Y-tube assisted coprecipitation synthesis of iron-based Prussian blue analogues cathode materials for sodium-ion batteries

• Published in: RSC advances 2024-04, Vol.14 (17), p.1296-1216
• Main Authors: Zhang, Ruizhong, Liu, Yuao, Liu, Hongquan, Zhong, Yanjun, Zhang, Yuan, Wu, Zhenguo, Wang, Xinlong
• Format: Article
• Language: English
• Subjects: Cathodes; Chemical precipitation; Chemical synthesis; Chemistry; Continuous production; Coprecipitation; Crystal defects; Electrochemical analysis; Electrode materials; Iron isotopes; Lattice vacancies; Low cost; Micromixing; Performance tests; Pigments; Sodium-ion batteries; Tube components
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/d4ra00762j

Prussian blue analogues possess numerous advantages as cathode materials for sodium-ion batteries, including high energy density, low cost, sustainability, and straightforward synthesis processes, making them highly promising for practical applications. However, during the synthesis, crystal defects such as vacancies and the incorporation of crystal water can lead to issues such as diminished capacity and suboptimal cycling stability. In the current study, a Y-tube assisted coprecipitation method was used to synthesize iron-based Prussian blue analogues, and the optimized feed flow rate during synthesis contributed to the successful preparation of the material with a formula of Na 1.56 Fe[Fe(CN) 6 ] 0.90 0.10 ·2.42H 2 O, representing a low-defect cathode material. This approach cleverly utilizes the Y-tube component to enhance the micro-mixing of materials in the co-precipitation reaction, featuring simplicity, low cost, user-friendly, and the ability to be used in continuous production. Electrochemical performance tests show that the sample retains 69.8% of its capacity after 200 cycles at a current density of 0.5C (1C = 140 mA g −1 ) and delivers a capacity of 71.9 mA h g −1 at a high rate of 10C. The findings of this research provide important insights for the development of high-performance Prussian blue analogues cathode materials for sodium-ion batteries. Prussian blue analogues are promising cathode materials for sodium-ion batteries due to their high energy density, low cost, sustainability, and simple synthesis processes.