Terahertz spectroscopy of collective charge density wave dynamics at the atomic scale

• Published in: Nature physics 2024, Vol.20 (10), p.1603-1608
• Main Authors: Sheng, Shaoxiang, Abdo, Mohamad, Rolf-Pissarczyk, Steffen, Lichtenberg, Kurt, Baumann, Susanne, Burgess, Jacob A. J., Malavolti, Luigi, Loth, Sebastian
• Format: Article
• Language: English
• Subjects: 140/125; 639/301/119/995; 639/624/400/561; 639/925/357/995; Atomic; Chalcogenides; Charge density waves; Charge materials; Classical and Continuum Physics; Complex Systems; Condensed Matter Physics; Defects; Dynamic structural analysis; Dynamics; Electric fields; Electron density; Excitation; Heterogeneity; Impurities; Mathematical and Computational Physics; Molecular; Optical and Plasma Physics; Physics; Physics and Astronomy; Spatial resolution; Spectroscopy; Spectrum analysis; Terahertz frequencies; Theoretical; Transition metal compounds
• ISSN: 1745-2473; 1745-2481
• DOI: 10.1038/s41567-024-02552-7

Charge density waves are wave-like modulations of a material’s electron density that display collective amplitude and phase dynamics. The interaction with atomic impurities induces strong spatial heterogeneity of the charge-ordered phase. Direct real-space observation of phase excitation dynamics of such defect-induced charge modulation is absent. Here, by utilizing terahertz pump–probe spectroscopy in a scanning tunnelling microscope, we measure the ultrafast collective dynamics of the charge density wave in the transition metal dichalcogenide 2H-NbSe 2 with atomic spatial resolution. The tip-enhanced electric field of the terahertz pulses excites oscillations of the charge density wave that vary in magnitude and frequency on the scale of individual atomic impurities. Overlapping phase excitations originating from the randomly distributed atomic defects in the surface create this spatially structured response of the charge density wave. This ability to observe collective charge order dynamics with local probes makes it possible to study the dynamics of correlated materials at the intrinsic length scale of their underlying interactions. The observation of phase modes of charge density wave has been a long-standing challenge. Such low-energy phase excitations have now been seen in a transition metal dichalcogenide.