Effect of Butadiene Rubber Crystallization on Low-Temperature Properties of Butadiene/Silicone Rubber Blends with Potential for Mars Applications

This study explores the impact of butadiene rubber (BR) crystallization on the low-temperature properties of butadiene/silicone (VMQ) rubber blends (BR/VMQ) designed for Martian applications. Two types of BR, semi-crystalline high-cis Buna CB24 and amorphous Buna CB550, were blended with VMQ, and th...

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Published in:Materials 2024-10, Vol.17 (19), p.4857
Main Authors: Nizel, Norbert, Bieliński, Dariusz M, Pawlak, Andrzej, Maciejewska, Magdalena, Wręczycki, Jakub, Masłowski, Marcin, Anyszka, Rafał
Format: Article
Language:English
Subjects:
Amorphous materials
Atmosphere
Butadiene
Calorimetry
Carbon black
Crosslinked polymers
Crystallization
Fourier transforms
Investigations
Low temperature
Mars
Mars (Planet)
Mechanical analysis
Mechanical properties
Mixtures
Polymers
Rubber
Silica
Silicone rubber
Silicones
Temperature
Thermal properties
Thermodynamic properties
Vulcanization
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container_issue 19
container_start_page 4857
container_title Materials
container_volume 17
creator Nizel, Norbert
Bieliński, Dariusz M
Pawlak, Andrzej
Maciejewska, Magdalena
Wręczycki, Jakub
Masłowski, Marcin
Anyszka, Rafał
description This study explores the impact of butadiene rubber (BR) crystallization on the low-temperature properties of butadiene/silicone (VMQ) rubber blends (BR/VMQ) designed for Martian applications. Two types of BR, semi-crystalline high-cis Buna CB24 and amorphous Buna CB550, were blended with VMQ, and their mechanical and thermal properties were evaluated. Kinetics of vulcanization, static mechanical properties, dynamical mechanical analysis, thermal shrinkage, and differential scanning calorimetry were utilized. The research demonstrates that the semi-crystalline BR improves mechanical properties but induces greater shrinkage at low temperatures. Conversely, using amorphous BR provided more consistent mechanical properties across the Martian temperature range and reduced material shrink by 6.71% for samples with carbon black, by 8.36% for samples with silica, and by 11.63% for unfilled samples. Future research will be required to evaluate the impact of volume change on the sealing properties of the BR/VMQ blends.
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source Publicly Available Content (ProQuest); PubMed Central; Free Full-Text Journals in Chemistry
subjects Amorphous materials
Atmosphere
Butadiene
Calorimetry
Carbon black
Crosslinked polymers
Crystallization
Fourier transforms
Investigations
Low temperature
Mars
Mars (Planet)
Mechanical analysis
Mechanical properties
Mixtures
Polymers
Rubber
Silica
Silicone rubber
Silicones
Temperature
Thermal properties
Thermodynamic properties
Vulcanization
title Effect of Butadiene Rubber Crystallization on Low-Temperature Properties of Butadiene/Silicone Rubber Blends with Potential for Mars Applications
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