Photocatalytic degradation of reactive brilliant blue X-BR in aqueous solution using quantum-sized ZnO

Quantum-sized ZnO was prepared using sol–gel method with zinc acetate dehydrate (Zn(CH 3COO) 2·2H 2O) and lithium hydroxide monohydrate (LiOH·H 2O) as raw material. The ZnO particles annealed at different temperature were characterized by means of X-ray diffraction (XRD), Infrared absorption spectro...

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Bibliographic Details
Published in:Materials research bulletin 2008-08, Vol.43 (8), p.2172-2178
Main Authors: Su, S., Lu, S.X., Xu, W.G.
Format: Article
Language:English
Subjects:
A. Oxides
A. Semiconductors
ABSORPTION SPECTROSCOPY
ACETATES
ANNEALING
AQUEOUS SOLUTIONS
B. Sol-gel chemistry
C. X-ray diffraction
D. Catalytic properties
HEAT
HYDRATES
LITHIUM HYDROXIDES
MATERIALS SCIENCE
PHOTOCATALYSIS
RAW MATERIALS
SEMICONDUCTOR MATERIALS
SOL-GEL PROCESS
X-RAY DIFFRACTION
ZINC COMPOUNDS
ZINC OXIDES
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Summary:Quantum-sized ZnO was prepared using sol–gel method with zinc acetate dehydrate (Zn(CH 3COO) 2·2H 2O) and lithium hydroxide monohydrate (LiOH·H 2O) as raw material. The ZnO particles annealed at different temperature were characterized by means of X-ray diffraction (XRD), Infrared absorption spectroscopy (IR) and UV–vis spectroscopy. The degradation rate of reactive brilliant blue X-BR in aqueous solution was used to evaluate the photocatalytic performance of the quantum-sized ZnO. The experimental results indicated that the photocatalytic property of the ZnO was excellent. The photocatalytic efficiency of quantum-sized ZnO was significantly influenced by the calcining heat. When calcined at 300 °C, its size is 6.78 nm and the photocatalytic performance is the best. The degradation rate of reactive brilliant blue X-BR could exceed 90% in 15 min at 35 °C, when the concentration of the quantum-sized ZnO was 0.35 mg/L.
ISSN:0025-5408
1873-4227
DOI:10.1016/j.materresbull.2007.08.029