Assessing the Influence of Illumination on Ion Conductivity in Perovskite Solar Cells

• Published in: The journal of physical chemistry letters 2024-11, Vol.15 (45), p.11252-11258
• Main Authors: Schiller, Andreas, Jenatsch, Sandra, Blülle, Balthasar, Torre Cachafeiro, Miguel Angel, Ebadi, Firouzeh, Kabir, Nasim, Othman, Mostafa, Wolff, Christian Michael, Hessler-Wyser, Aïcha, Ballif, Christophe, Tress, Wolfgang, Ruhstaller, Beat
• Format: Article
• Language: English
• Subjects: Letter; Physical Insights into Light Interacting with Matter
• ISSN: 1948-7185; 1948-7185
• DOI: 10.1021/acs.jpclett.4c02403

Whether illumination influences the ion conductivity in lead-halide perovskite solar cells containing iodide halides has been an ongoing debate. Experiments to elucidate the presence of a photoconductive effect require special devices or measurement techniques and neglect possible influences of the enhanced electronic charge concentrations. Here, we assess the electronic-ionic charge transport using drift-diffusion simulations and show that the well-known increase in capacitance at low frequencies under illumination is caused by electronic currents that are amplified due to the screening of the alternating electric field by the ions. We propose a novel characterization technique to detect a potential photoinduced increase in ionic conductivity based on capacitance measurements on fully integrated devices. The method is applied to a range of perovskite solar cells with different active layer materials. Remarkably, all measured samples show a clear signature of photoenhanced ion conductivity, posing fundamental questions on the underlying nature of the photosensitive mechanism.