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Baeyer-Villiger oxidation: a promising tool for the synthesis of natural products: a review
Baeyer-Villiger oxidation is a well-known reaction utilized for the synthesis of lactones and ester functionalities from ketones. Chiral lactones can be synthesized from chiral or racemic ketones by employing asymmetric Baeyer-Villiger oxidation. These lactones act as key intermediates in the synthe...
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| Published in: | RSC advances 2024-07, Vol.14 (32), p.23423-23458 |
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| Main Authors: | , , , , , , , , , |
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| container_end_page | 23458 |
| container_issue | 32 |
| container_start_page | 23423 |
| container_title | RSC advances |
| container_volume | 14 |
| creator | Fatima, Summaya Zahoor, Ameer Fawad Khan, Samreen Gul Naqvi, Syed Ali Raza Hussain, Syed Makhdoom Nazeer, Usman Mansha, Asim Ahmad, Hamad Chaudhry, Aijaz Rasool Irfan, Ahmad |
| description | Baeyer-Villiger oxidation is a well-known reaction utilized for the synthesis of lactones and ester functionalities from ketones. Chiral lactones can be synthesized from chiral or racemic ketones by employing asymmetric Baeyer-Villiger oxidation. These lactones act as key intermediates in the synthesis of most of the biologically active natural products, their analogues, and derivatives. Various monooxygenases and oxidizing agents facilitate BV oxidation, providing a broad range of synthetic applications in organic chemistry. The variety of enzymatic and chemoselective Baeyer-Villiger oxidations and their substantial role in the synthesis of natural products
i.e.
, alkaloids, polyketides, fatty acids, terpenoids,
etc.
(reported since 2018) have been summarized in this review article.
Baeyer-Villiger oxidation is a renowned reaction that provides an efficient route for the synthesis of biologically active natural products such as alkaloids, terpenoids, polyketides and fatty acid-based naturally occurring organic compounds. |
| doi_str_mv | 10.1039/d4ra03914a |
| format | article |
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i.e.
, alkaloids, polyketides, fatty acids, terpenoids,
etc.
(reported since 2018) have been summarized in this review article.
Baeyer-Villiger oxidation is a renowned reaction that provides an efficient route for the synthesis of biologically active natural products such as alkaloids, terpenoids, polyketides and fatty acid-based naturally occurring organic compounds.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d4ra03914a</identifier><identifier>PMID: 39055269</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Chemical synthesis ; Chemistry ; Ketones ; Lactones ; Natural products ; Organic chemistry ; Oxidation ; Oxidizing agents ; Terpenes</subject><ispartof>RSC advances, 2024-07, Vol.14 (32), p.23423-23458</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2024</rights><rights>This journal is © The Royal Society of Chemistry 2024 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c318t-672d6b86e2f884c15e0411a0432402da1d8ef5608a39c960fec01b0414280f743</cites><orcidid>0000-0003-2127-8848</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC11270005/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC11270005/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,27924,27925,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39055269$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Fatima, Summaya</creatorcontrib><creatorcontrib>Zahoor, Ameer Fawad</creatorcontrib><creatorcontrib>Khan, Samreen Gul</creatorcontrib><creatorcontrib>Naqvi, Syed Ali Raza</creatorcontrib><creatorcontrib>Hussain, Syed Makhdoom</creatorcontrib><creatorcontrib>Nazeer, Usman</creatorcontrib><creatorcontrib>Mansha, Asim</creatorcontrib><creatorcontrib>Ahmad, Hamad</creatorcontrib><creatorcontrib>Chaudhry, Aijaz Rasool</creatorcontrib><creatorcontrib>Irfan, Ahmad</creatorcontrib><title>Baeyer-Villiger oxidation: a promising tool for the synthesis of natural products: a review</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>Baeyer-Villiger oxidation is a well-known reaction utilized for the synthesis of lactones and ester functionalities from ketones. Chiral lactones can be synthesized from chiral or racemic ketones by employing asymmetric Baeyer-Villiger oxidation. These lactones act as key intermediates in the synthesis of most of the biologically active natural products, their analogues, and derivatives. Various monooxygenases and oxidizing agents facilitate BV oxidation, providing a broad range of synthetic applications in organic chemistry. The variety of enzymatic and chemoselective Baeyer-Villiger oxidations and their substantial role in the synthesis of natural products
i.e.
, alkaloids, polyketides, fatty acids, terpenoids,
etc.
(reported since 2018) have been summarized in this review article.
Baeyer-Villiger oxidation is a renowned reaction that provides an efficient route for the synthesis of biologically active natural products such as alkaloids, terpenoids, polyketides and fatty acid-based naturally occurring organic compounds.</description><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Ketones</subject><subject>Lactones</subject><subject>Natural products</subject><subject>Organic chemistry</subject><subject>Oxidation</subject><subject>Oxidizing agents</subject><subject>Terpenes</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpdkUtLxDAUhYMojuhs3CsBNyJU82raupHxLQiCqBsXIZPejpFOMyatOv_ejKPjI5sTuF_OvTcHoU1K9inhxUEpvI5KhV5Ca4wImTAii-Vf9x7qh_BM4pEpZZKuoh4vSJoyWayhx2MNU_DJg61rOwKP3bstdWtdc4g1nng3tsE2I9w6V-PKedw-AQ7TJkqwAbsKN7rtvK5nbNmZNszeeXi18LaBVipdB-h_6Tq6Pz-7O7lMrm8urk4G14nhNG8TmbFSDnMJrMpzYWgKRFCqieBMEFZqWuZQpZLkmhemkKQCQ-gwMoLlpMoEX0dHc99JNxxDaaBp40Bq4u1Y-6ly2qq_lcY-qZF7VZSyLH5LGh12vxy8e-kgtCqubaCudQOuC4qTXGQZj80juvMPfXadb-J-MyqjJBMFj9TenDLeheChWkxDiZrlpk7F7eAzt0GEt3_Pv0C_U4rA1hzwwSyqP8HzDzjinEE</recordid><startdate>20240719</startdate><enddate>20240719</enddate><creator>Fatima, Summaya</creator><creator>Zahoor, Ameer Fawad</creator><creator>Khan, Samreen Gul</creator><creator>Naqvi, Syed Ali Raza</creator><creator>Hussain, Syed Makhdoom</creator><creator>Nazeer, Usman</creator><creator>Mansha, Asim</creator><creator>Ahmad, Hamad</creator><creator>Chaudhry, Aijaz Rasool</creator><creator>Irfan, Ahmad</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0003-2127-8848</orcidid></search><sort><creationdate>20240719</creationdate><title>Baeyer-Villiger oxidation: a promising tool for the synthesis of natural products: a review</title><author>Fatima, Summaya ; Zahoor, Ameer Fawad ; Khan, Samreen Gul ; Naqvi, Syed Ali Raza ; Hussain, Syed Makhdoom ; Nazeer, Usman ; Mansha, Asim ; Ahmad, Hamad ; Chaudhry, Aijaz Rasool ; Irfan, Ahmad</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c318t-672d6b86e2f884c15e0411a0432402da1d8ef5608a39c960fec01b0414280f743</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Ketones</topic><topic>Lactones</topic><topic>Natural products</topic><topic>Organic chemistry</topic><topic>Oxidation</topic><topic>Oxidizing agents</topic><topic>Terpenes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fatima, Summaya</creatorcontrib><creatorcontrib>Zahoor, Ameer Fawad</creatorcontrib><creatorcontrib>Khan, Samreen Gul</creatorcontrib><creatorcontrib>Naqvi, Syed Ali Raza</creatorcontrib><creatorcontrib>Hussain, Syed Makhdoom</creatorcontrib><creatorcontrib>Nazeer, Usman</creatorcontrib><creatorcontrib>Mansha, Asim</creatorcontrib><creatorcontrib>Ahmad, Hamad</creatorcontrib><creatorcontrib>Chaudhry, Aijaz Rasool</creatorcontrib><creatorcontrib>Irfan, Ahmad</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fatima, Summaya</au><au>Zahoor, Ameer Fawad</au><au>Khan, Samreen Gul</au><au>Naqvi, Syed Ali Raza</au><au>Hussain, Syed Makhdoom</au><au>Nazeer, Usman</au><au>Mansha, Asim</au><au>Ahmad, Hamad</au><au>Chaudhry, Aijaz Rasool</au><au>Irfan, Ahmad</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Baeyer-Villiger oxidation: a promising tool for the synthesis of natural products: a review</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2024-07-19</date><risdate>2024</risdate><volume>14</volume><issue>32</issue><spage>23423</spage><epage>23458</epage><pages>23423-23458</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Baeyer-Villiger oxidation is a well-known reaction utilized for the synthesis of lactones and ester functionalities from ketones. Chiral lactones can be synthesized from chiral or racemic ketones by employing asymmetric Baeyer-Villiger oxidation. These lactones act as key intermediates in the synthesis of most of the biologically active natural products, their analogues, and derivatives. Various monooxygenases and oxidizing agents facilitate BV oxidation, providing a broad range of synthetic applications in organic chemistry. The variety of enzymatic and chemoselective Baeyer-Villiger oxidations and their substantial role in the synthesis of natural products
i.e.
, alkaloids, polyketides, fatty acids, terpenoids,
etc.
(reported since 2018) have been summarized in this review article.
Baeyer-Villiger oxidation is a renowned reaction that provides an efficient route for the synthesis of biologically active natural products such as alkaloids, terpenoids, polyketides and fatty acid-based naturally occurring organic compounds.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>39055269</pmid><doi>10.1039/d4ra03914a</doi><tpages>36</tpages><orcidid>https://orcid.org/0000-0003-2127-8848</orcidid><oa>free_for_read</oa></addata></record> |
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| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_pubmed_primary_39055269 |
| source | PubMed Central |
| subjects | Chemical synthesis Chemistry Ketones Lactones Natural products Organic chemistry Oxidation Oxidizing agents Terpenes |
| title | Baeyer-Villiger oxidation: a promising tool for the synthesis of natural products: a review |
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