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Corrosion protection properties of tetraphenylethylene-based inhibitors toward carbon steel in acidic medium
Four novel corrosion inhibitors ( 1 , 2 , 3 and 4 ) integrating different tetraphenylethylene (TPE) cations and thiocyanate (SCN − ) anions were developed. Weight-loss and electrochemical measurements were employed to assess their protective properties toward carbon steel in 0.5 M H 2 SO 4 , reveali...
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| Published in: | RSC advances 2023-03, Vol.13 (12), p.8317-8326 |
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| Main Authors: | , , , , , , , , , , , , , |
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| Language: | English |
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| container_end_page | 8326 |
| container_issue | 12 |
| container_start_page | 8317 |
| container_title | RSC advances |
| container_volume | 13 |
| creator | Chen, Yumeng An, Yiming Ma, Jing Zhang, Zhihua Qiao, Fulin Lei, Xue Sun, Fei Wang, Chunlu Gao, Song Zhao, Yue Wang, Jinhua Fu, Xiaoping Wang, Hui Yu, Zhengqi |
| description | Four novel corrosion inhibitors (
1
,
2
,
3
and
4
) integrating different tetraphenylethylene (TPE) cations and thiocyanate (SCN
−
) anions were developed. Weight-loss and electrochemical measurements were employed to assess their protective properties toward carbon steel in 0.5 M H
2
SO
4
, revealing them as effective corrosion inhibitors in the order of
3
>
4
>
2
>
1
, with the inhibition efficiencies of
2
,
3
and
4
all exceeding 97%. The inhibitory effect could be attributed to hard and soft acids and bases theory and the synergistic effect of the charged ingredients. The efficiency trend of the corrosion inhibition, as well as inhibition mechanism, was verified by multi-scaled theoretical simulations combined with grand canonical Monte Carlo and molecular dynamic methods.
Four corrosion inhibitors containing tetraphenylethylene were synthesized and proved to protect carbon steel effectively in acidic medium. |
| doi_str_mv | 10.1039/d2ra08062a |
| format | article |
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1
,
2
,
3
and
4
) integrating different tetraphenylethylene (TPE) cations and thiocyanate (SCN
−
) anions were developed. Weight-loss and electrochemical measurements were employed to assess their protective properties toward carbon steel in 0.5 M H
2
SO
4
, revealing them as effective corrosion inhibitors in the order of
3
>
4
>
2
>
1
, with the inhibition efficiencies of
2
,
3
and
4
all exceeding 97%. The inhibitory effect could be attributed to hard and soft acids and bases theory and the synergistic effect of the charged ingredients. The efficiency trend of the corrosion inhibition, as well as inhibition mechanism, was verified by multi-scaled theoretical simulations combined with grand canonical Monte Carlo and molecular dynamic methods.
Four corrosion inhibitors containing tetraphenylethylene were synthesized and proved to protect carbon steel effectively in acidic medium.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d2ra08062a</identifier><identifier>PMID: 36926014</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Carbon steels ; Chemistry ; Corrosion effects ; Corrosion inhibitors ; Corrosion mechanisms ; Corrosion prevention ; Molecular dynamics ; Sulfuric acid ; Synergistic effect ; Thiocyanates</subject><ispartof>RSC advances, 2023-03, Vol.13 (12), p.8317-8326</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2023</rights><rights>This journal is © The Royal Society of Chemistry 2023 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c388t-9f9bf4de1a0875372f79136ae0ff8c37fa91a0af40c0f2c7ede79e80827134a83</cites><orcidid>0000-0003-4439-1202</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10012333/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10012333/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,724,777,781,882,27905,27906,53772,53774</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36926014$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Chen, Yumeng</creatorcontrib><creatorcontrib>An, Yiming</creatorcontrib><creatorcontrib>Ma, Jing</creatorcontrib><creatorcontrib>Zhang, Zhihua</creatorcontrib><creatorcontrib>Qiao, Fulin</creatorcontrib><creatorcontrib>Lei, Xue</creatorcontrib><creatorcontrib>Sun, Fei</creatorcontrib><creatorcontrib>Wang, Chunlu</creatorcontrib><creatorcontrib>Gao, Song</creatorcontrib><creatorcontrib>Zhao, Yue</creatorcontrib><creatorcontrib>Wang, Jinhua</creatorcontrib><creatorcontrib>Fu, Xiaoping</creatorcontrib><creatorcontrib>Wang, Hui</creatorcontrib><creatorcontrib>Yu, Zhengqi</creatorcontrib><title>Corrosion protection properties of tetraphenylethylene-based inhibitors toward carbon steel in acidic medium</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>Four novel corrosion inhibitors (
1
,
2
,
3
and
4
) integrating different tetraphenylethylene (TPE) cations and thiocyanate (SCN
−
) anions were developed. Weight-loss and electrochemical measurements were employed to assess their protective properties toward carbon steel in 0.5 M H
2
SO
4
, revealing them as effective corrosion inhibitors in the order of
3
>
4
>
2
>
1
, with the inhibition efficiencies of
2
,
3
and
4
all exceeding 97%. The inhibitory effect could be attributed to hard and soft acids and bases theory and the synergistic effect of the charged ingredients. The efficiency trend of the corrosion inhibition, as well as inhibition mechanism, was verified by multi-scaled theoretical simulations combined with grand canonical Monte Carlo and molecular dynamic methods.
Four corrosion inhibitors containing tetraphenylethylene were synthesized and proved to protect carbon steel effectively in acidic medium.</description><subject>Carbon steels</subject><subject>Chemistry</subject><subject>Corrosion effects</subject><subject>Corrosion inhibitors</subject><subject>Corrosion mechanisms</subject><subject>Corrosion prevention</subject><subject>Molecular dynamics</subject><subject>Sulfuric acid</subject><subject>Synergistic effect</subject><subject>Thiocyanates</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpdkstr3DAQxkVpSMI2l9wbDL2UgFs9bD1OYdm-AoFAac9ClkddBa_lSHJC_vuo2e02yRykge_HzHwaIXRK8CeCmfrc02iwxJyaN-iY4obXFHP19ll-hE5SusEleEsoJ4foiHFFOSbNMRpWIcaQfBirKYYMNu_SCWL2kKrgqgw5mmkN48MAeV2OEerOJOgrP65953OIqcrh3sS-siZ2pUDKAEORK2N97221gd7Pm3fowJkhwcnuXqDf377-Wv2or66_X66WV7VlUuZaOdW5pgdSjImWCeqEIowbwM5Jy4QzqkjGNdhiR62AHoQCiSUVhDVGsgW62Nad5q50tjAWA4Oeot-Y-KCD8fqlMvq1_hPuNMGYUFZigT7uKsRwO0PKeuOThWEwI4Q5aSrbpqFtWxou0IdX6E2Y41j8aSokb6lSRBTqfEvZ8topgttPQ7D-u0j9hf5cPi1yWeCz5_Pv0X9rK8D7LRCT3av_fwJ7BG3fpTw</recordid><startdate>20230308</startdate><enddate>20230308</enddate><creator>Chen, Yumeng</creator><creator>An, Yiming</creator><creator>Ma, Jing</creator><creator>Zhang, Zhihua</creator><creator>Qiao, Fulin</creator><creator>Lei, Xue</creator><creator>Sun, Fei</creator><creator>Wang, Chunlu</creator><creator>Gao, Song</creator><creator>Zhao, Yue</creator><creator>Wang, Jinhua</creator><creator>Fu, Xiaoping</creator><creator>Wang, Hui</creator><creator>Yu, Zhengqi</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0003-4439-1202</orcidid></search><sort><creationdate>20230308</creationdate><title>Corrosion protection properties of tetraphenylethylene-based inhibitors toward carbon steel in acidic medium</title><author>Chen, Yumeng ; An, Yiming ; Ma, Jing ; Zhang, Zhihua ; Qiao, Fulin ; Lei, Xue ; Sun, Fei ; Wang, Chunlu ; Gao, Song ; Zhao, Yue ; Wang, Jinhua ; Fu, Xiaoping ; Wang, Hui ; Yu, Zhengqi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c388t-9f9bf4de1a0875372f79136ae0ff8c37fa91a0af40c0f2c7ede79e80827134a83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Carbon steels</topic><topic>Chemistry</topic><topic>Corrosion effects</topic><topic>Corrosion inhibitors</topic><topic>Corrosion mechanisms</topic><topic>Corrosion prevention</topic><topic>Molecular dynamics</topic><topic>Sulfuric acid</topic><topic>Synergistic effect</topic><topic>Thiocyanates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Yumeng</creatorcontrib><creatorcontrib>An, Yiming</creatorcontrib><creatorcontrib>Ma, Jing</creatorcontrib><creatorcontrib>Zhang, Zhihua</creatorcontrib><creatorcontrib>Qiao, Fulin</creatorcontrib><creatorcontrib>Lei, Xue</creatorcontrib><creatorcontrib>Sun, Fei</creatorcontrib><creatorcontrib>Wang, Chunlu</creatorcontrib><creatorcontrib>Gao, Song</creatorcontrib><creatorcontrib>Zhao, Yue</creatorcontrib><creatorcontrib>Wang, Jinhua</creatorcontrib><creatorcontrib>Fu, Xiaoping</creatorcontrib><creatorcontrib>Wang, Hui</creatorcontrib><creatorcontrib>Yu, Zhengqi</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Yumeng</au><au>An, Yiming</au><au>Ma, Jing</au><au>Zhang, Zhihua</au><au>Qiao, Fulin</au><au>Lei, Xue</au><au>Sun, Fei</au><au>Wang, Chunlu</au><au>Gao, Song</au><au>Zhao, Yue</au><au>Wang, Jinhua</au><au>Fu, Xiaoping</au><au>Wang, Hui</au><au>Yu, Zhengqi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Corrosion protection properties of tetraphenylethylene-based inhibitors toward carbon steel in acidic medium</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2023-03-08</date><risdate>2023</risdate><volume>13</volume><issue>12</issue><spage>8317</spage><epage>8326</epage><pages>8317-8326</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Four novel corrosion inhibitors (
1
,
2
,
3
and
4
) integrating different tetraphenylethylene (TPE) cations and thiocyanate (SCN
−
) anions were developed. Weight-loss and electrochemical measurements were employed to assess their protective properties toward carbon steel in 0.5 M H
2
SO
4
, revealing them as effective corrosion inhibitors in the order of
3
>
4
>
2
>
1
, with the inhibition efficiencies of
2
,
3
and
4
all exceeding 97%. The inhibitory effect could be attributed to hard and soft acids and bases theory and the synergistic effect of the charged ingredients. The efficiency trend of the corrosion inhibition, as well as inhibition mechanism, was verified by multi-scaled theoretical simulations combined with grand canonical Monte Carlo and molecular dynamic methods.
Four corrosion inhibitors containing tetraphenylethylene were synthesized and proved to protect carbon steel effectively in acidic medium.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>36926014</pmid><doi>10.1039/d2ra08062a</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0003-4439-1202</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2046-2069 |
| ispartof | RSC advances, 2023-03, Vol.13 (12), p.8317-8326 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_10012333 |
| source | PubMed Central |
| subjects | Carbon steels Chemistry Corrosion effects Corrosion inhibitors Corrosion mechanisms Corrosion prevention Molecular dynamics Sulfuric acid Synergistic effect Thiocyanates |
| title | Corrosion protection properties of tetraphenylethylene-based inhibitors toward carbon steel in acidic medium |
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