(PMe
3
)
3
] gives the salts [TbbEIrH(PMe
3
)
3
][BAr
F
4
] [E = Ge (
3
), Sn (
4
)] and [Ar*EIrH(PMe
3
)
3
][BAr
F
4
] [E = Ge (
3′
), E = Sn (
4′
)] (Tbb = 2,6-[CH(SiMe
3
)
2
]
2
-4-(
t
-Bu)C
6
H
2
, Ar* = 2,6-Trip
2
C
6
H
3
, Trip = 2,4,6-triisopropylphenyl). Bonding analysis suggests their most suitable description as metalla-tetrela vinyl cations with an Ir&z.dbd;E double bond and a near linear coordination at the Ge/Sn atoms. Cationic complexes
3
and
4
oxidatively add NH
3
, N
2
H
4
, H
2
O, HCl, and H
2
selectively to give: [TbbGe(NH
2
)IrH
2
(PMe
3
)
3
][BAr
F
4
] (
5
), [TbbE(NHNH
2
)IrH
2
(PMe
3
)
3
][BAr
F
4
] [E = Ge (
7
), Sn (
8
)], [TbbE(OH)IrH
2
(PMe
3
)
3
][BAr
F
4
] [E = Ge (
9
), Sn (
10
)], [TbbE(Cl)IrH
2
(PMe
3
)
3
][BAr
F
4
] [E = Ge (
11a
), Sn (
12a
)], [TbbGe(H)IrH
2
(PMe
3
)
3
][BAr
F
4
] (
13
), [TbbSn(μ-H
3
)Ir(PMe
3
)
3
][BAr
F
4
] (
14
), and [TbbSn(H)IrH
2
(PMe
3
)
3
][BAr
F
4
] (
15
).
14
isomerizes to give
15
via
an 1,2-H shift reaction. Hydride addition to cation
3
gives a mixture of products [TbbGeHIrH(PMe
3
)
3
] (
16
) and [TbbGeIrH
2
(PMe
3
)
3
] (
17
) and a reversible 1,2-H shift between
16
and
17
was studied. In the tin case
4
the dihydride [TbbSnIrH
2
(PMe
3
)
3
] (
18
) was isolated exclusively. The PMe
3
and PEt
3
derivatives,
18
and [TbbSnIrH
2
(PEt
3
)
3
] (
19
), respectively, could also be synthesized in reaction of [TbbSnH
2
]
−
with the respective chloride [(R
3
P)
n
IrCl] (R = Me,
n
= 4; R = Et,
n
= 3). Reaction of complex
19
with CO gives the substitution product [TbbSnIrH
2
(CO)(PEt
3
)
2
] (
20
). Further reaction with CO results in hydrogen transfer from the iridium to the tin atom to give [TbbSnH
2
Ir(CO)
2
(PEt
3
)
2
] (
21
). The reversibility of this ligand induced reductive elimination transferring
20
to
21
is shown.
Tetrylidinium-iridium cations [ArE = IrHL
3
]
+
(E = Ge, Sn) show a vinyl-cation type bonding situation and are highly reactive electrophiles acting as a cooperative metal-ligand Lewis acid enabling 1,2-addition of NH
3
, N
2
H
4
, H
2
O, HCl and H
2
. |
| doi_str_mv | 10.1039/d2sc05620h |
| format | article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmed_primary_36741530</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2766480832</sourcerecordid><originalsourceid>FETCH-LOGICAL-c303t-15c4dd4dfb2aa99474a4dad57f7403087649c6d88430b5e9f1c7892a297f0dce3</originalsourceid><addsrcrecordid>eNpdkd1LwzAUxYMoOqYvvisBX6ZYzVeb5lHmR4WhD-pzyZKUZbTNTNqN_fdmTid44XAD95fDTQ4ApxjdYETFrSZBoTQjaLYHBgQxnGQpFfu7M0FH4CSEOYpFKU4JPwRHNOMMpxQNwKIwcrmGjelkXUu4tO26TpTsrGsDDDO32o6SiVnZAKWyGirnFsZHZGm7NbQt9EaqzQW4st0MhiY6wcbVRvW1CXD0UlzDjYrXqMtjcFDJOpiTnz4EH48P7-Mimbw-PY_vJomiiHYJThXTmulqSqQUgnEmmZY65RVniKKcZ0yoTOc5o2iaGlFhxXNBJBG8QloZOgSjre_Cu8_ehK5sbFAmPrI1rg8l4ZxynGMiInrxD5273rdxu0hlGctRTkmkrraU8i4Eb6py4W0j_brEqNxEUd6Tt_F3FEWEz38s-2lj9A79_fgInG0BH9Ru-pcl_QJTjIup</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2766480832</pqid></control><display><type>article</type><title>Heavy metalla vinyl-cations show metal-Lewis acid cooperativity in reaction with small molecules (NH, NH, HO, H)</title><source>PubMed (Medline)</source><creator>Auer, Maximilian ; Bolten, Janina ; Eichele, Klaus ; Schubert, Hartmut ; Sindlinger, Christian P ; Wesemann, Lars</creator><creatorcontrib>Auer, Maximilian ; Bolten, Janina ; Eichele, Klaus ; Schubert, Hartmut ; Sindlinger, Christian P ; Wesemann, Lars</creatorcontrib><description>Halide abstraction from tetrylidene complexes [TbbE(Br)IrH(PMe
3
)
3
] [E = Ge (
1
), Sn (
2
)] and [Ar*E(Cl)IrH(PMe
3
)
3
] gives the salts [TbbEIrH(PMe
3
)
3
][BAr
F
4
] [E = Ge (
3
), Sn (
4
)] and [Ar*EIrH(PMe
3
)
3
][BAr
F
4
] [E = Ge (
3′
), E = Sn (
4′
)] (Tbb = 2,6-[CH(SiMe
3
)
2
]
2
-4-(
t
-Bu)C
6
H
2
, Ar* = 2,6-Trip
2
C
6
H
3
, Trip = 2,4,6-triisopropylphenyl). Bonding analysis suggests their most suitable description as metalla-tetrela vinyl cations with an Ir&z.dbd;E double bond and a near linear coordination at the Ge/Sn atoms. Cationic complexes
3
and
4
oxidatively add NH
3
, N
2
H
4
, H
2
O, HCl, and H
2
selectively to give: [TbbGe(NH
2
)IrH
2
(PMe
3
)
3
][BAr
F
4
] (
5
), [TbbE(NHNH
2
)IrH
2
(PMe
3
)
3
][BAr
F
4
] [E = Ge (
7
), Sn (
8
)], [TbbE(OH)IrH
2
(PMe
3
)
3
][BAr
F
4
] [E = Ge (
9
), Sn (
10
)], [TbbE(Cl)IrH
2
(PMe
3
)
3
][BAr
F
4
] [E = Ge (
11a
), Sn (
12a
)], [TbbGe(H)IrH
2
(PMe
3
)
3
][BAr
F
4
] (
13
), [TbbSn(μ-H
3
)Ir(PMe
3
)
3
][BAr
F
4
] (
14
), and [TbbSn(H)IrH
2
(PMe
3
)
3
][BAr
F
4
] (
15
).
14
isomerizes to give
15
via
an 1,2-H shift reaction. Hydride addition to cation
3
gives a mixture of products [TbbGeHIrH(PMe
3
)
3
] (
16
) and [TbbGeIrH
2
(PMe
3
)
3
] (
17
) and a reversible 1,2-H shift between
16
and
17
was studied. In the tin case
4
the dihydride [TbbSnIrH
2
(PMe
3
)
3
] (
18
) was isolated exclusively. The PMe
3
and PEt
3
derivatives,
18
and [TbbSnIrH
2
(PEt
3
)
3
] (
19
), respectively, could also be synthesized in reaction of [TbbSnH
2
]
−
with the respective chloride [(R
3
P)
n
IrCl] (R = Me,
n
= 4; R = Et,
n
= 3). Reaction of complex
19
with CO gives the substitution product [TbbSnIrH
2
(CO)(PEt
3
)
2
] (
20
). Further reaction with CO results in hydrogen transfer from the iridium to the tin atom to give [TbbSnH
2
Ir(CO)
2
(PEt
3
)
2
] (
21
). The reversibility of this ligand induced reductive elimination transferring
20
to
21
is shown.
Tetrylidinium-iridium cations [ArE = IrHL
3
]
+
(E = Ge, Sn) show a vinyl-cation type bonding situation and are highly reactive electrophiles acting as a cooperative metal-ligand Lewis acid enabling 1,2-addition of NH
3
, N
2
H
4
, H
2
O, HCl and H
2
.</description><identifier>ISSN: 2041-6520</identifier><identifier>EISSN: 2041-6539</identifier><identifier>DOI: 10.1039/d2sc05620h</identifier><identifier>PMID: 36741530</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Ammonia ; Cations ; Chemical synthesis ; Dihydrides ; Germanium ; Iridium ; Lewis acid ; Shift reaction ; Substitution reactions ; Tin</subject><ispartof>Chemical science (Cambridge), 2023-01, Vol.14 (3), p.514-524</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c303t-15c4dd4dfb2aa99474a4dad57f7403087649c6d88430b5e9f1c7892a297f0dce3</citedby><cites>FETCH-LOGICAL-c303t-15c4dd4dfb2aa99474a4dad57f7403087649c6d88430b5e9f1c7892a297f0dce3</cites><orcidid>0000-0002-0392-7149 ; 0000-0003-4701-4410</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36741530$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Auer, Maximilian</creatorcontrib><creatorcontrib>Bolten, Janina</creatorcontrib><creatorcontrib>Eichele, Klaus</creatorcontrib><creatorcontrib>Schubert, Hartmut</creatorcontrib><creatorcontrib>Sindlinger, Christian P</creatorcontrib><creatorcontrib>Wesemann, Lars</creatorcontrib><title>Heavy metalla vinyl-cations show metal-Lewis acid cooperativity in reaction with small molecules (NH, NH, HO, H)</title><title>Chemical science (Cambridge)</title><addtitle>Chem Sci</addtitle><description>Halide abstraction from tetrylidene complexes [TbbE(Br)IrH(PMe
3
)
3
] [E = Ge (
1
), Sn (
2
)] and [Ar*E(Cl)IrH(PMe
3
)
3
] gives the salts [TbbEIrH(PMe
3
)
3
][BAr
F
4
] [E = Ge (
3
), Sn (
4
)] and [Ar*EIrH(PMe
3
)
3
][BAr
F
4
] [E = Ge (
3′
), E = Sn (
4′
)] (Tbb = 2,6-[CH(SiMe
3
)
2
]
2
-4-(
t
-Bu)C
6
H
2
, Ar* = 2,6-Trip
2
C
6
H
3
, Trip = 2,4,6-triisopropylphenyl). Bonding analysis suggests their most suitable description as metalla-tetrela vinyl cations with an Ir&z.dbd;E double bond and a near linear coordination at the Ge/Sn atoms. Cationic complexes
3
and
4
oxidatively add NH
3
, N
2
H
4
, H
2
O, HCl, and H
2
selectively to give: [TbbGe(NH
2
)IrH
2
(PMe
3
)
3
][BAr
F
4
] (
5
), [TbbE(NHNH
2
)IrH
2
(PMe
3
)
3
][BAr
F
4
] [E = Ge (
7
), Sn (
8
)], [TbbE(OH)IrH
2
(PMe
3
)
3
][BAr
F
4
] [E = Ge (
9
), Sn (
10
)], [TbbE(Cl)IrH
2
(PMe
3
)
3
][BAr
F
4
] [E = Ge (
11a
), Sn (
12a
)], [TbbGe(H)IrH
2
(PMe
3
)
3
][BAr
F
4
] (
13
), [TbbSn(μ-H
3
)Ir(PMe
3
)
3
][BAr
F
4
] (
14
), and [TbbSn(H)IrH
2
(PMe
3
)
3
][BAr
F
4
] (
15
).
14
isomerizes to give
15
via
an 1,2-H shift reaction. Hydride addition to cation
3
gives a mixture of products [TbbGeHIrH(PMe
3
)
3
] (
16
) and [TbbGeIrH
2
(PMe
3
)
3
] (
17
) and a reversible 1,2-H shift between
16
and
17
was studied. In the tin case
4
the dihydride [TbbSnIrH
2
(PMe
3
)
3
] (
18
) was isolated exclusively. The PMe
3
and PEt
3
derivatives,
18
and [TbbSnIrH
2
(PEt
3
)
3
] (
19
), respectively, could also be synthesized in reaction of [TbbSnH
2
]
−
with the respective chloride [(R
3
P)
n
IrCl] (R = Me,
n
= 4; R = Et,
n
= 3). Reaction of complex
19
with CO gives the substitution product [TbbSnIrH
2
(CO)(PEt
3
)
2
] (
20
). Further reaction with CO results in hydrogen transfer from the iridium to the tin atom to give [TbbSnH
2
Ir(CO)
2
(PEt
3
)
2
] (
21
). The reversibility of this ligand induced reductive elimination transferring
20
to
21
is shown.
Tetrylidinium-iridium cations [ArE = IrHL
3
]
+
(E = Ge, Sn) show a vinyl-cation type bonding situation and are highly reactive electrophiles acting as a cooperative metal-ligand Lewis acid enabling 1,2-addition of NH
3
, N
2
H
4
, H
2
O, HCl and H
2
.</description><subject>Ammonia</subject><subject>Cations</subject><subject>Chemical synthesis</subject><subject>Dihydrides</subject><subject>Germanium</subject><subject>Iridium</subject><subject>Lewis acid</subject><subject>Shift reaction</subject><subject>Substitution reactions</subject><subject>Tin</subject><issn>2041-6520</issn><issn>2041-6539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpdkd1LwzAUxYMoOqYvvisBX6ZYzVeb5lHmR4WhD-pzyZKUZbTNTNqN_fdmTid44XAD95fDTQ4ApxjdYETFrSZBoTQjaLYHBgQxnGQpFfu7M0FH4CSEOYpFKU4JPwRHNOMMpxQNwKIwcrmGjelkXUu4tO26TpTsrGsDDDO32o6SiVnZAKWyGirnFsZHZGm7NbQt9EaqzQW4st0MhiY6wcbVRvW1CXD0UlzDjYrXqMtjcFDJOpiTnz4EH48P7-Mimbw-PY_vJomiiHYJThXTmulqSqQUgnEmmZY65RVniKKcZ0yoTOc5o2iaGlFhxXNBJBG8QloZOgSjre_Cu8_ehK5sbFAmPrI1rg8l4ZxynGMiInrxD5273rdxu0hlGctRTkmkrraU8i4Eb6py4W0j_brEqNxEUd6Tt_F3FEWEz38s-2lj9A79_fgInG0BH9Ru-pcl_QJTjIup</recordid><startdate>20230118</startdate><enddate>20230118</enddate><creator>Auer, Maximilian</creator><creator>Bolten, Janina</creator><creator>Eichele, Klaus</creator><creator>Schubert, Hartmut</creator><creator>Sindlinger, Christian P</creator><creator>Wesemann, Lars</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-0392-7149</orcidid><orcidid>https://orcid.org/0000-0003-4701-4410</orcidid></search><sort><creationdate>20230118</creationdate><title>Heavy metalla vinyl-cations show metal-Lewis acid cooperativity in reaction with small molecules (NH, NH, HO, H)</title><author>Auer, Maximilian ; Bolten, Janina ; Eichele, Klaus ; Schubert, Hartmut ; Sindlinger, Christian P ; Wesemann, Lars</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c303t-15c4dd4dfb2aa99474a4dad57f7403087649c6d88430b5e9f1c7892a297f0dce3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Ammonia</topic><topic>Cations</topic><topic>Chemical synthesis</topic><topic>Dihydrides</topic><topic>Germanium</topic><topic>Iridium</topic><topic>Lewis acid</topic><topic>Shift reaction</topic><topic>Substitution reactions</topic><topic>Tin</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Auer, Maximilian</creatorcontrib><creatorcontrib>Bolten, Janina</creatorcontrib><creatorcontrib>Eichele, Klaus</creatorcontrib><creatorcontrib>Schubert, Hartmut</creatorcontrib><creatorcontrib>Sindlinger, Christian P</creatorcontrib><creatorcontrib>Wesemann, Lars</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical science (Cambridge)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Auer, Maximilian</au><au>Bolten, Janina</au><au>Eichele, Klaus</au><au>Schubert, Hartmut</au><au>Sindlinger, Christian P</au><au>Wesemann, Lars</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Heavy metalla vinyl-cations show metal-Lewis acid cooperativity in reaction with small molecules (NH, NH, HO, H)</atitle><jtitle>Chemical science (Cambridge)</jtitle><addtitle>Chem Sci</addtitle><date>2023-01-18</date><risdate>2023</risdate><volume>14</volume><issue>3</issue><spage>514</spage><epage>524</epage><pages>514-524</pages><issn>2041-6520</issn><eissn>2041-6539</eissn><abstract>Halide abstraction from tetrylidene complexes [TbbE(Br)IrH(PMe
3
)
3
] [E = Ge (
1
), Sn (
2
)] and [Ar*E(Cl)IrH(PMe
3
)
3
] gives the salts [TbbEIrH(PMe
3
)
3
][BAr
F
4
] [E = Ge (
3
), Sn (
4
)] and [Ar*EIrH(PMe
3
)
3
][BAr
F
4
] [E = Ge (
3′
), E = Sn (
4′
)] (Tbb = 2,6-[CH(SiMe
3
)
2
]
2
-4-(
t
-Bu)C
6
H
2
, Ar* = 2,6-Trip
2
C
6
H
3
, Trip = 2,4,6-triisopropylphenyl). Bonding analysis suggests their most suitable description as metalla-tetrela vinyl cations with an Ir&z.dbd;E double bond and a near linear coordination at the Ge/Sn atoms. Cationic complexes
3
and
4
oxidatively add NH
3
, N
2
H
4
, H
2
O, HCl, and H
2
selectively to give: [TbbGe(NH
2
)IrH
2
(PMe
3
)
3
][BAr
F
4
] (
5
), [TbbE(NHNH
2
)IrH
2
(PMe
3
)
3
][BAr
F
4
] [E = Ge (
7
), Sn (
8
)], [TbbE(OH)IrH
2
(PMe
3
)
3
][BAr
F
4
] [E = Ge (
9
), Sn (
10
)], [TbbE(Cl)IrH
2
(PMe
3
)
3
][BAr
F
4
] [E = Ge (
11a
), Sn (
12a
)], [TbbGe(H)IrH
2
(PMe
3
)
3
][BAr
F
4
] (
13
), [TbbSn(μ-H
3
)Ir(PMe
3
)
3
][BAr
F
4
] (
14
), and [TbbSn(H)IrH
2
(PMe
3
)
3
][BAr
F
4
] (
15
).
14
isomerizes to give
15
via
an 1,2-H shift reaction. Hydride addition to cation
3
gives a mixture of products [TbbGeHIrH(PMe
3
)
3
] (
16
) and [TbbGeIrH
2
(PMe
3
)
3
] (
17
) and a reversible 1,2-H shift between
16
and
17
was studied. In the tin case
4
the dihydride [TbbSnIrH
2
(PMe
3
)
3
] (
18
) was isolated exclusively. The PMe
3
and PEt
3
derivatives,
18
and [TbbSnIrH
2
(PEt
3
)
3
] (
19
), respectively, could also be synthesized in reaction of [TbbSnH
2
]
−
with the respective chloride [(R
3
P)
n
IrCl] (R = Me,
n
= 4; R = Et,
n
= 3). Reaction of complex
19
with CO gives the substitution product [TbbSnIrH
2
(CO)(PEt
3
)
2
] (
20
). Further reaction with CO results in hydrogen transfer from the iridium to the tin atom to give [TbbSnH
2
Ir(CO)
2
(PEt
3
)
2
] (
21
). The reversibility of this ligand induced reductive elimination transferring
20
to
21
is shown.
Tetrylidinium-iridium cations [ArE = IrHL
3
]
+
(E = Ge, Sn) show a vinyl-cation type bonding situation and are highly reactive electrophiles acting as a cooperative metal-ligand Lewis acid enabling 1,2-addition of NH
3
, N
2
H
4
, H
2
O, HCl and H
2
.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>36741530</pmid><doi>10.1039/d2sc05620h</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-0392-7149</orcidid><orcidid>https://orcid.org/0000-0003-4701-4410</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2041-6520 |
| ispartof | Chemical science (Cambridge), 2023-01, Vol.14 (3), p.514-524 |
| issn | 2041-6520 2041-6539 |
| language | eng |
| recordid | cdi_pubmed_primary_36741530 |
| source | PubMed (Medline) |
| subjects | Ammonia Cations Chemical synthesis Dihydrides Germanium Iridium Lewis acid Shift reaction Substitution reactions Tin |
| title | Heavy metalla vinyl-cations show metal-Lewis acid cooperativity in reaction with small molecules (NH, NH, HO, H) |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-26T00%3A08%3A45IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Heavy%20metalla%20vinyl-cations%20show%20metal-Lewis%20acid%20cooperativity%20in%20reaction%20with%20small%20molecules%20(NH,%20NH,%20HO,%20H)&rft.jtitle=Chemical%20science%20(Cambridge)&rft.au=Auer,%20Maximilian&rft.date=2023-01-18&rft.volume=14&rft.issue=3&rft.spage=514&rft.epage=524&rft.pages=514-524&rft.issn=2041-6520&rft.eissn=2041-6539&rft_id=info:doi/10.1039/d2sc05620h&rft_dat=%3Cproquest_pubme%3E2766480832%3C/proquest_pubme%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c303t-15c4dd4dfb2aa99474a4dad57f7403087649c6d88430b5e9f1c7892a297f0dce3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2766480832&rft_id=info:pmid/36741530&rfr_iscdi=true |