Triazole-rich 3D metal-organic framework incorporated solid electrolytes for superior proton conductivity and durability in fuel cells

• Published in: Physical chemistry chemical physics : PCCP 2024-08, Vol.26 (31), p.2971-2983
• Main Authors: Ray, Madhuparna, Sethy, Sunil K, Maiti, Subrata Kumar, Ali, Nasir, Bhosale, Amit C, Negi, Yuvraj Singh, Chattopadhyay, Sujay
• Format: Article
• Language: English
• Subjects: Durability; Electrochemical analysis; Electrochemical impedance spectroscopy; Electrolytes; Electrolytic cells; Fourier transforms; Fuel cells; Infrared spectroscopy; Ion exchange; Ketones; Membranes; Metal-organic frameworks; Molten salt electrolytes; Polymer matrix composites; Proton exchange membrane fuel cells; Protons; Reagents; Solid electrolytes; Spectroscopic analysis; Spectrum analysis; Stability; Triazoles
• ISSN: 1463-9076; 1463-9084; 1463-9084
• DOI: 10.1039/d4cp02196g

Insufficient proton conductivity and oxidative stability of sulfonated hydrocarbons hinder their applicability as proton exchange membrane electrolytes in fuel cells. In this regard, fabrication of proton conducting mixed-matrix membranes (PC-MMMs) can be a superior approach to obtain desirable properties. In this work, a triazole ligand (1H-1,2,4 triazole) was coordinated to a zinc metal node to create a 3D metal-organic framework (MOF) and incorporated as an additive in a sulfonated poly(ether ether ketone) matrix at 1, 3, and 5 weight percentage to fabricate PC-MMMs by the casting process. Several characterization tools such as electrochemical impedance spectroscopy, Fourier transform infrared spectroscopy and scanning electron microscopy were used to characterise these membranes and study their potential application as electrolyte(s) in PEMFCs (proton exchange membrane fuel cells). Membranes were also tested for water uptake, ion-exchange capacity and oxidative stability in Fenton's reagent. The performance of the polymeric composite membrane containing a 3 wt% MOF was then assessed in a H 2 /O 2 single cell as it demonstrated the highest proton conductivity of 0.04 S cm −1 among all the compositions and a maximum current density of 1191 mA cm −2 . The membrane was also subjected to an OCV hold test for 12 hours to study the chemical durability over a period of time. This report establishes that the inclusion of a triazole based MOF enhances the proton conductivity, performance, and thermal and chemical durability of composite membranes which can be considered as a promising electrolyte material at intermediate temperatures after a proper optimisation of different cell parameters. MOF-assisted proton conduction mechanism in the membrane electrolyte and fuel cell performance.