Encapsulated chloride coordinating with two in-in protons of bridgehead amines in an octaprotonated azacryptand

An encapsulated chloride in a thiophene-based cryptand is bridged by two in-in protons of tertiary amines with an N...Cl(-) distance of 3.048(3) A, similar to that observed in Park and Simmons' katapinand chloride complex.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2009-01 (42), p.6409-6411
Main Authors: Saeed, Musabbir A, Fronczek, Frank R, Hossain, Md Alamgir
Format: Article
Language:English
Subjects:
Amines - chemistry
Azabicyclo Compounds - chemistry
Chlorides - chemistry
Crystallography, X-Ray
Hydrogen Bonding
Molecular Conformation
Protons
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Description
Summary:An encapsulated chloride in a thiophene-based cryptand is bridged by two in-in protons of tertiary amines with an N...Cl(-) distance of 3.048(3) A, similar to that observed in Park and Simmons' katapinand chloride complex.
ISSN:1359-7345
1364-548X
DOI:10.1039/b916099j