Structural Motifs in Aryl Organogermanium Ge-O Derivatives for Material Design

The aim of this work was to understand the main structural features and ways of formation of Ge-O bonds in organogermanium compounds under the conditions of ArnGeHal4-n (Hal = halide) hydrolysis. The structural types of these compounds were considered, providing 11 blocks (A–K). The molecular struct...

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Bibliographic Details
Published in:International journal of molecular sciences 2023-09, Vol.24 (17), p.13575
Main Authors: Zaitsev, Kirill V., Makarov, Igor S., Oprunenko, Yuri F., Tafeenko, Victor A., Lermontova, Elmira Kh, Churakov, Andrei V.
Format: Article
Language:English
Subjects:
Crystallization
Fluorides
Ions
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Summary:The aim of this work was to understand the main structural features and ways of formation of Ge-O bonds in organogermanium compounds under the conditions of ArnGeHal4-n (Hal = halide) hydrolysis. The structural types of these compounds were considered, providing 11 blocks (A–K). The molecular structures of the novel compounds [(p-FC6H4)3Ge]2O (1), [(p-F3CC6H4)3Ge]2O (2), and cyclo-[(p-F3CC6H4)2GeO]4 (3) were studied through XRD (X-ray diffraction) analysis. The molecular structure of [(p-F3CC6H4)3GeO]4Ge (4), representing a novel structural type, was also investigated. The data presented in this study will be important in the design of materials with useful properties based on group 14 element derivatives with element–oxygen bonding.
ISSN:1422-0067
1661-6596
1422-0067
DOI:10.3390/ijms241713575