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Effect of regulating the different proportions of Zr to Mn elements on the hydrogen storage properties of titanium-iron-manganese-hydrogen storage alloys
The effect of regulating the different proportions (0, 1 : 3, 1 : 2 and 1 : 1) of Zr to Mn elements on the hydrogen storage properties of TiFe 0.85− x Mn 0.15 Zr x ( x = 0, 0.05, 0.075 and 0.15) alloys was systematically studied in this work. The results showed that all alloys mainly showed TiFe and...
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| Published in: | RSC advances 2023-03, Vol.13 (15), p.1157-1167 |
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| cites | cdi_FETCH-LOGICAL-c429t-fc477e60d5309acd8ee89214c0506fadba81724eb21e55530f72a4647f002c2a3 |
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| container_issue | 15 |
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| creator | Lv, Peng Peng, Cheng Liu, Quanyu Zhong, Changlin Huang, Dongfang Liu, Zhichen Zhou, Quanbao Zhao, Ruixue |
| description | The effect of regulating the different proportions (0, 1 : 3, 1 : 2 and 1 : 1) of Zr to Mn elements on the hydrogen storage properties of TiFe
0.85−
x
Mn
0.15
Zr
x
(
x
= 0, 0.05, 0.075 and 0.15) alloys was systematically studied in this work. The results showed that all alloys mainly showed TiFe and MgZn
2
type phases. The MgZn
2
type phase went up with the proportion of Zr to Mn elements. At the same time, increasing the proportion of Zr to Mn elements enhanced the first hydrogenation properties. In addition, the
x
= 0.15 alloy showed the highest hydrogen storage capacity during the first hydrogenation process. This was because the MgZn
2
type phase could improve the penetration of hydrogen atoms and enhance the diffusion of hydrogen atoms. During the test of prolonged air exposure, it was clear that the oxidation resistance also increased with the proportion of Zr to Mn elements. In addition to this, the effect of the starting particle size was also studied. When the length of the starting particle size was around 0.5 cm, the
x
= 0.05 alloy did not absorb any hydrogen within 1500 seconds. However, the
x
= 0.15 alloy could be activated in only around 100 seconds. Finally, the rate limiting step of the first hydrogenation and PCT properties were also investigated.
Increasing the proportion of Zr to Mn elements enhanced the first hydrogenation properties and oxidation resistance of TiFe
0.85−
x
Mn
0.15
Zr
x
(
x
= 0, 0.05, 0.075 and 0.15) alloys. |
| doi_str_mv | 10.1039/d3ra01131c |
| format | article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_10069393</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2795922125</sourcerecordid><originalsourceid>FETCH-LOGICAL-c429t-fc477e60d5309acd8ee89214c0506fadba81724eb21e55530f72a4647f002c2a3</originalsourceid><addsrcrecordid>eNplkl1rFDEUhoNYbKm98V4JeCOF0XzMZCZXUrb1AyqC6I03IZs5mU2ZSdYkI-xP6b9tdreureYmIe_zvpyTE4ReUPKWEi7f9TxqQimn5gk6YaQWFSNCPn1wPkZnKd2QskRDmaDP0DFvCSNdJ07Q7ZW1YDIOFkcY5lFn5wecV4B7V5QIPuN1DOsQsws-bbmfEeeAv3gMI0xFL5d-51ht-hgG8DjlEPUAOyMUI-x82WXt3TxVLgZfTdoP2kOC6j-bHsewSc_RkdVjgrP7_RT9-HD1ffGpuv768fPi4royNZO5sqZuWxCkbziR2vQdQCcZrQ1piLC6X-qOtqyGJaPQNAWyLdO1qFtLCDNM81P0fp-7npcT9KZ0FPWo1tFNOm5U0E49VrxbqSH8VrQ8qOSSl4Q39wkx_JohZTW5ZGAcS39hToq1sqW1IF1d0Nf_oDdhjr70t6UayRhlTaHO95SJIaUI9lANJWo7dXXJv13spr4o8KuH9R_QPzMuwMs9EJM5qH-_Db8Ddd20-Q</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2795922125</pqid></control><display><type>article</type><title>Effect of regulating the different proportions of Zr to Mn elements on the hydrogen storage properties of titanium-iron-manganese-hydrogen storage alloys</title><source>PubMed Central</source><creator>Lv, Peng ; Peng, Cheng ; Liu, Quanyu ; Zhong, Changlin ; Huang, Dongfang ; Liu, Zhichen ; Zhou, Quanbao ; Zhao, Ruixue</creator><creatorcontrib>Lv, Peng ; Peng, Cheng ; Liu, Quanyu ; Zhong, Changlin ; Huang, Dongfang ; Liu, Zhichen ; Zhou, Quanbao ; Zhao, Ruixue</creatorcontrib><description>The effect of regulating the different proportions (0, 1 : 3, 1 : 2 and 1 : 1) of Zr to Mn elements on the hydrogen storage properties of TiFe
0.85−
x
Mn
0.15
Zr
x
(
x
= 0, 0.05, 0.075 and 0.15) alloys was systematically studied in this work. The results showed that all alloys mainly showed TiFe and MgZn
2
type phases. The MgZn
2
type phase went up with the proportion of Zr to Mn elements. At the same time, increasing the proportion of Zr to Mn elements enhanced the first hydrogenation properties. In addition, the
x
= 0.15 alloy showed the highest hydrogen storage capacity during the first hydrogenation process. This was because the MgZn
2
type phase could improve the penetration of hydrogen atoms and enhance the diffusion of hydrogen atoms. During the test of prolonged air exposure, it was clear that the oxidation resistance also increased with the proportion of Zr to Mn elements. In addition to this, the effect of the starting particle size was also studied. When the length of the starting particle size was around 0.5 cm, the
x
= 0.05 alloy did not absorb any hydrogen within 1500 seconds. However, the
x
= 0.15 alloy could be activated in only around 100 seconds. Finally, the rate limiting step of the first hydrogenation and PCT properties were also investigated.
Increasing the proportion of Zr to Mn elements enhanced the first hydrogenation properties and oxidation resistance of TiFe
0.85−
x
Mn
0.15
Zr
x
(
x
= 0, 0.05, 0.075 and 0.15) alloys.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d3ra01131c</identifier><identifier>PMID: 37020886</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Alloys ; Chemistry ; Hydrogen ; Hydrogen atoms ; Hydrogen storage materials ; Hydrogenation ; Manganese ; Oxidation resistance ; Particle size ; Storage capacity ; Zirconium</subject><ispartof>RSC advances, 2023-03, Vol.13 (15), p.1157-1167</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2023</rights><rights>This journal is © The Royal Society of Chemistry 2023 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c429t-fc477e60d5309acd8ee89214c0506fadba81724eb21e55530f72a4647f002c2a3</citedby><cites>FETCH-LOGICAL-c429t-fc477e60d5309acd8ee89214c0506fadba81724eb21e55530f72a4647f002c2a3</cites><orcidid>0000-0002-0061-2053</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10069393/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10069393/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,27924,27925,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37020886$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Lv, Peng</creatorcontrib><creatorcontrib>Peng, Cheng</creatorcontrib><creatorcontrib>Liu, Quanyu</creatorcontrib><creatorcontrib>Zhong, Changlin</creatorcontrib><creatorcontrib>Huang, Dongfang</creatorcontrib><creatorcontrib>Liu, Zhichen</creatorcontrib><creatorcontrib>Zhou, Quanbao</creatorcontrib><creatorcontrib>Zhao, Ruixue</creatorcontrib><title>Effect of regulating the different proportions of Zr to Mn elements on the hydrogen storage properties of titanium-iron-manganese-hydrogen storage alloys</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>The effect of regulating the different proportions (0, 1 : 3, 1 : 2 and 1 : 1) of Zr to Mn elements on the hydrogen storage properties of TiFe
0.85−
x
Mn
0.15
Zr
x
(
x
= 0, 0.05, 0.075 and 0.15) alloys was systematically studied in this work. The results showed that all alloys mainly showed TiFe and MgZn
2
type phases. The MgZn
2
type phase went up with the proportion of Zr to Mn elements. At the same time, increasing the proportion of Zr to Mn elements enhanced the first hydrogenation properties. In addition, the
x
= 0.15 alloy showed the highest hydrogen storage capacity during the first hydrogenation process. This was because the MgZn
2
type phase could improve the penetration of hydrogen atoms and enhance the diffusion of hydrogen atoms. During the test of prolonged air exposure, it was clear that the oxidation resistance also increased with the proportion of Zr to Mn elements. In addition to this, the effect of the starting particle size was also studied. When the length of the starting particle size was around 0.5 cm, the
x
= 0.05 alloy did not absorb any hydrogen within 1500 seconds. However, the
x
= 0.15 alloy could be activated in only around 100 seconds. Finally, the rate limiting step of the first hydrogenation and PCT properties were also investigated.
Increasing the proportion of Zr to Mn elements enhanced the first hydrogenation properties and oxidation resistance of TiFe
0.85−
x
Mn
0.15
Zr
x
(
x
= 0, 0.05, 0.075 and 0.15) alloys.</description><subject>Alloys</subject><subject>Chemistry</subject><subject>Hydrogen</subject><subject>Hydrogen atoms</subject><subject>Hydrogen storage materials</subject><subject>Hydrogenation</subject><subject>Manganese</subject><subject>Oxidation resistance</subject><subject>Particle size</subject><subject>Storage capacity</subject><subject>Zirconium</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNplkl1rFDEUhoNYbKm98V4JeCOF0XzMZCZXUrb1AyqC6I03IZs5mU2ZSdYkI-xP6b9tdreureYmIe_zvpyTE4ReUPKWEi7f9TxqQimn5gk6YaQWFSNCPn1wPkZnKd2QskRDmaDP0DFvCSNdJ07Q7ZW1YDIOFkcY5lFn5wecV4B7V5QIPuN1DOsQsws-bbmfEeeAv3gMI0xFL5d-51ht-hgG8DjlEPUAOyMUI-x82WXt3TxVLgZfTdoP2kOC6j-bHsewSc_RkdVjgrP7_RT9-HD1ffGpuv768fPi4royNZO5sqZuWxCkbziR2vQdQCcZrQ1piLC6X-qOtqyGJaPQNAWyLdO1qFtLCDNM81P0fp-7npcT9KZ0FPWo1tFNOm5U0E49VrxbqSH8VrQ8qOSSl4Q39wkx_JohZTW5ZGAcS39hToq1sqW1IF1d0Nf_oDdhjr70t6UayRhlTaHO95SJIaUI9lANJWo7dXXJv13spr4o8KuH9R_QPzMuwMs9EJM5qH-_Db8Ddd20-Q</recordid><startdate>20230327</startdate><enddate>20230327</enddate><creator>Lv, Peng</creator><creator>Peng, Cheng</creator><creator>Liu, Quanyu</creator><creator>Zhong, Changlin</creator><creator>Huang, Dongfang</creator><creator>Liu, Zhichen</creator><creator>Zhou, Quanbao</creator><creator>Zhao, Ruixue</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-0061-2053</orcidid></search><sort><creationdate>20230327</creationdate><title>Effect of regulating the different proportions of Zr to Mn elements on the hydrogen storage properties of titanium-iron-manganese-hydrogen storage alloys</title><author>Lv, Peng ; Peng, Cheng ; Liu, Quanyu ; Zhong, Changlin ; Huang, Dongfang ; Liu, Zhichen ; Zhou, Quanbao ; Zhao, Ruixue</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c429t-fc477e60d5309acd8ee89214c0506fadba81724eb21e55530f72a4647f002c2a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Alloys</topic><topic>Chemistry</topic><topic>Hydrogen</topic><topic>Hydrogen atoms</topic><topic>Hydrogen storage materials</topic><topic>Hydrogenation</topic><topic>Manganese</topic><topic>Oxidation resistance</topic><topic>Particle size</topic><topic>Storage capacity</topic><topic>Zirconium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lv, Peng</creatorcontrib><creatorcontrib>Peng, Cheng</creatorcontrib><creatorcontrib>Liu, Quanyu</creatorcontrib><creatorcontrib>Zhong, Changlin</creatorcontrib><creatorcontrib>Huang, Dongfang</creatorcontrib><creatorcontrib>Liu, Zhichen</creatorcontrib><creatorcontrib>Zhou, Quanbao</creatorcontrib><creatorcontrib>Zhao, Ruixue</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lv, Peng</au><au>Peng, Cheng</au><au>Liu, Quanyu</au><au>Zhong, Changlin</au><au>Huang, Dongfang</au><au>Liu, Zhichen</au><au>Zhou, Quanbao</au><au>Zhao, Ruixue</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of regulating the different proportions of Zr to Mn elements on the hydrogen storage properties of titanium-iron-manganese-hydrogen storage alloys</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2023-03-27</date><risdate>2023</risdate><volume>13</volume><issue>15</issue><spage>1157</spage><epage>1167</epage><pages>1157-1167</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>The effect of regulating the different proportions (0, 1 : 3, 1 : 2 and 1 : 1) of Zr to Mn elements on the hydrogen storage properties of TiFe
0.85−
x
Mn
0.15
Zr
x
(
x
= 0, 0.05, 0.075 and 0.15) alloys was systematically studied in this work. The results showed that all alloys mainly showed TiFe and MgZn
2
type phases. The MgZn
2
type phase went up with the proportion of Zr to Mn elements. At the same time, increasing the proportion of Zr to Mn elements enhanced the first hydrogenation properties. In addition, the
x
= 0.15 alloy showed the highest hydrogen storage capacity during the first hydrogenation process. This was because the MgZn
2
type phase could improve the penetration of hydrogen atoms and enhance the diffusion of hydrogen atoms. During the test of prolonged air exposure, it was clear that the oxidation resistance also increased with the proportion of Zr to Mn elements. In addition to this, the effect of the starting particle size was also studied. When the length of the starting particle size was around 0.5 cm, the
x
= 0.05 alloy did not absorb any hydrogen within 1500 seconds. However, the
x
= 0.15 alloy could be activated in only around 100 seconds. Finally, the rate limiting step of the first hydrogenation and PCT properties were also investigated.
Increasing the proportion of Zr to Mn elements enhanced the first hydrogenation properties and oxidation resistance of TiFe
0.85−
x
Mn
0.15
Zr
x
(
x
= 0, 0.05, 0.075 and 0.15) alloys.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>37020886</pmid><doi>10.1039/d3ra01131c</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-0061-2053</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
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| ispartof | RSC advances, 2023-03, Vol.13 (15), p.1157-1167 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_10069393 |
| source | PubMed Central |
| subjects | Alloys Chemistry Hydrogen Hydrogen atoms Hydrogen storage materials Hydrogenation Manganese Oxidation resistance Particle size Storage capacity Zirconium |
| title | Effect of regulating the different proportions of Zr to Mn elements on the hydrogen storage properties of titanium-iron-manganese-hydrogen storage alloys |
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