Synthesis of 3D Porous Cu Nanostructures on Ag Thin Film Using Dynamic Hydrogen Bubble Template for Electrochemical Conversion of CO 2 to Ethanol

• Published in: Nanomaterials (Basel, Switzerland) Switzerland), 2023-02, Vol.13 (4)
• Main Authors: Rahmati, Farnood, Sabouhanian, Negar, Lipkowski, Jacek, Chen, Aicheng
• Format: Article
• Language: English
• ISSN: 2079-4991; 2079-4991

Cu-based nanomaterials have been widely considered to be promising electrocatalysts for the direct conversion of CO to high-value hydrocarbons. However, poor selectivity and slow kinetics have hindered the use of Cu-based catalysts for large-scale industrial applications. In this work, we report on a tunable Cu-based synthesis strategy using a dynamic hydrogen bubble template (DHBT) coupled with a sputtered Ag thin film for the electrochemical reduction of CO to ethanol. Remarkably, the introduction of Ag into the base of the three-dimensional (3D) Cu nanostructure induced changes in the CO reduction reaction (CO2RR) pathway, which resulted in the generation of ethanol with high Faradaic Efficiency (FE). This observation was further investigated through Tafel and electrochemical impedance spectroscopic analyses. The rational design of the electrocatalyst was shown to promote the spillover of formed CO intermediates from the Ag sites to the 3D porous Cu nanostructure for further reduction to C products. Finally, challenges toward the development of multi-metallic electrocatalysts for the direct catalysis of CO to hydrocarbons were elucidated, and future perspectives were highlighted.