Recent advances in the synthesis of transition metal hydroxyl oxide catalysts and their application in electrocatalytic oxygen evolution reactions

• Published in: Nanoscale 2024-11, Vol.16 (43), p.1997-19997
• Main Authors: Zhang, Zhi-Jie, Xu, Hui-Min, Huang, Chen-Jin, Shuai, Ting-Yu, Zhan, Qi-Ni, Li, Gao-Ren
• Format: Article
• Language: English
• Subjects: Catalysts; Chemical synthesis; Electrolysis; Electron transfer; Energy; Energy conversion; Hydrogen evolution reactions; Hydrogen production; Oxygen evolution reactions; Specific energy; Stability; Transition metals
• ISSN: 2040-3364; 2040-3372; 2040-3372
• DOI: 10.1039/d4nr02400a

With the extensive use of fossil energy, people will face the depletion of fossil energy and increasingly severe problems. As a non-polluting, high specific energy density energy source, hydrogen energy is expected to solve this problem by producing hydrogen through electrolysis of water through renewable energy power generation. Water electrolysis technology involves two important half-reactions: the cathode hydrogen evolution reaction (HER) and anode oxygen evolution reaction (OER). The OER is a 4-electron transfer process with a high energy barrier. In order to achieve higher energy conversion, OER catalyst technology is a key part of the process. Researchers have conducted a lot of research into high-performance, high-stability, and highly economical OER catalysts, among which oxyhydroxide (MOOH), as an active substance for OER, has received particular attention. This article provides a timely follow-up to the research on oxyhydroxides, first introducing the two catalytic mechanisms of OER, namely the adsorbate evolution mechanism (AEM) and lattice-oxygen-mediated mechanism (LOM). Then, strategies are proposed to improve OER catalytic performance by increasing catalytic active surface area/active sites, optimizing intermediate adsorption energy based on the AEM, triggering the LOM, and enhancing catalyst stability. Finally, the challenges and future development directions of MOOH catalysts are analyzed, which provides guidance for the design and preparation of high-performance OER catalysts in the future. The oxyhydroxides (MOOH) for oxygen evolution reaction (OER) in recent years is reviewed. The control mechanism of improving OER catalytic performance of MOOH is discussed. Finally, the challenges and future developments of MOOH in OER are analyzed.