Employing the Trifluoromethyl Group on a 5/5 Fused Triazolo[4,3‑b][1,2,4]triazole Backbone: A Viable Strategy for Attaining Balanced Energetics

In this study, we synthesized trifluoromethyl-substituted bis-triazole nitrogen-rich compounds (3–5) using a simple, cost-effective method. The newly made compounds were characterized using NMR, IR, elemental analysis, TGA-DSC, and single-crystal X-ray diffraction (for compounds 3 and 4). They demon...

Full description

Saved in:
Bibliographic Details
Published in:Organic letters 2024-12, Vol.26 (49), p.10611-10615
Main Authors: Kukreja, Sonali, Yadav, Abhishek Kumar, Nehe, Sagar, Dharavath, Srinivas
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:In this study, we synthesized trifluoromethyl-substituted bis-triazole nitrogen-rich compounds (3–5) using a simple, cost-effective method. The newly made compounds were characterized using NMR, IR, elemental analysis, TGA-DSC, and single-crystal X-ray diffraction (for compounds 3 and 4). They demonstrated high density (1.82–1.92 g cm–3), moderate detonation performance (7567–7905 m s–1), good thermal stability (146–215 °C), and low sensitivity to impact (40 J) and friction (360 N), offering high potential nature as a cationic component in energetic salts, defense, and civilian applications.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.4c04134