Mesoporous carbon nitride supported MgO for enhanced CO2 capture

• Published in: Environmental science and pollution research international 2023-04, Vol.30 (18), p.53817-53832
• Main Authors: Refaat, Zakaria, Saied, Mohamed El, Naga, Ahmed O. Abo El, Shaban, Seham A., Hassan, Hanaa B., Shehata, Mohamed Refaat, Kady, Fathy Y. El
• Format: Article
• Language: English
• Subjects: Adsorbents; Adsorption; Anthropogenic factors; Aquatic Pollution; Atmospheric Protection/Air Quality Control/Air Pollution; Carbon dioxide; Carbon dioxide emissions; Carbon nitride; Carbon sequestration; Earth and Environmental Science; Ecotoxicology; Efficiency; Emissions; Endothermic reactions; Environment; Environmental Chemistry; Environmental Health; Environmental science; Fixed beds; Flow rates; Flow velocity; Fossil fuels; Global warming; Human influences; Magnesium oxide; Porous materials; Research Article; Sorbents; Waste Water Technology; Water Management; Water Pollution Control; Zeolites
• ISSN: 1614-7499; 0944-1344; 1614-7499
• DOI: 10.1007/s11356-023-26013-5

The growing concern about the environmental consequences of anthropogenic CO 2 emissions significantly stimulated the research of low-cost, efficient, and recyclable solid adsorbents for CO 2 capture. In this work, a series of MgO-supported mesoporous carbon nitride adsorbents with different MgO contents (xMgO/MCN) was prepared using a facile process. The obtained materials were tested for CO 2 capture from 10 vol% CO 2 mixture gas with N 2 using a fixed bed adsorber at atmospheric pressure. At 25 ºC, the bare MCN support and unsupported MgO samples demonstrated CO 2 capture capacities of 0.99, and 0.74 mmol g −1 , respectively, which were lower than those of the xMgO/MCN composites.The incorporation of MgO into the MCN improved the CO 2 uptake, and the 20MgO/MCN exhibited the highest CO 2 capture capacity of 1.15 mmol g −1 at 25 °C. The improved performance of the 20MgO/MCN nanohybrid can be possibly assigned to the presence of high content of highly dispersed MgO NPs along with its improved textural properties in terms of high specific surface area (215 m 2 g −1 ), large pore volume (0.22 cm 3 g −1 ), and abundant mesoporous structure. The efffects of temperature and CO 2 flow rate were also investigated on the CO 2 capture performance of 20MgO/MCN. Temperature was found to have a negative influence on the CO 2 capture capacity of the 20MgO/MCN, which decreased from 1.15 to 0.65 mmol g −1 with temperature rise from 25 C to 150º C, due to the endothermicity of the process. Similarly, the capture capacity decreased from 1.15 to 0.54 mmol g −1 with the increase of the flow rate from 50 to 200 ml minute −1 respectively. Importantly, 20MgO/MCN showed excellent reusability with consistent CO 2 capture capacity over five sequential sorption–desorption cycles, suggesting its suitability for the practical capture of CO 2 .