Performance evaluation of PdO/ CuO TiO2 photocatalytic membrane on ceramic support for removing pharmaceutical compounds from water

• Published in: Journal of environmental health science and engineering 2023-12, Vol.21 (2), p.389-401
• Main Authors: Ghaderi, Samaneh, Lahafchi, Roxana Taleb, Jamshidi, Sona
• Format: Article
• Language: English
• Subjects: Aqueous solutions; Copper oxide; Copper oxides; Cuprite; Degradation; Diffraction; Diphenhydramine; Earth and Environmental Science; Energy bands; Environment; Environmental Economics; Environmental Engineering/Biotechnology; Environmental Health; Environmental Law/Policy/Ecojustice; Flow rates; Fourier transforms; Infrared spectroscopy; Irradiation; Light diffraction; Light scattering; Light sources; Membranes; Metronidazole; Palladium; Performance evaluation; pH effects; Pharmaceuticals; Photocatalysis; Photodegradation; Photon correlation spectroscopy; Quality of Life Research; Research Article; Scanning electron microscopy; Stability tests; Titanium dioxide; Ultraviolet radiation; Waste Management/Waste Technology; X ray powder diffraction; X-rays
• ISSN: 2052-336X; 2052-336X
• DOI: 10.1007/s40201-023-00866-x

This study investigated photocatalytic degradation of pharmaceutical compound using CuO or PdO–TiO 2 membrane. The synthesized membranes were characterized by some techniques including X-ray powder diffraction (XRD), dynamic light scattering (DLS), scanning electron microscopy (SEM), and Fourier-transform infrared spectroscopy (FT-IR). The structural properties confirmed that the photocatalytic membranes were successfully prepared on ceramic supports. The PdO-TiO 2 and CuO-TiO 2 membranes were employed as photocatalytic membranes to degrade metronidazole (MNZ) and diphenhydramine (DPH) in aqueous solutions, respectively. Some parameters affecting the photocatalytic reaction such as pH, initial concentration, and light source were also investigated. The maximum degradation for both pharmaceutical compounds was obtained at basic pH (pH = 10), low initial concentration (C 0  = 10 ppm) under UV irradiation. At high transmembrane pressure (ΔP = 3 bar), the flow rate across the membrane increased up 0.0078 and 0.0082 cc/s.cm 2 for CuO-TiO 2 and PdO-TiO 2 photocatalytic membrane respectively while not affected on degradation efficiency (DE). At the same condition operation (C 0  = 10 ppm, pH = 10, ΔP = 2 bar under UV irradiation), the MNZ and DPH degradation of the PdO-TiO 2 membrane was 94 and 95% respectively that relatively higher than the CuO-TiO 2 membrane. It is probably due to the lower energy band gap of PdO-TiO 2 (2.5 eV) than CuO-TiO 2 (2.7 eV). The membrane stability tests confirmed the high performance of the prepared membranes.