Potential of 3D Hierarchical Porous TiO 2 -Graphene Aerogel (TiO 2 -GA) as Electrocatalyst Support for Direct Methanol Fuel Cells

• Published in: Nanomaterials (Basel, Switzerland) Switzerland), 2023-06, Vol.13 (12)
• Main Authors: Osman, Siti Hasanah, Kamarudin, Siti Kartom, Basri, Sahriah, Karim, Nabila A
• Format: Article
• Language: English
• ISSN: 2079-4991; 2079-4991
• DOI: 10.3390/nano13121819

Fuel cells have already demonstrated their potential for green energy generation. However, the low reaction performance becomes an obstacle in terms of large-scale commercial manufacturing. Accordingly, this work focuses on a new unique fabrication of three-dimensional pore hierarchy TiO -graphene aerogel (TiO -GA) supporting PtRu catalyst for anodic catalyst direct methanol fuel cell, which is facile, ecologically benign, and economical. In this work, a hydrothermal technique was used, followed by a freeze-drying technique and a microwave-assisted ethylene reduction technique. The structural properties of the studied materials were confirmed by UV/visible spectroscopy, XRD, Raman spectrum, FESEM TEM, and XPS. Based on existing structural advantages, the performance of PtRu/TiO -GA has been investigated on DMFC anode catalysts. Furthermore, electrocatalytic stability performance with the same loading (~20%) was compared to commercial PtRu/C. Experimental outcomes show that the TiO -GA support offered a significantly high surface area value of 68.44 m g , mass activity/specific activity (608.17 mAmg /0.45 mA/cm ) that is higher than commercial PtRu/C (79.11 mAmg /0.19 mA/cm ). In passive DMFC mode, PtRu/TiO -GA showed a maximum power density of 3.1 mW cm , which is 2.6 times higher than that of the PtRu/C commercial electrocatalyst. This suggests that PtRu/TiO -GA has a promising possibility for methanol oxidation and may be used as an anodic element in DMFC.