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Ion exchange in semiconductor magic-size clusters
As a crucial post-synthesis method, ion exchange allows for precise control over the composition, interface, and morphology of nanocrystals at the atomic scale, achieving material properties that are difficult to obtain with traditional synthesis techniques. In nanomaterial science, semiconductor ma...
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Published in: | Nanoscale 2024-09, Vol.16 (37), p.1723-17247 |
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creator | Yang, Yuelin Zhang, Haoyang Deng, Yalei Kong, Xinke Wang, Yuanyuan |
description | As a crucial post-synthesis method, ion exchange allows for precise control over the composition, interface, and morphology of nanocrystals at the atomic scale, achieving material properties that are difficult to obtain with traditional synthesis techniques. In nanomaterial science, semiconductor magic-size clusters (MSCs), with their atomic-level precision and unique quantum confinement effects, serve as a bridge between molecules and nanocrystals. Despite this, research on ion exchange in MSCs is still in its infancy. This review introduces the principles of ion exchange and reactions in colloidal nanocrystals and MSCs, analyzing the importance and challenges of ion exchange in studying MSCs. This paper begins with a focus on the current research progress of cation and anion exchange in II-VI and III-V semiconductor MSCs. Then, the common methods for characterizing MSCs during the ion exchange process are discussed. Finally, the article envisions future research directions based on MSCs' ion exchange. Research on MSCs' ion exchange not only aids in designing MSCs with complex functionalities, but also plays an essential role in elucidating the ion exchange mechanisms in nanocrystals, providing new insights for the innovative design and synthesis of nanomaterials.
This review aims to present recent advances in ion exchange of semiconductor magic-size clusters, discussing classification, influencing factors, challenges, and applications, while also providing an outlook on future research directions. |
doi_str_mv | 10.1039/d4nr02769h |
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This review aims to present recent advances in ion exchange of semiconductor magic-size clusters, discussing classification, influencing factors, challenges, and applications, while also providing an outlook on future research directions.</description><identifier>ISSN: 2040-3364</identifier><identifier>ISSN: 2040-3372</identifier><identifier>EISSN: 2040-3372</identifier><identifier>DOI: 10.1039/d4nr02769h</identifier><identifier>PMID: 39219401</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Anion exchanging ; Chemical synthesis ; Clusters ; Colloiding ; Group III-V semiconductors ; Ion exchange ; Material properties ; Nanocrystals ; Nanomaterials ; Quantum confinement</subject><ispartof>Nanoscale, 2024-09, Vol.16 (37), p.1723-17247</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c226t-fbe8995d81621a04b8e81296daad5efe07eaf795fc4f577affbea921ba1945c63</cites><orcidid>0000-0003-3971-8362</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39219401$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Yang, Yuelin</creatorcontrib><creatorcontrib>Zhang, Haoyang</creatorcontrib><creatorcontrib>Deng, Yalei</creatorcontrib><creatorcontrib>Kong, Xinke</creatorcontrib><creatorcontrib>Wang, Yuanyuan</creatorcontrib><title>Ion exchange in semiconductor magic-size clusters</title><title>Nanoscale</title><addtitle>Nanoscale</addtitle><description>As a crucial post-synthesis method, ion exchange allows for precise control over the composition, interface, and morphology of nanocrystals at the atomic scale, achieving material properties that are difficult to obtain with traditional synthesis techniques. In nanomaterial science, semiconductor magic-size clusters (MSCs), with their atomic-level precision and unique quantum confinement effects, serve as a bridge between molecules and nanocrystals. Despite this, research on ion exchange in MSCs is still in its infancy. This review introduces the principles of ion exchange and reactions in colloidal nanocrystals and MSCs, analyzing the importance and challenges of ion exchange in studying MSCs. This paper begins with a focus on the current research progress of cation and anion exchange in II-VI and III-V semiconductor MSCs. Then, the common methods for characterizing MSCs during the ion exchange process are discussed. Finally, the article envisions future research directions based on MSCs' ion exchange. Research on MSCs' ion exchange not only aids in designing MSCs with complex functionalities, but also plays an essential role in elucidating the ion exchange mechanisms in nanocrystals, providing new insights for the innovative design and synthesis of nanomaterials.
This review aims to present recent advances in ion exchange of semiconductor magic-size clusters, discussing classification, influencing factors, challenges, and applications, while also providing an outlook on future research directions.</description><subject>Anion exchanging</subject><subject>Chemical synthesis</subject><subject>Clusters</subject><subject>Colloiding</subject><subject>Group III-V semiconductors</subject><subject>Ion exchange</subject><subject>Material properties</subject><subject>Nanocrystals</subject><subject>Nanomaterials</subject><subject>Quantum confinement</subject><issn>2040-3364</issn><issn>2040-3372</issn><issn>2040-3372</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpd0dtLwzAUBvAgipvTF9-Vgi8iVHNv8yjzssFQEH0uaXqydfQykxbUv97MzQk-JZBfDh_fQeiU4GuCmbopeOMwTaRa7KEhxRzHjCV0f3eXfICOvF9iLBWT7BANmKJEcUyGiEzbJoIPs9DNHKKyiTzUpWmbojdd66Jaz0sT-_ILIlP1vgPnj9GB1ZWHk-05Qm8P96_jSTx7fpyOb2exoVR2sc0hVUoUKZGUaMzzFFJClSy0LgRYwAlomyhhDbciSbQNH3SIleuQTBjJRuhyM3fl2vcefJfVpTdQVbqBtvcZw0qlIhEMB3rxjy7b3jUhXcYIVpKLVK3V1UYZ13rvwGYrV9bafWYEZ-siszv-9PJT5CTg8-3IPq-h2NHf5gI42wDnze71bxPsG9qydu8</recordid><startdate>20240926</startdate><enddate>20240926</enddate><creator>Yang, Yuelin</creator><creator>Zhang, Haoyang</creator><creator>Deng, Yalei</creator><creator>Kong, Xinke</creator><creator>Wang, Yuanyuan</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-3971-8362</orcidid></search><sort><creationdate>20240926</creationdate><title>Ion exchange in semiconductor magic-size clusters</title><author>Yang, Yuelin ; Zhang, Haoyang ; Deng, Yalei ; Kong, Xinke ; Wang, Yuanyuan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c226t-fbe8995d81621a04b8e81296daad5efe07eaf795fc4f577affbea921ba1945c63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Anion exchanging</topic><topic>Chemical synthesis</topic><topic>Clusters</topic><topic>Colloiding</topic><topic>Group III-V semiconductors</topic><topic>Ion exchange</topic><topic>Material properties</topic><topic>Nanocrystals</topic><topic>Nanomaterials</topic><topic>Quantum confinement</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Yuelin</creatorcontrib><creatorcontrib>Zhang, Haoyang</creatorcontrib><creatorcontrib>Deng, Yalei</creatorcontrib><creatorcontrib>Kong, Xinke</creatorcontrib><creatorcontrib>Wang, Yuanyuan</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Nanoscale</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Yuelin</au><au>Zhang, Haoyang</au><au>Deng, Yalei</au><au>Kong, Xinke</au><au>Wang, Yuanyuan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ion exchange in semiconductor magic-size clusters</atitle><jtitle>Nanoscale</jtitle><addtitle>Nanoscale</addtitle><date>2024-09-26</date><risdate>2024</risdate><volume>16</volume><issue>37</issue><spage>1723</spage><epage>17247</epage><pages>1723-17247</pages><issn>2040-3364</issn><issn>2040-3372</issn><eissn>2040-3372</eissn><abstract>As a crucial post-synthesis method, ion exchange allows for precise control over the composition, interface, and morphology of nanocrystals at the atomic scale, achieving material properties that are difficult to obtain with traditional synthesis techniques. In nanomaterial science, semiconductor magic-size clusters (MSCs), with their atomic-level precision and unique quantum confinement effects, serve as a bridge between molecules and nanocrystals. Despite this, research on ion exchange in MSCs is still in its infancy. This review introduces the principles of ion exchange and reactions in colloidal nanocrystals and MSCs, analyzing the importance and challenges of ion exchange in studying MSCs. This paper begins with a focus on the current research progress of cation and anion exchange in II-VI and III-V semiconductor MSCs. Then, the common methods for characterizing MSCs during the ion exchange process are discussed. Finally, the article envisions future research directions based on MSCs' ion exchange. Research on MSCs' ion exchange not only aids in designing MSCs with complex functionalities, but also plays an essential role in elucidating the ion exchange mechanisms in nanocrystals, providing new insights for the innovative design and synthesis of nanomaterials.
This review aims to present recent advances in ion exchange of semiconductor magic-size clusters, discussing classification, influencing factors, challenges, and applications, while also providing an outlook on future research directions.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>39219401</pmid><doi>10.1039/d4nr02769h</doi><tpages>18</tpages><orcidid>https://orcid.org/0000-0003-3971-8362</orcidid></addata></record> |
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source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
subjects | Anion exchanging Chemical synthesis Clusters Colloiding Group III-V semiconductors Ion exchange Material properties Nanocrystals Nanomaterials Quantum confinement |
title | Ion exchange in semiconductor magic-size clusters |
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