Multi-Block Copolymer Membranes Consisting of Sulfonated Poly( p -phenylene) and Naphthalene Containing Poly(arylene Ether Ketone) for Proton Exchange Membrane Water Electrolysis

Glassy hydrocarbon-based membranes are being researched as a replacement for perfluorosulfonic acid (PFSA) membranes in proton exchange membrane water electrolysis (PEMWE). Here, naphthalene containing Poly(arylene Ether Ketone) was introduced into the Poly( -phenylene)-based multi-block copolymers...

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Published in:Polymers 2023-03, Vol.15 (7), p.1748
Main Authors: Ko, Eui Jin, Lee, Eunju, Lee, Jang Yong, Yu, Duk Man, Yoon, Sang Jun, Oh, Keun-Hwan, Hong, Young Taik, So, Soonyong
Format: Article
Language:English
Subjects:
Block copolymers
Copolymers
Electrolysis
Electrolytic cells
Gases
Hydrocarbons
Hydrogen
Ion exchange
Ketones
Mechanical properties
Membranes
Naphthalene
NMR
Nuclear magnetic resonance
Permeability
Physical properties
Polymers
Protons
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Summary:Glassy hydrocarbon-based membranes are being researched as a replacement for perfluorosulfonic acid (PFSA) membranes in proton exchange membrane water electrolysis (PEMWE). Here, naphthalene containing Poly(arylene Ether Ketone) was introduced into the Poly( -phenylene)-based multi-block copolymers through Ni(0)-catalyzed coupling reaction to enhance interactions of the naphthalene units. It is discovered that there is an optimum input ratio of the hydrophilic monomer and NBP oligomer for the multi-block copolymers with high ion exchange capacity (IEC) and polymerization yield. With the optimum input ratio, the naphthalene containing copolymer exhibits good hydrogen gas barrier property, chemical stability, and mechanical toughness, even with its high IEC value over 2.4 meq g . The membrane shows 3.6 times higher proton selectivity to hydrogen gas than Nafion 212. The PEMWE single cells using the membrane performed better (5.5 A cm ) than Nafion 212 (4.75 A cm ) at 1.9 V and 80 °C. These findings suggest that naphthalene containing copolymer membranes are a promising replacement for PFSA membranes in PEMWE.
ISSN:2073-4360
2073-4360
DOI:10.3390/polym15071748