Dicarbonyl-1κ2C-μ-chlorido-2:3κ2Cl:Cl-penta­chlorido-2κ2Cl,3κ3Cl-[1(η6)-toluene]digallium(III)ruthenium(I)(Ru—Ga)

The title compound is a ruthenium–gallium metal cluster. The ruthenium and gallium have a direct metal–metal bond with a length of 2.4575 (2) Å. The title compound, [RuGa 2 Cl 6 (C 7 H 8 )(CO) 2 ] or [(CO) 2 (GaCl 2 )(η 6 -toluene)Ru] + [GaCl 4 ] − , was isolated from the reaction of Ga 2 Cl 4 with...

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Bibliographic Details
Published in:IUCrData 2024-07, Vol.9 (Pt 7)
Main Authors: Smith, Danielle, Harakas, George N.
Format: Article
Language:English
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Summary:The title compound is a ruthenium–gallium metal cluster. The ruthenium and gallium have a direct metal–metal bond with a length of 2.4575 (2) Å. The title compound, [RuGa 2 Cl 6 (C 7 H 8 )(CO) 2 ] or [(CO) 2 (GaCl 2 )(η 6 -toluene)Ru] + [GaCl 4 ] − , was isolated from the reaction of Ga 2 Cl 4 with di­phenyl­silanediol in toluene, followed by the addition of Ru 3 (CO) 12 . The compound contains a ruthenium–gallium metal–metal bond with a length of 2.4575 (2) Å.
ISSN:2414-3146
DOI:10.1107/S2414314624006576