Solvent-free hydroboration of alkenes and alkynes catalyzed by rhodium-ruthenium nanoparticles on carbon nanotubes

A heterogeneous catalyst consisting of bimetallic rhodium-ruthenium particles immobilized on carbon nanotubes was used in the hydroboration reaction and proved highly effective for a variety of alkenes and alkynes. The reactions were carried out with low catalytic loadings (0.04 mol%), under solvent...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2023-03, Vol.59 (19), p.2763-2766
Main Authors: Nunes, Mateus P, Jawale, Dhanaji V, Delolo, Fábio G, Araujo, Maria H, Gravel, Edmond, Doris, Eric, da Silva Júnior, Eufrânio N
Format: Article
Language:English
Subjects:
Alkenes
Alkynes
Bimetals
Carbon nanotubes
Catalysts
Chemical Sciences
Hydroboration
Nanoparticles
Recyclability
Rhodium
Room temperature
Ruthenium
Solvents
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A heterogeneous catalyst consisting of bimetallic rhodium-ruthenium particles immobilized on carbon nanotubes was used in the hydroboration reaction and proved highly effective for a variety of alkenes and alkynes. The reactions were carried out with low catalytic loadings (0.04 mol%), under solvent-free conditions, and at room temperature. In addition, to demonstrate its recyclability, the catalyst was recovered by a simple centrifugation process and reused over 5 consecutive cycles without losing any activity. A heterogeneous catalyst consisting of bimetallic rhodium-ruthenium particles immobilized on carbon nanotubes was used in the hydroboration reaction and proved highly effective for a variety of alkenes and alkynes.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc06864h