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Trigonal Planar Heteroleptic Lanthanide(III) Bis(silyl)amide Complexes Containing Aminoxyl Radicals and Anions

Modulation of the crystal field (CF) in lanthanide (Ln) complexes can enhance optical and magnetic properties, and large CF splitting can be achieved with low coordination numbers in specific geometries. We previously reported that the homoleptic near-linear Sm2+ complex [SmII{N­(SiiPr3)2}2] (1-Sm)...

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Published in:Inorganic chemistry 2024-11, Vol.63 (47), p.22422-22434
Main Authors: Gransbury, Gemma K., Nicholas, Hannah M., Murphy, Siobhan R., Emerson-King, Jack, Vonci, Michele, Goodwin, Conrad A. P., Winpenny, Richard E. P., Chilton, Nicholas F., Giansiracusa, Marcus J., Mills, David P.
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container_end_page 22434
container_issue 47
container_start_page 22422
container_title Inorganic chemistry
container_volume 63
creator Gransbury, Gemma K.
Nicholas, Hannah M.
Murphy, Siobhan R.
Emerson-King, Jack
Vonci, Michele
Goodwin, Conrad A. P.
Winpenny, Richard E. P.
Chilton, Nicholas F.
Giansiracusa, Marcus J.
Mills, David P.
description Modulation of the crystal field (CF) in lanthanide (Ln) complexes can enhance optical and magnetic properties, and large CF splitting can be achieved with low coordination numbers in specific geometries. We previously reported that the homoleptic near-linear Sm2+ complex [SmII{N­(SiiPr3)2}2] (1-Sm) is oxidized by the 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO•) radical to give the heteroleptic, approximately trigonal planar Sm3+ complex, [SmIII{N­(SiiPr3)2}2(TEMPO–)] (2-Sm). Here, we report the synthesis of homologous [LnIII{N­(SiiPr3)2}2(TEMPO–)] (2-Ln; Ln = Tm, Yb) complexes by the oxidation of the parent [Ln­{N­(SiiPr3)2}2] (1-Ln; Ln = Tm, Yb) with TEMPO•; complexes 2-Ln all contain TEMPO– anions. The homoleptic bent Ln3+ complexes [LnIII{N­(SiiPr3)2}2]­[B­(C6F5)4] (3-Ln; Ln = Sm, Tm, Yb) were also treated with TEMPO• to yield the heteroleptic, approximately trigonal planar Ln3+ complexes [LnIII{N­(SiiPr3)2}2(TEMPO•)]­[B­(C6F5)4] (4-Ln; Ln = Sm, Tm, Yb); the cations of 4-Ln all contain TEMPO• radicals. We have compared the electronic structures of the two geometrically similar families of Ln3+ complexes with the TEMPO– anion (2-Ln) or TEMPO• radical (4-Ln) using a combination of UV–vis-NIR and EPR spectroscopy, magnetic measurements, and ab initio calculations. These studies revealed no single-molecule magnet behavior for 2-Yb despite evidence for sizable CF splitting and a high degree of purity of the ground stabilized m J = |±7/2⟩ state, while the radical TEMPO• in 4-Yb did not significantly improve performance.
doi_str_mv 10.1021/acs.inorgchem.4c03281
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Here, we report the synthesis of homologous [LnIII{N­(SiiPr3)2}2(TEMPO–)] (2-Ln; Ln = Tm, Yb) complexes by the oxidation of the parent [Ln­{N­(SiiPr3)2}2] (1-Ln; Ln = Tm, Yb) with TEMPO•; complexes 2-Ln all contain TEMPO– anions. The homoleptic bent Ln3+ complexes [LnIII{N­(SiiPr3)2}2]­[B­(C6F5)4] (3-Ln; Ln = Sm, Tm, Yb) were also treated with TEMPO• to yield the heteroleptic, approximately trigonal planar Ln3+ complexes [LnIII{N­(SiiPr3)2}2(TEMPO•)]­[B­(C6F5)4] (4-Ln; Ln = Sm, Tm, Yb); the cations of 4-Ln all contain TEMPO• radicals. We have compared the electronic structures of the two geometrically similar families of Ln3+ complexes with the TEMPO– anion (2-Ln) or TEMPO• radical (4-Ln) using a combination of UV–vis-NIR and EPR spectroscopy, magnetic measurements, and ab initio calculations. 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We previously reported that the homoleptic near-linear Sm2+ complex [SmII{N­(SiiPr3)2}2] (1-Sm) is oxidized by the 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO•) radical to give the heteroleptic, approximately trigonal planar Sm3+ complex, [SmIII{N­(SiiPr3)2}2(TEMPO–)] (2-Sm). Here, we report the synthesis of homologous [LnIII{N­(SiiPr3)2}2(TEMPO–)] (2-Ln; Ln = Tm, Yb) complexes by the oxidation of the parent [Ln­{N­(SiiPr3)2}2] (1-Ln; Ln = Tm, Yb) with TEMPO•; complexes 2-Ln all contain TEMPO– anions. The homoleptic bent Ln3+ complexes [LnIII{N­(SiiPr3)2}2]­[B­(C6F5)4] (3-Ln; Ln = Sm, Tm, Yb) were also treated with TEMPO• to yield the heteroleptic, approximately trigonal planar Ln3+ complexes [LnIII{N­(SiiPr3)2}2(TEMPO•)]­[B­(C6F5)4] (4-Ln; Ln = Sm, Tm, Yb); the cations of 4-Ln all contain TEMPO• radicals. We have compared the electronic structures of the two geometrically similar families of Ln3+ complexes with the TEMPO– anion (2-Ln) or TEMPO• radical (4-Ln) using a combination of UV–vis-NIR and EPR spectroscopy, magnetic measurements, and ab initio calculations. 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title Trigonal Planar Heteroleptic Lanthanide(III) Bis(silyl)amide Complexes Containing Aminoxyl Radicals and Anions
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