Stability of Viscoelastic Solutions: BrijL4 and Sodium Cholate Mixtures with Metal Ions Across a Broad pH and Temperature Range

• Published in: Langmuir 2024-01, Vol.40 (3), p.1707-1716
• Main Authors: Warmbier, Ewelina, Altaee, Ali, Różański, Jacek, Kazwini, Tayma, Różańska, Sylwia, Ibrar, Ibrar, Wagner, Patrycja, Al-Ejji, Maryam, Hawari, Alaa H.
• Format: Article
• Language: English
• ISSN: 0743-7463; 1520-5827; 1520-5827
• DOI: 10.1021/acs.langmuir.3c02879

The impact of pH, temperature, and metal ions on the rheological and interfacial properties of aqueous mixed surfactant solutions composed of anionic NaC (sodium cholate) and nonionic BrijL4 [polyoxyethylene (4) lauryl ether] surfactants has been investigated. The various compound systems were analyzed, considering variations in each selected factor. The results highlight the unique characteristics of the BrijL4/NaC mixture, suggesting its potential as a viable alternative to other existing surfactants. The synergistic effect between BrijL4 and NaC significantly reduces the critical micelle concentration (CMC) and improves the wetting properties on hydrophobic surfaces, surpassing those of single-component solutions. Additionally, sodium, calcium, and magnesium ions enhance surface wetting and decrease the CMC. Besides, the BrijL4/NaC solutions exhibit viscoelastic fluid behavior at higher surfactant concentrations. These viscoelastic BrijL4/NaC solutions demonstrate stability over various pH and temperature variations, exhibiting lower flow activation and scission energy values than those of other viscoelastic surfactant solutions. Notably, the BrijL4/NaC mixture has potential applications in gel-based foliar fertilizers and drug delivery systems. Furthermore, the rheological studies examine the impact of humic acid on the rheological properties of BrijL4/NaC mixture solutions, revealing that incorporating additional humic acids can achieve stable rheological properties.