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Modification of cellulose with TiO2 nanoparticles: Potential solar driven photocatalyst and adsorbent
In-situ modification of cellulose fibers with titania nanoparticles (TiO 2 NPs) (TiO 2 NPs-cellulose) was carried out via the sol–gel process using titania sol and fibers of cellulose. Cellulose fibers were extracted from wheat straw, an agricultural waste material, whereas titania sol was prepared...
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| Published in: | Journal of environmental health science and engineering 2024-06, Vol.22 (1), p.167-178 |
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| Language: | English |
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| container_end_page | 178 |
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| container_start_page | 167 |
| container_title | Journal of environmental health science and engineering |
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| creator | Sharma, Deepti Mishra, Jai Prakash Dhayal, Veena |
| description | In-situ
modification of cellulose fibers with titania nanoparticles (TiO
2
NPs) (TiO
2
NPs-cellulose) was carried out via the sol–gel process using titania sol and fibers of cellulose. Cellulose fibers were extracted from wheat straw, an agricultural waste material, whereas titania sol was prepared from titanium(IV) acetoximate, [Ti{ONC(CH
3
)
2
}
4
]. The synthesized TiO
2
NPs-cellulose composite was characterized by FT-IR, SEM–EDX, and XRD analyses. The obtained results exposed that TiO
2
NPs were homogeneously dispersed over the surface of cellulose fibers. A study was conducted to compare the photocatalytic activities of TiO
2
NPs-cellulose composite and TiO
2
NPs towards the degradation of methylene blue and methyl orange dyes under sunlight, and it was observed that the photo-degradation of methylene blue (99.99%) and methyl orange (80.73%) within 160 min is higher in the presence of TiO
2
NPs-cellulose composite than TiO
2
NPs. The adsorption capabilities of TiO
2
NPs-cellulose composite towards Pb
2+
, Cd
2+
, and Cr
3+
toxic metal ions were also examined, and it was found 44.73 mg. g
−1
(89.46%), 38.82 mg. g
−1
(77.65%), and 4.42 mg. g
−1
(8.85%), respectively. Removal of pollutants from textile industrial effluent were also investigated using TiO
2
NPs-cellulose composite under sun light. The results obtained were very promising which shows potential of TiO
2
NPs-cellulose composite as an efficient photocatalyst and absorbent for real time applications.
Graphical abstract |
| doi_str_mv | 10.1007/s40201-023-00884-9 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_11569373</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3130211174</sourcerecordid><originalsourceid>FETCH-LOGICAL-c403t-9b2d1ae9850922a331cca8a3cab6d1334f52cb2ef4445962bce66dd9e68e405d3</originalsourceid><addsrcrecordid>eNp9kU1vFSEUhonR2Kb2D7giceNm9MCBuYMbYxq_kpq6qIk7wgDTS8OFKzA1_fdSb-PXwhUkPO_DgZeQpwxeMIDNyyqAAxuA4wAwTWJQD8gxB8kHxPHrwz_2R-S01msAYIA4KfmYHKGSUm0EHBP_KbuwBGtayInmhVof4xpz9fR7aFt6GS44TSblvSkt2OjrK_o5N59aMJHWHE2hroQbn-h-m1vuIhNva6MmOWpczWXu7BPyaDGx-tP79YR8eff28uzDcH7x_uPZm_PBCsA2qJk7ZryaJCjODSKz1kwGrZlHxxDFIrmduV-EEFKNfLZ-HJ1Tfpy8AOnwhLw-ePfrvPPO9quLiXpfws6UW51N0H-fpLDVV_lGMyZHhRvshuf3hpK_rb42vQv17k9M8nmtGhkCZ4xtREef_YNe57Wk_r5OjThxOUnZKX6gbMm1Fr_8moaBvmtSH5rUvUn9s0mteggPodrhdOXLb_V_Uj8Ad46hZQ</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3163825855</pqid></control><display><type>article</type><title>Modification of cellulose with TiO2 nanoparticles: Potential solar driven photocatalyst and adsorbent</title><source>Springer Link</source><creator>Sharma, Deepti ; Mishra, Jai Prakash ; Dhayal, Veena</creator><creatorcontrib>Sharma, Deepti ; Mishra, Jai Prakash ; Dhayal, Veena</creatorcontrib><description>In-situ
modification of cellulose fibers with titania nanoparticles (TiO
2
NPs) (TiO
2
NPs-cellulose) was carried out via the sol–gel process using titania sol and fibers of cellulose. Cellulose fibers were extracted from wheat straw, an agricultural waste material, whereas titania sol was prepared from titanium(IV) acetoximate, [Ti{ONC(CH
3
)
2
}
4
]. The synthesized TiO
2
NPs-cellulose composite was characterized by FT-IR, SEM–EDX, and XRD analyses. The obtained results exposed that TiO
2
NPs were homogeneously dispersed over the surface of cellulose fibers. A study was conducted to compare the photocatalytic activities of TiO
2
NPs-cellulose composite and TiO
2
NPs towards the degradation of methylene blue and methyl orange dyes under sunlight, and it was observed that the photo-degradation of methylene blue (99.99%) and methyl orange (80.73%) within 160 min is higher in the presence of TiO
2
NPs-cellulose composite than TiO
2
NPs. The adsorption capabilities of TiO
2
NPs-cellulose composite towards Pb
2+
, Cd
2+
, and Cr
3+
toxic metal ions were also examined, and it was found 44.73 mg. g
−1
(89.46%), 38.82 mg. g
−1
(77.65%), and 4.42 mg. g
−1
(8.85%), respectively. Removal of pollutants from textile industrial effluent were also investigated using TiO
2
NPs-cellulose composite under sun light. The results obtained were very promising which shows potential of TiO
2
NPs-cellulose composite as an efficient photocatalyst and absorbent for real time applications.
Graphical abstract</description><identifier>ISSN: 2052-336X</identifier><identifier>EISSN: 2052-336X</identifier><identifier>DOI: 10.1007/s40201-023-00884-9</identifier><identifier>PMID: 39559740</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Agricultural wastes ; Cellulose ; Cellulose fibers ; Dyes ; Earth and Environmental Science ; Environment ; Environmental Economics ; Environmental Engineering/Biotechnology ; Environmental Health ; Environmental Law/Policy/Ecojustice ; Fibers ; Industrial effluents ; Industrial wastewater ; Lead ; Metal ions ; Methylene blue ; Nanoparticles ; Photocatalysis ; Photocatalysts ; Photodegradation ; Pollutant removal ; Quality of Life Research ; Research Article ; Sol-gel processes ; Sunlight ; Titanium ; Titanium dioxide ; Waste Management/Waste Technology ; Waste materials ; Wheat straw</subject><ispartof>Journal of environmental health science and engineering, 2024-06, Vol.22 (1), p.167-178</ispartof><rights>The Author(s), under exclusive licence to Tehran University of Medical Sciences 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>Copyright BioMed Central 2024</rights><rights>The Author(s), under exclusive licence to Tehran University of Medical Sciences 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. 2023</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c403t-9b2d1ae9850922a331cca8a3cab6d1334f52cb2ef4445962bce66dd9e68e405d3</cites><orcidid>0000-0001-9170-4748</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,27901,27902</link.rule.ids></links><search><creatorcontrib>Sharma, Deepti</creatorcontrib><creatorcontrib>Mishra, Jai Prakash</creatorcontrib><creatorcontrib>Dhayal, Veena</creatorcontrib><title>Modification of cellulose with TiO2 nanoparticles: Potential solar driven photocatalyst and adsorbent</title><title>Journal of environmental health science and engineering</title><addtitle>J Environ Health Sci Engineer</addtitle><description>In-situ
modification of cellulose fibers with titania nanoparticles (TiO
2
NPs) (TiO
2
NPs-cellulose) was carried out via the sol–gel process using titania sol and fibers of cellulose. Cellulose fibers were extracted from wheat straw, an agricultural waste material, whereas titania sol was prepared from titanium(IV) acetoximate, [Ti{ONC(CH
3
)
2
}
4
]. The synthesized TiO
2
NPs-cellulose composite was characterized by FT-IR, SEM–EDX, and XRD analyses. The obtained results exposed that TiO
2
NPs were homogeneously dispersed over the surface of cellulose fibers. A study was conducted to compare the photocatalytic activities of TiO
2
NPs-cellulose composite and TiO
2
NPs towards the degradation of methylene blue and methyl orange dyes under sunlight, and it was observed that the photo-degradation of methylene blue (99.99%) and methyl orange (80.73%) within 160 min is higher in the presence of TiO
2
NPs-cellulose composite than TiO
2
NPs. The adsorption capabilities of TiO
2
NPs-cellulose composite towards Pb
2+
, Cd
2+
, and Cr
3+
toxic metal ions were also examined, and it was found 44.73 mg. g
−1
(89.46%), 38.82 mg. g
−1
(77.65%), and 4.42 mg. g
−1
(8.85%), respectively. Removal of pollutants from textile industrial effluent were also investigated using TiO
2
NPs-cellulose composite under sun light. The results obtained were very promising which shows potential of TiO
2
NPs-cellulose composite as an efficient photocatalyst and absorbent for real time applications.
Graphical abstract</description><subject>Agricultural wastes</subject><subject>Cellulose</subject><subject>Cellulose fibers</subject><subject>Dyes</subject><subject>Earth and Environmental Science</subject><subject>Environment</subject><subject>Environmental Economics</subject><subject>Environmental Engineering/Biotechnology</subject><subject>Environmental Health</subject><subject>Environmental Law/Policy/Ecojustice</subject><subject>Fibers</subject><subject>Industrial effluents</subject><subject>Industrial wastewater</subject><subject>Lead</subject><subject>Metal ions</subject><subject>Methylene blue</subject><subject>Nanoparticles</subject><subject>Photocatalysis</subject><subject>Photocatalysts</subject><subject>Photodegradation</subject><subject>Pollutant removal</subject><subject>Quality of Life Research</subject><subject>Research Article</subject><subject>Sol-gel processes</subject><subject>Sunlight</subject><subject>Titanium</subject><subject>Titanium dioxide</subject><subject>Waste Management/Waste Technology</subject><subject>Waste materials</subject><subject>Wheat straw</subject><issn>2052-336X</issn><issn>2052-336X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kU1vFSEUhonR2Kb2D7giceNm9MCBuYMbYxq_kpq6qIk7wgDTS8OFKzA1_fdSb-PXwhUkPO_DgZeQpwxeMIDNyyqAAxuA4wAwTWJQD8gxB8kHxPHrwz_2R-S01msAYIA4KfmYHKGSUm0EHBP_KbuwBGtayInmhVof4xpz9fR7aFt6GS44TSblvSkt2OjrK_o5N59aMJHWHE2hroQbn-h-m1vuIhNva6MmOWpczWXu7BPyaDGx-tP79YR8eff28uzDcH7x_uPZm_PBCsA2qJk7ZryaJCjODSKz1kwGrZlHxxDFIrmduV-EEFKNfLZ-HJ1Tfpy8AOnwhLw-ePfrvPPO9quLiXpfws6UW51N0H-fpLDVV_lGMyZHhRvshuf3hpK_rb42vQv17k9M8nmtGhkCZ4xtREef_YNe57Wk_r5OjThxOUnZKX6gbMm1Fr_8moaBvmtSH5rUvUn9s0mteggPodrhdOXLb_V_Uj8Ad46hZQ</recordid><startdate>20240601</startdate><enddate>20240601</enddate><creator>Sharma, Deepti</creator><creator>Mishra, Jai Prakash</creator><creator>Dhayal, Veena</creator><general>Springer International Publishing</general><general>BioMed Central</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>K9.</scope><scope>SOI</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-9170-4748</orcidid></search><sort><creationdate>20240601</creationdate><title>Modification of cellulose with TiO2 nanoparticles: Potential solar driven photocatalyst and adsorbent</title><author>Sharma, Deepti ; Mishra, Jai Prakash ; Dhayal, Veena</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c403t-9b2d1ae9850922a331cca8a3cab6d1334f52cb2ef4445962bce66dd9e68e405d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Agricultural wastes</topic><topic>Cellulose</topic><topic>Cellulose fibers</topic><topic>Dyes</topic><topic>Earth and Environmental Science</topic><topic>Environment</topic><topic>Environmental Economics</topic><topic>Environmental Engineering/Biotechnology</topic><topic>Environmental Health</topic><topic>Environmental Law/Policy/Ecojustice</topic><topic>Fibers</topic><topic>Industrial effluents</topic><topic>Industrial wastewater</topic><topic>Lead</topic><topic>Metal ions</topic><topic>Methylene blue</topic><topic>Nanoparticles</topic><topic>Photocatalysis</topic><topic>Photocatalysts</topic><topic>Photodegradation</topic><topic>Pollutant removal</topic><topic>Quality of Life Research</topic><topic>Research Article</topic><topic>Sol-gel processes</topic><topic>Sunlight</topic><topic>Titanium</topic><topic>Titanium dioxide</topic><topic>Waste Management/Waste Technology</topic><topic>Waste materials</topic><topic>Wheat straw</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sharma, Deepti</creatorcontrib><creatorcontrib>Mishra, Jai Prakash</creatorcontrib><creatorcontrib>Dhayal, Veena</creatorcontrib><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Environment Abstracts</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Journal of environmental health science and engineering</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sharma, Deepti</au><au>Mishra, Jai Prakash</au><au>Dhayal, Veena</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Modification of cellulose with TiO2 nanoparticles: Potential solar driven photocatalyst and adsorbent</atitle><jtitle>Journal of environmental health science and engineering</jtitle><stitle>J Environ Health Sci Engineer</stitle><date>2024-06-01</date><risdate>2024</risdate><volume>22</volume><issue>1</issue><spage>167</spage><epage>178</epage><pages>167-178</pages><issn>2052-336X</issn><eissn>2052-336X</eissn><abstract>In-situ
modification of cellulose fibers with titania nanoparticles (TiO
2
NPs) (TiO
2
NPs-cellulose) was carried out via the sol–gel process using titania sol and fibers of cellulose. Cellulose fibers were extracted from wheat straw, an agricultural waste material, whereas titania sol was prepared from titanium(IV) acetoximate, [Ti{ONC(CH
3
)
2
}
4
]. The synthesized TiO
2
NPs-cellulose composite was characterized by FT-IR, SEM–EDX, and XRD analyses. The obtained results exposed that TiO
2
NPs were homogeneously dispersed over the surface of cellulose fibers. A study was conducted to compare the photocatalytic activities of TiO
2
NPs-cellulose composite and TiO
2
NPs towards the degradation of methylene blue and methyl orange dyes under sunlight, and it was observed that the photo-degradation of methylene blue (99.99%) and methyl orange (80.73%) within 160 min is higher in the presence of TiO
2
NPs-cellulose composite than TiO
2
NPs. The adsorption capabilities of TiO
2
NPs-cellulose composite towards Pb
2+
, Cd
2+
, and Cr
3+
toxic metal ions were also examined, and it was found 44.73 mg. g
−1
(89.46%), 38.82 mg. g
−1
(77.65%), and 4.42 mg. g
−1
(8.85%), respectively. Removal of pollutants from textile industrial effluent were also investigated using TiO
2
NPs-cellulose composite under sun light. The results obtained were very promising which shows potential of TiO
2
NPs-cellulose composite as an efficient photocatalyst and absorbent for real time applications.
Graphical abstract</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><pmid>39559740</pmid><doi>10.1007/s40201-023-00884-9</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0001-9170-4748</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2052-336X |
| ispartof | Journal of environmental health science and engineering, 2024-06, Vol.22 (1), p.167-178 |
| issn | 2052-336X 2052-336X |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_11569373 |
| source | Springer Link |
| subjects | Agricultural wastes Cellulose Cellulose fibers Dyes Earth and Environmental Science Environment Environmental Economics Environmental Engineering/Biotechnology Environmental Health Environmental Law/Policy/Ecojustice Fibers Industrial effluents Industrial wastewater Lead Metal ions Methylene blue Nanoparticles Photocatalysis Photocatalysts Photodegradation Pollutant removal Quality of Life Research Research Article Sol-gel processes Sunlight Titanium Titanium dioxide Waste Management/Waste Technology Waste materials Wheat straw |
| title | Modification of cellulose with TiO2 nanoparticles: Potential solar driven photocatalyst and adsorbent |
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