Secondary Organic Aerosol from OH-Initiated Oxidation of Mixtures of d‑Limonene and β‑Myrcene

• Published in: Environmental science & technology 2024-07, Vol.58 (30), p.13391-13401
• Main Authors: Liu, Sijia, Galeazzo, Tommaso, Valorso, Richard, Shiraiwa, Manabu, Faiola, Celia L., Nizkorodov, Sergey A.
• Format: Article
• Language: English
• Subjects: acyclic monoterpene; Aerosols; Chemical composition; Chemical interactions; cross-reaction product; cyclic monoterpene; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Ionization; Limonene; Liquid chromatography; Mass spectra; Mass spectrometry; Mass spectroscopy; Mixtures; Myrcene; Occurrence, Fate, and Transport of Contaminants in Indoor Air and Atmosphere; oligomer; oligomers; Oxidation; Physical properties; Smog; stressed-plant emissions; thermodynamic properties; viscosity; volatile organic compounds; volatility
• ISSN: 0013-936X; 1520-5851; 1520-5851
• DOI: 10.1021/acs.est.4c04870

The chemical composition and physical properties of secondary organic aerosol (SOA) generated through OH-initiated oxidation of mixtures containing β-myrcene, an acyclic monoterpene, and d-limonene, a cyclic monoterpene, were investigated to assess the extent of the chemical interactions between their oxidation products. The SOA samples were prepared in an environmental smog chamber, and their composition was analyzed offline using ultraperformance liquid chromatography coupled with electrospray ionization high-resolution mass spectrometry (UPLC-ESI-HRMS). Our results suggested that SOA containing β-myrcene showed a higher proportion of oligomeric compounds with low volatility compared to that of SOA from d-limonene. The formula distribution and signal intensities of the mixed SOA could be accurately predicted by a linear combination of the mass spectra of the SOA from individual precursors. Effects of cross-reactions were observed in the distribution of isomeric oxidation products within the mixed SOA, as made evident by chromatographic analysis. On the whole, β-myrcene and d-limonene appear to undergo oxidation by OH largely independently from each other, with only subtle effects from cross-reactions influencing the yields of specific oxidation products.