Magnetized cubic zinc MOFs for efficient removal of hazardous cationic and anionic dyes in aqueous solutions

• Published in: RSC advances 2024-06, Vol.14 (27), p.19322-1933
• Main Authors: Abd El-Mouhsen, Ramy R, El-Sayed, Gamal O, El-Feky, Hesham H, Khalil, Mostafa M. H, El-Sewify, Islam M
• Format: Article
• Language: English
• Subjects: Adsorbents; Adsorption; Aqueous solutions; Chemistry; Clean energy; Cultural factors; Dyes; Industrial effluents; Iron oxides; Magnetic properties; Metal-organic frameworks; Water purification; Zinc
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/d4ra02453b

A significant amount of dye runoff and aqueous waste are released from the manufacturing process of dyes with intense and permanent colors, which are undesirable from a cultural and ecological aspect. In this paper, we present a green, simple, low-effort, and energy-efficient method of creating magnetized cubic Zn-MOFs for the adsorption and elimination of various organic dyes. Magnetic iron oxide materials with a hierarchical structure were loaded and doped into cubic zinc metal-organic frameworks (MDLZ). High magnetic characteristics, chemical stability, minimal toxicity, and ease of removing various dyes from aqueous effluents are all exhibited by the developed MDLZ adsorbent. To assess MDLZ's capacity to adsorb organic dyes from an aqueous solution, organic dyes such as Crystal Violet (CV), Neutral Red (NR), and Congo Red (CR) were used as model materials. Many adsorption factors were examined, including temperature, pH, contact time, initial concentration, and adsorbent dosage. Under optimal elimination circumstances, MDLZ was utilized to evaluate the kinetic, thermodynamic, and isotherm models for the adsorption of CR, NR, and CV dyes. The adsorption capacity ( q m ) of the MDLZ adsorbent at 25 °C was 39.37 mg g −1 for CV, 239.81 mg g −1 for CR, and 321.54 mg g −1 for NR, which is significantly higher than those of other adsorbents reported. The magnetized nanocubes' large surface area and uniform micropores enabled them to eliminate a large number of organic dyes from wastewater effectively, and their strong adsorption capability persisted even after four reuse cycles. The microporous MLDZ adsorbent offers a simple and effective method for handling industrial effluents and filtration of water. The magnetized nanocubes with large surface area and uniform micropores allow for eliminating a large number of organic dyes from wastewater effectively, and their strong adsorption capability persisted even after four reuse cycles.