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Ideal trigonal prismatic coordination geometry of Co() in a honeycomb MOF with a triptycene-based ligand
A metal-organic framework (MOF) comprised of cobalt ions and triptycene-based 3-fold symmetric bridging ligands 9,10-[1,2]benzenoanthracene-2,3,6,7,14,15(9 H ,10 H )-hexaone ( o -TT) was prepared. Single-crystal structure analysis revealed a 2D honeycomb network structure and the ideal trigonal pris...
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| Published in: | Chemical communications (Cambridge, England) England), 2023-08, Vol.59 (67), p.115-118 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c373t-e8d7320236f54f3f88080f984f3faa927ba77a942b5f5c7f49e87e26768f50903 |
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| cites | cdi_FETCH-LOGICAL-c373t-e8d7320236f54f3f88080f984f3faa927ba77a942b5f5c7f49e87e26768f50903 |
| container_end_page | 118 |
| container_issue | 67 |
| container_start_page | 115 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 59 |
| creator | Shuku, Yoshiaki Suizu, Rie Tsuchiizu, Masahisa Awaga, Kunio |
| description | A metal-organic framework (MOF) comprised of cobalt ions and triptycene-based 3-fold symmetric bridging ligands 9,10-[1,2]benzenoanthracene-2,3,6,7,14,15(9
H
,10
H
)-hexaone (
o
-TT) was prepared. Single-crystal structure analysis revealed a 2D honeycomb network structure and the ideal trigonal prismatic geometry of the Co(
ii
) ion. The magnetic anisotropy of the Co(
ii
) ion in the trigonal prism coordination geometry was analyzed
via
magnetic measurements and model calculations.
An ideal trigonal prismatic coordination geometry was achieved in the honeycomb metal-organic framework comprised of Co ions and triptycene-based bridging ligands. |
| doi_str_mv | 10.1039/d3cc02986g |
| format | article |
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H
,10
H
)-hexaone (
o
-TT) was prepared. Single-crystal structure analysis revealed a 2D honeycomb network structure and the ideal trigonal prismatic geometry of the Co(
ii
) ion. The magnetic anisotropy of the Co(
ii
) ion in the trigonal prism coordination geometry was analyzed
via
magnetic measurements and model calculations.
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H
,10
H
)-hexaone (
o
-TT) was prepared. Single-crystal structure analysis revealed a 2D honeycomb network structure and the ideal trigonal prismatic geometry of the Co(
ii
) ion. The magnetic anisotropy of the Co(
ii
) ion in the trigonal prism coordination geometry was analyzed
via
magnetic measurements and model calculations.
An ideal trigonal prismatic coordination geometry was achieved in the honeycomb metal-organic framework comprised of Co ions and triptycene-based bridging ligands.</description><subject>Coordination</subject><subject>Crystal structure</subject><subject>Ligands</subject><subject>Magnetic anisotropy</subject><subject>Magnetic measurement</subject><subject>Metal-organic frameworks</subject><subject>Single crystals</subject><subject>Structural analysis</subject><subject>Two dimensional analysis</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpdkUFLwzAYhoMobk4v3pWAlylU06RpkqNUNweTXRS8lTRNto62mUmH7N-buTnB75KXLw_v4fkAuIzRfYyIeCiJUggLns6PQD8maRLRhH8cbzMVESMJ7YEz75coTEz5KegRRmOBOemDxaTUsoadq-a2DWHlKt_IrlJQWevKqg3ZtnCubaM7t4HWwMwOb2HVQgkXttUbZZsCvs5G8KvqFmEZqlbdRulWR4X0uoR1NZdteQ5OjKy9vti_A_A-en7LXqLpbDzJHqeRIox0keYlIxhhkhqaGGI4RxwZwbdZSoFZIRmTIsEFNVQxkwjNmcYpS7mhSCAyAMNd78rZz7X2Xd5UXum6lq22a59jniSIM8bSgN78Q5d27YKFLUVjjoMjGqi7HaWc9d5pkwdHjXSbPEb51n_-RLLsx_84wNf7ynXR6PKA_goPwNUOcF4dfv8OSL4BBRyIwQ</recordid><startdate>20230817</startdate><enddate>20230817</enddate><creator>Shuku, Yoshiaki</creator><creator>Suizu, Rie</creator><creator>Tsuchiizu, Masahisa</creator><creator>Awaga, Kunio</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-2193-0747</orcidid><orcidid>https://orcid.org/0000-0002-3968-4791</orcidid><orcidid>https://orcid.org/0000-0001-7632-2186</orcidid></search><sort><creationdate>20230817</creationdate><title>Ideal trigonal prismatic coordination geometry of Co() in a honeycomb MOF with a triptycene-based ligand</title><author>Shuku, Yoshiaki ; Suizu, Rie ; Tsuchiizu, Masahisa ; Awaga, Kunio</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c373t-e8d7320236f54f3f88080f984f3faa927ba77a942b5f5c7f49e87e26768f50903</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Coordination</topic><topic>Crystal structure</topic><topic>Ligands</topic><topic>Magnetic anisotropy</topic><topic>Magnetic measurement</topic><topic>Metal-organic frameworks</topic><topic>Single crystals</topic><topic>Structural analysis</topic><topic>Two dimensional analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shuku, Yoshiaki</creatorcontrib><creatorcontrib>Suizu, Rie</creatorcontrib><creatorcontrib>Tsuchiizu, Masahisa</creatorcontrib><creatorcontrib>Awaga, Kunio</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shuku, Yoshiaki</au><au>Suizu, Rie</au><au>Tsuchiizu, Masahisa</au><au>Awaga, Kunio</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ideal trigonal prismatic coordination geometry of Co() in a honeycomb MOF with a triptycene-based ligand</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2023-08-17</date><risdate>2023</risdate><volume>59</volume><issue>67</issue><spage>115</spage><epage>118</epage><pages>115-118</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>A metal-organic framework (MOF) comprised of cobalt ions and triptycene-based 3-fold symmetric bridging ligands 9,10-[1,2]benzenoanthracene-2,3,6,7,14,15(9
H
,10
H
)-hexaone (
o
-TT) was prepared. Single-crystal structure analysis revealed a 2D honeycomb network structure and the ideal trigonal prismatic geometry of the Co(
ii
) ion. The magnetic anisotropy of the Co(
ii
) ion in the trigonal prism coordination geometry was analyzed
via
magnetic measurements and model calculations.
An ideal trigonal prismatic coordination geometry was achieved in the honeycomb metal-organic framework comprised of Co ions and triptycene-based bridging ligands.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>37519283</pmid><doi>10.1039/d3cc02986g</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-2193-0747</orcidid><orcidid>https://orcid.org/0000-0002-3968-4791</orcidid><orcidid>https://orcid.org/0000-0001-7632-2186</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2023-08, Vol.59 (67), p.115-118 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_pubmed_primary_37519283 |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Coordination Crystal structure Ligands Magnetic anisotropy Magnetic measurement Metal-organic frameworks Single crystals Structural analysis Two dimensional analysis |
| title | Ideal trigonal prismatic coordination geometry of Co() in a honeycomb MOF with a triptycene-based ligand |
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